In order to investigate the oxidation kinetics of gas coal at low temperatures, we derived a rate equation of oxygen consumption during low-temperature oxidation of gas coal and deduced an E-c equation, expressing the...In order to investigate the oxidation kinetics of gas coal at low temperatures, we derived a rate equation of oxygen consumption during low-temperature oxidation of gas coal and deduced an E-c equation, expressing the relation between active energy E and oxygen concentration c. The reaction order n and active energy E were calculated with this equation based on experiments of static oxygen consumption tests. In addition, we proved the rationality of the E-c equation using a kinetic compensation effect and obtained the isokinetic temperature Tc. The results show that： 1） the gas coal oxidizes easily with increasing temperature and the oxidation tends to be spontaneous at higher temperatures; 2） the oxygen concentration c affects oxygen consumption very much at lower temperatures but has only a small effect at higher temperatures; 3） the isokinetic temperature Tc was 127 ℃ which has been experimentally validated as the key turning point during low-temperature spontaneous combustion of gas coal.展开更多
In order to reveal the law of raw coal seepage at different gas pressures, the gravity constant load seepage experimental system was developed and used. The law of raw coal seepage at different gas pressures with He, ...In order to reveal the law of raw coal seepage at different gas pressures, the gravity constant load seepage experimental system was developed and used. The law of raw coal seepage at different gas pressures with He, N2 and CO2 was investigated. The results show that, in a given state of stress during the experiment, with the increase of gas pressure, the permeability of raw coal sample prone to outburst exhibits a significantly decrease, and then exhibits an increasing trend when reaching the extreme point. The law of Klingberg coefficient related to the stress state and the gas adsorption properties was also obtained. Under the same experimental conditions, the Klingberg coefficient of He is greater than that of N2; and the Klingberg coefficient of CO2 has minimum value; so the stronger the gas adsorption is, the smaller the Klingberg coefficient of gas goes. Klinkenberg coefficient decreases with the increase of effective stress. Under the same conditions, the permeability of He is greater than that of N2; the permeability of CO2 has minimum value; so the stronger the gas adsorption is, the lower the permeability of the coal sample goes. The results have important significance in revealing the mechanism of gas seenage. Dredicting coal mine gas disaster, and gas drainage and safety nroduction.展开更多
The similarities and differences in seepage flow evolution laws of CH4 and CO2 during complete stress- strain process of samples were comparatively analyzed. The results show that the seepage flow evolution laws of CH...The similarities and differences in seepage flow evolution laws of CH4 and CO2 during complete stress- strain process of samples were comparatively analyzed. The results show that the seepage flow evolution laws of CH4 and CO2 are extremely similar during the stress-strain process, showing that the character- istic first decreased and then increased. A mathematical model was also established according to the rela- tionship of seepage velocity and axial strain. However, due to the strong adsorption ability of CO2, the coal samples generated a more serious ''Klinkenberg effect'' under the condition of CO2. Owing to this, the CO2 seepage flow resulted into occurrence of ''stagnation'' phenomenon during the late linear elastic stage II. In the strain consolidation stage III, the increment rate of CH4 seepage velocity was significantly greater than that of CO2. In the stress descent stage IV, when the axial load reached the peak pressure of coal, the increment rates of CH4 seepage velocity presented a turning point. But the changing rate of CO2 seepage velocity still remained slow and a turning point was presented at one time after the peak of thestrain pressure, which showed an obvious feature of hysteresis.展开更多
In order to study the propagation law of shock waves and gas flow during coal and gas outburst,we analyzed the formation process of outburst shock waves and gas flow and established the numerical simulation models of ...In order to study the propagation law of shock waves and gas flow during coal and gas outburst,we analyzed the formation process of outburst shock waves and gas flow and established the numerical simulation models of the roadways with 45°intersection and 135°intersection to simulate the propagation of outburst gas flow and the process of gas transport.Based on the analysis of the simulation results,we obtained the qualitative and quantitative conclusions on the characteristics and patterns of propagation and attenuation of outburst shock waves and gas flow.With the experimental models,we investigated the outburst shock waves and gas flow in the roadways with the similar structures to the simulated ones.According to the simulation results,when the angle between the driving roadway and the adjacent roadway increased,the sudden pressure variation range in adjacent roadway and the influencing scope of gas flow increased and the sudden pressure variation duration decreased.The intersection between the driving roadway and the adjacent roadway has no effect on airflow reversal induced by the shock waves and gas flow.展开更多
