采用静电纺丝技术结合后续热处理制备了尖晶石型Li_(0.35)Zn_(0.3)Fe_(2.35)O_4微纳米纤维.利用差示扫描量热(DSC)-热重分析(TGA)、傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和场发射扫描电子显微镜(FESEM)等手段研究了煅烧温度(700,80...采用静电纺丝技术结合后续热处理制备了尖晶石型Li_(0.35)Zn_(0.3)Fe_(2.35)O_4微纳米纤维.利用差示扫描量热(DSC)-热重分析(TGA)、傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和场发射扫描电子显微镜(FESEM)等手段研究了煅烧温度(700,800,900,1000℃)对产物物相和形貌的影响;利用矢量网络分析仪分析了纤维状产物的吸波性能.研究结果表明,Li_(0.35)Zn_(0.3)Fe_(2.35)O_4在700℃及以上温度煅烧后可生成单一尖晶石结构.随着煅烧温度的升高,产物依次呈现出微纳米纤维状、三维网络状、竹节状和颗粒状的微观形貌.随着匹配厚度增加,微纳米纤维状Li_(0.35)Zn_(0.3)Fe_(2.35)O_4的最低反射率向低频移动,在8 GHz以下的最佳匹配厚度为6 mm,在此厚度下吸波性能优良,最低反射率为-26 d B,对应的吸收频率为5.0 GHz,低于-10 d B的吸收频带为4.0~8.0 GHz,带宽为4 GHz.展开更多
Before densification by chemical vapor infiltration,carbon or SiC nanofibers were grown on the surface of carbon fibers by catalytic chemical vapor deposition using electroplated Ni as catalyst.The modification and me...Before densification by chemical vapor infiltration,carbon or SiC nanofibers were grown on the surface of carbon fibers by catalytic chemical vapor deposition using electroplated Ni as catalyst.The modification and mechanism of nanofibers on the pyrocarbon deposition during chemical vapor infiltration were investigated.The results show that the nanofibers improve the surface activity of the carbon fibers and become active nucleation centers during chemical vapor infiltration.They can induce the ordered deposition of pyrocarbon and adjust the interface bonding between pyrocarbon and carbon fibers during the infiltration.展开更多
基金supported by the Natural Science Foundation of Hebei Province,China(No.E2015506011)~~
文摘采用静电纺丝技术结合后续热处理制备了尖晶石型Li_(0.35)Zn_(0.3)Fe_(2.35)O_4微纳米纤维.利用差示扫描量热(DSC)-热重分析(TGA)、傅里叶变换红外光谱(FTIR)、X射线衍射(XRD)和场发射扫描电子显微镜(FESEM)等手段研究了煅烧温度(700,800,900,1000℃)对产物物相和形貌的影响;利用矢量网络分析仪分析了纤维状产物的吸波性能.研究结果表明,Li_(0.35)Zn_(0.3)Fe_(2.35)O_4在700℃及以上温度煅烧后可生成单一尖晶石结构.随着煅烧温度的升高,产物依次呈现出微纳米纤维状、三维网络状、竹节状和颗粒状的微观形貌.随着匹配厚度增加,微纳米纤维状Li_(0.35)Zn_(0.3)Fe_(2.35)O_4的最低反射率向低频移动,在8 GHz以下的最佳匹配厚度为6 mm,在此厚度下吸波性能优良,最低反射率为-26 d B,对应的吸收频率为5.0 GHz,低于-10 d B的吸收频带为4.0~8.0 GHz,带宽为4 GHz.
基金Project(12JJ6051) supported by the Natural Science Foundation of Hunan Province,ChinaProject(2011CB605806) supported by the National Basic Research Program of China
文摘Before densification by chemical vapor infiltration,carbon or SiC nanofibers were grown on the surface of carbon fibers by catalytic chemical vapor deposition using electroplated Ni as catalyst.The modification and mechanism of nanofibers on the pyrocarbon deposition during chemical vapor infiltration were investigated.The results show that the nanofibers improve the surface activity of the carbon fibers and become active nucleation centers during chemical vapor infiltration.They can induce the ordered deposition of pyrocarbon and adjust the interface bonding between pyrocarbon and carbon fibers during the infiltration.
