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高钛渣强化焙烧—浸出法制备人造金红石 被引量:4
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作者 蒋伟 蒋训雄 +4 位作者 范艳青 汪胜东 张登高 刘巍 冯林勇 《有色金属工程》 CSCD 北大核心 2011年第5期35-37,共3页
通过对高钛渣化学成分及物相的分析,选择强化焙烧—浸出工艺制备人造金红石,为氯化法生产钛白粉提供优质原料。试验研究得出最佳工艺条件为:焙烧温度900℃,洗涤剂浓度50 g/L,洗涤液固比3:1,洗涤温度为60℃,洗涤时间为0.5 h。制备出的人... 通过对高钛渣化学成分及物相的分析,选择强化焙烧—浸出工艺制备人造金红石,为氯化法生产钛白粉提供优质原料。试验研究得出最佳工艺条件为:焙烧温度900℃,洗涤剂浓度50 g/L,洗涤液固比3:1,洗涤温度为60℃,洗涤时间为0.5 h。制备出的人造金红石TiO2品位高达94%以上,满足《中华人民共和国有色行业标准》YS/T299-2010规定的人造金红石TiO2-1产品的要求。 展开更多
关键词 高钛渣 人造金红石 强化焙烧 浸出
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强化氯化焙烧梯级分离电镀污泥中铬镍铜机制研究 被引量:2
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作者 罗教生 龚杰 +2 位作者 曾桂生 熊甘霖 王忠兵 《有色金属(冶炼部分)》 CAS 北大核心 2023年第9期98-108,共11页
电镀污泥是一种具有资源和危害双重特性的人造富矿典型危险废物。采用NH_(4)Cl和CaCl_(2)为复合氯化剂,同时引入FeSO_(4)·7H_(2)O为强化剂,采用强化氯化焙烧的方式,通过控制调节温度场梯级分离电镀污泥中的Cr、Ni、Cu,并探究其梯... 电镀污泥是一种具有资源和危害双重特性的人造富矿典型危险废物。采用NH_(4)Cl和CaCl_(2)为复合氯化剂,同时引入FeSO_(4)·7H_(2)O为强化剂,采用强化氯化焙烧的方式,通过控制调节温度场梯级分离电镀污泥中的Cr、Ni、Cu,并探究其梯级分离机制。热力学计算表明,电镀污泥中Ni、Cr、Cu的主要物相(Cr_(2)O_(3)除外)均能被HCl或Cl_(2)氯化成相应金属氯化物。试验结果表明:NH4Cl在大约400℃分解产生HCl,首先将电镀污泥中Ni、Cr、Cu的主要物相进行氯化,生成的少量CrCl_(3)在500℃左右挥发;在700℃时,FeSO_(4)·7H_(2)O分解产生SO_(2)和O_(2)促进CaCl_(2)分解生成Cl_(2)进行二次氯化;生成的NiCl_(2)在800℃时大量挥发,挥发过程可采用零级化学反应动力学模型即属相边界反应控制来描述;而生成的CuCl_(2)在900℃左右开始挥发,1100℃时挥发完全,且该温度下收集到的CuCl_(2)(H_(2)O)_(2)晶体纯度达到94%,高温挥发过程可用1级反应动力学模型和1/2级反应动力学模型共同描述。因此,在可控的温度场下,通过氯化剂的定向相变,可以实现Cr、Ni、Cu的逐步分离和高效回收。该研究为电镀污泥中有价金属资源化回收提供了新的方法和重要的理论依据,同时对其他多金属固废的资源化利用具有借鉴意义。 展开更多
关键词 电镀污泥 强化氯化焙烧 有价金属 梯级分离 挥发动力学
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Effects of intense magnetic field on digestion and settling performances of bauxite 被引量:1
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作者 吕国志 张廷安 +4 位作者 王小晓 张旭华 刘燕 赵秋月 豆志河 《Journal of Central South University》 SCIE EI CAS 2014年第6期2168-2175,共8页
The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate... The effects of magnetic field intensity, roasting temperature and roasting time on digestion rate and settling performance of bauxite with different iron contents were investigated systematically. The results indicate that such magnetic treatment can profoundly change the microstructure and digestion performance of bauxite. For the two samples carrying different iron contents, phase transformation of the aluminum oxide phase proceeds faster in the high iron bauxite than the low one. The optimal pretreatment conditions of low iron bauxite are roasting temperature 550 ℃ and magnetic field intensity 6 T, while for high iron bauxite are 500 ℃ and 9 T. The digestion rate of alumina can reach 95% and 92% at digestion temperature of 190 ℃ and 250 ℃. The settling performances of roasted ore by intense magnetic field after digestion are enhanced through pretreatment. 展开更多
关键词 BAUXITE intense magnetic field phase transformation digestion performance settling performance
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Strengthening pelletization of manganese ore fines containing high combined water by high pressure roll grinding and optimized temperature elevation system 被引量:5
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作者 朱德庆 余为 +1 位作者 周仙霖 潘建 《Journal of Central South University》 SCIE EI CAS 2014年第9期3485-3491,共7页
Pelletization is one of useful processes for the agglomeration of iron ore or concentrates. However, manganese ore fines are mainly agglomerated by sintering due to its high combined water which adversely affects the ... Pelletization is one of useful processes for the agglomeration of iron ore or concentrates. However, manganese ore fines are mainly agglomerated by sintering due to its high combined water which adversely affects the roasting performance of pellets. In this work, high pressure roll grinding(HPRG) process and optimization of temperature elevation system were investigated to improve the strength of fired manganese ore pellets. It is shown that the manganese ore possesses good ballability after being pretreated by HPRG twice, and good green balls were produced under the conditions of blending 2.0% bentonite in the feed, balling for 7 min at 16.00% moisture. High quality roasted pellets with the compressive strength of 2711 N per pellet were manufactured through preheating at 1050 °C for 10 min and firing at 1335 °C for 15 min by controlling the cracks formation. The fired manganese pellets keep the strength by the solid interconnection of recrystallized pyrolusite grains and the binding of manganite liquid phase which filled the pores and clearance among minerals. The product pellets contain high Mn grade and low impurities, and can be used to smelt ferromanganese, which provides a possible way to use imported manganese ore fines containing high combined water to produce high value ferromanganese. 展开更多
关键词 manganese ore fines containing high combined water PELLETIZATION high pressure roll grinding optimized temperatureelevation system consolidation mechanism
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