In light of the possibility of reignition when unsealing the closed fire zones, the occurrence of reignition was simulated by a home-made experimental device, hydrogen variety rule from combustion to unsealing was ana...In light of the possibility of reignition when unsealing the closed fire zones, the occurrence of reignition was simulated by a home-made experimental device, hydrogen variety rule from combustion to unsealing was analyzed, the three-stage generation model of hydrogen during reignition in fire zone was put forward and the probability that hydrogen was taken as an indicator gas was discussed. The results show that: when fire zone is ready to unseal, which is filled with hydrogen at a high concentration, it is more prone to reignite.展开更多
Where are the zones more enriched in sand deposits in the down slope and deep depression of the low swelling slope belt? Are there any screening conditions for oil and gas there? These are the chief geological problem...Where are the zones more enriched in sand deposits in the down slope and deep depression of the low swelling slope belt? Are there any screening conditions for oil and gas there? These are the chief geological problems to be solved during exploration of a region. Taking the Paleogene system developed along the east slope belt of Chengdao as an example the concepts of sequence stratigraphy and sedimentary sequenc are applied. A new research method likened to a way ''to get a melon by following the vine'' is proposed to determine the direction for exploring within un-drilled or less-drilled areas. This is the process: ''the characteristics of the sequence boundary ? the forming mechanism of the stratigraphic sequence ? the conditions of oil and gas accumulation ? the distribution zones of oil and gas''. The relationship between the dynamic mechanism of stratigraphic sequence and the forming conditions for oil and gas accumulation establishes that the tectonic disturbance of the slope belt has significant responses as denudation and deposition. Above the stratigraphic sequence boundary there are large scale sand bodies of the low stand system tract (LST) that have developed in the low swelling slope belt and its deep depression. Below the sequence boundary there are the remaining sand bodies of the high stand system tract (HST). On the slope there is a convergence of mudstone layers of the extended system tract (EST) with the mudstone of the underlying strata, which constitutes the screening conditions for the reservoir of the down slope and deep depression. The distribution regularities in preferred sand bodies on the surface of the sequence boundary, and in the system tract, indicate the ordering of oil-gas deposits. From the higher stand down to the depth of the slope there are, in order, areas where exploration was unfavorable, major areas of stratigraphic overlap of oil-gas reservoirs, unconformity screened oil-gas reservoirs, and, finally, sandstone lens oil-gas reservoirs. The low swelling slope belt of Chengdao was tectonically active, which is typical for a continental rift basin. The methodology and results of the present paper are significant for the theory and practice of predicting subtle reservoir and selecting strategic areas for exploration.展开更多
基金financial support provided by the National Key Technology R&D Program during the 11th Five-Year Period (No. 2006BAK03B05)the National Natural Science Foundation of China (Nos.50534090, 50674090 and 50804047)+1 种基金the Research Fund of the State Key Laboratory of Coal Resources and Mine Safety, China University of Mining and Technology (Nos.08KF14 and SKLCRSM09X04)the Scien-tific Research Foundation of China University of Mining & Technology (No.2007A001)
文摘In order to investigate the oxidation kinetics of gas coal at low temperatures, we derived a rate equation of oxygen consumption during low-temperature oxidation of gas coal and deduced an E-c equation, expressing the relation between active energy E and oxygen concentration c. The reaction order n and active energy E were calculated with this equation based on experiments of static oxygen consumption tests. In addition, we proved the rationality of the E-c equation using a kinetic compensation effect and obtained the isokinetic temperature Tc. The results show that： 1） the gas coal oxidizes easily with increasing temperature and the oxidation tends to be spontaneous at higher temperatures; 2） the oxygen concentration c affects oxygen consumption very much at lower temperatures but has only a small effect at higher temperatures; 3） the isokinetic temperature Tc was 127 ℃ which has been experimentally validated as the key turning point during low-temperature spontaneous combustion of gas coal.
基金supported by the Fundamental Research Funds for the Central Universities (No. 2011QZ02)the National Natural Science Foundation of China (No. 51204189)the National Basic Research Program of China (No. 2011CB201202)
文摘In order to reveal the law of raw coal seepage at different gas pressures, the gravity constant load seepage experimental system was developed and used. The law of raw coal seepage at different gas pressures with He, N2 and CO2 was investigated. The results show that, in a given state of stress during the experiment, with the increase of gas pressure, the permeability of raw coal sample prone to outburst exhibits a significantly decrease, and then exhibits an increasing trend when reaching the extreme point. The law of Klingberg coefficient related to the stress state and the gas adsorption properties was also obtained. Under the same experimental conditions, the Klingberg coefficient of He is greater than that of N2; and the Klingberg coefficient of CO2 has minimum value; so the stronger the gas adsorption is, the smaller the Klingberg coefficient of gas goes. Klinkenberg coefficient decreases with the increase of effective stress. Under the same conditions, the permeability of He is greater than that of N2; the permeability of CO2 has minimum value; so the stronger the gas adsorption is, the lower the permeability of the coal sample goes. The results have important significance in revealing the mechanism of gas seenage. Dredicting coal mine gas disaster, and gas drainage and safety nroduction.
