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应用气相色谱-质谱联用仪及微分流技术测定重芳烃中萘 被引量:1
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作者 王红卫 王华 +2 位作者 张晓冬 王爱国 陆彩霞 《理化检验(化学分册)》 CAS CSCD 北大核心 2009年第1期27-29,共3页
将微分流技术与气相色谱-质谱相结合并应用于重芳烃中萘的定性与定量检测,用甲苯作溶剂稀释重芳烃样品制成试样溶液,测定中采用火焰离子化检测器,峰面积的测定值与相应的萘浓度在0.200 g/100 mL以内呈线性关系。对同一样品分析5次,算得... 将微分流技术与气相色谱-质谱相结合并应用于重芳烃中萘的定性与定量检测,用甲苯作溶剂稀释重芳烃样品制成试样溶液,测定中采用火焰离子化检测器,峰面积的测定值与相应的萘浓度在0.200 g/100 mL以内呈线性关系。对同一样品分析5次,算得测定结果的相对标准偏差为0.45%,用标准加入法进行了回收试验,测得回收率在92.8%~100.2%之间。 展开更多
关键词 气相色谱-质谱联用法 微分流技术 重芳烃
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Imaging dynamic water invasion behavior in microfractures based on microfluidics
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作者 ZHANG Ji-cheng CHEN Shao-jie +3 位作者 JI Song-tao FENG Fan ALEKSEY A.Khoreshok ZAKI M.Mohammed 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第12期3986-4001,共16页
Fluid invasion through fractures is frequently observed in subsurface engineering. To elucidate the microkinetic behavior of fracture fluids, the microfracture structure of coal from the Surat Basin was reconstructed ... Fluid invasion through fractures is frequently observed in subsurface engineering. To elucidate the microkinetic behavior of fracture fluids, the microfracture structure of coal from the Surat Basin was reconstructed using a 3D morphometric system and stitching algorithm, then the transparent models characterizing the fracture structure were produced using microfluidics, and water invasion in the microfracture model was measured via visualization experiments under various conditions. High flow rate facilitated the invasion of the water phase into the closed channel, improving the efficiency of water invasion in the neutral wetting system. Wettability reversal changed the dominant channel for water invasion in the hydrophobic system. The invasion efficiency in closed and small aperture bypass channels was low.The reduction of effective seepage channels led to the fastest breakthrough time. Higher surface tension and interfacial curvature promoted the hysteresis effect. The reduction of effective seepage channels led to the fastest breakthrough time. The larger surface tension and interfacial curvature make the hysteresis effect more significant. These results will enable a better understanding of the rock-gas-liquid multiphase interaction mechanisms under unsaturated conditions of rocks. 展开更多
关键词 MICROFRACTURE visualized models MICROFLUIDICS phase distribution capillary hysteresis
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