基金supported by the National Natural Science Foundation of China (Nos. 51074197 and 50674111)the Natural Science Foundation of CQ CSTC (No. 2010BB6118)the Fundamental Research Funds for the Central Universities (No. CDJXS11241181)
文摘The similarities and differences in seepage flow evolution laws of CH4 and CO2 during complete stress- strain process of samples were comparatively analyzed. The results show that the seepage flow evolution laws of CH4 and CO2 are extremely similar during the stress-strain process, showing that the character- istic first decreased and then increased. A mathematical model was also established according to the rela- tionship of seepage velocity and axial strain. However, due to the strong adsorption ability of CO2, the coal samples generated a more serious ''Klinkenberg effect'' under the condition of CO2. Owing to this, the CO2 seepage flow resulted into occurrence of ''stagnation'' phenomenon during the late linear elastic stage II. In the strain consolidation stage III, the increment rate of CH4 seepage velocity was significantly greater than that of CO2. In the stress descent stage IV, when the axial load reached the peak pressure of coal, the increment rates of CH4 seepage velocity presented a turning point. But the changing rate of CO2 seepage velocity still remained slow and a turning point was presented at one time after the peak of thestrain pressure, which showed an obvious feature of hysteresis.
基金financially supported by the National Natural Science Foundation of China (No.51304213)the Open Funds of State Key Laboratory Cultivation Base for Gas Geology and Gas Control-Henan Polytechnic University of China (No.WS2013A03)the Fundamental Research Funds for Central Universities of China (No.2013QZ01)
文摘In order to study the propagation law of shock waves and gas flow during coal and gas outburst,we analyzed the formation process of outburst shock waves and gas flow and established the numerical simulation models of the roadways with 45°intersection and 135°intersection to simulate the propagation of outburst gas flow and the process of gas transport.Based on the analysis of the simulation results,we obtained the qualitative and quantitative conclusions on the characteristics and patterns of propagation and attenuation of outburst shock waves and gas flow.With the experimental models,we investigated the outburst shock waves and gas flow in the roadways with the similar structures to the simulated ones.According to the simulation results,when the angle between the driving roadway and the adjacent roadway increased,the sudden pressure variation range in adjacent roadway and the influencing scope of gas flow increased and the sudden pressure variation duration decreased.The intersection between the driving roadway and the adjacent roadway has no effect on airflow reversal induced by the shock waves and gas flow.
基金supported by the National Natural Science Foundation of China (No.50604014)the Program for New Century Excellent Talent Project(No.NCET-08-0838)the Research Fund of the State Key Laboratory of Coal Resources and Safe Mining,CUMT (No.09KF11)
文摘In light of the possibility of reignition when unsealing the closed fire zones, the occurrence of reignition was simulated by a home-made experimental device, hydrogen variety rule from combustion to unsealing was analyzed, the three-stage generation model of hydrogen during reignition in fire zone was put forward and the probability that hydrogen was taken as an indicator gas was discussed. The results show that: when fire zone is ready to unseal, which is filled with hydrogen at a high concentration, it is more prone to reignite.
基金The present paper is a part of the research work of the post-doc program: ''The Research on the Genesis of Paleogene Sand Bodies in the Chengdao East Slope and Its Controlling Factors'' (No.YKB 0804)
文摘Where are the zones more enriched in sand deposits in the down slope and deep depression of the low swelling slope belt? Are there any screening conditions for oil and gas there? These are the chief geological problems to be solved during exploration of a region. Taking the Paleogene system developed along the east slope belt of Chengdao as an example the concepts of sequence stratigraphy and sedimentary sequenc are applied. A new research method likened to a way ''to get a melon by following the vine'' is proposed to determine the direction for exploring within un-drilled or less-drilled areas. This is the process: ''the characteristics of the sequence boundary ? the forming mechanism of the stratigraphic sequence ? the conditions of oil and gas accumulation ? the distribution zones of oil and gas''. The relationship between the dynamic mechanism of stratigraphic sequence and the forming conditions for oil and gas accumulation establishes that the tectonic disturbance of the slope belt has significant responses as denudation and deposition. Above the stratigraphic sequence boundary there are large scale sand bodies of the low stand system tract (LST) that have developed in the low swelling slope belt and its deep depression. Below the sequence boundary there are the remaining sand bodies of the high stand system tract (HST). On the slope there is a convergence of mudstone layers of the extended system tract (EST) with the mudstone of the underlying strata, which constitutes the screening conditions for the reservoir of the down slope and deep depression. The distribution regularities in preferred sand bodies on the surface of the sequence boundary, and in the system tract, indicate the ordering of oil-gas deposits. From the higher stand down to the depth of the slope there are, in order, areas where exploration was unfavorable, major areas of stratigraphic overlap of oil-gas reservoirs, unconformity screened oil-gas reservoirs, and, finally, sandstone lens oil-gas reservoirs. The low swelling slope belt of Chengdao was tectonically active, which is typical for a continental rift basin. The methodology and results of the present paper are significant for the theory and practice of predicting subtle reservoir and selecting strategic areas for exploration.
