Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state an...The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state and the input control matrices. By applying an input delay approach, the system was transformed into a continuous time-delay system. Attention was focused on the design of a robust guaranteed cost sampled-data control law which guarantees that the closed-loop system is asymptotically stable and the quadratic performance index is less than a certain bound for all admissible uncertainties. By applying Lyapunov stability theory, the theorems were derived to provide sufficient conditions for the existence of robust guaranteed cost sampled-data control law in the form of linear matrix inequalities (LMIs), especially an optimal state-feedback guaranteed cost sampled-data control law which ensures the minimization of the guaranteed cost was given. The effectiveness of the proposed method was illustrated by a simulation example with the asymptotically stable curves of system state under the initial condition of x(0)=[0.679 6 0].展开更多
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
基金Project(12511109) supported by the Science and Technology Studies Foundation of Heilongjiang Educational Committee of 2011, China
文摘The robust guaranteed cost sampled-data control was studied for a class of uncertain nonlinear systems with time-varying delay. The parameter uncertainties are time-varying norm-bounded and appear in both the state and the input control matrices. By applying an input delay approach, the system was transformed into a continuous time-delay system. Attention was focused on the design of a robust guaranteed cost sampled-data control law which guarantees that the closed-loop system is asymptotically stable and the quadratic performance index is less than a certain bound for all admissible uncertainties. By applying Lyapunov stability theory, the theorems were derived to provide sufficient conditions for the existence of robust guaranteed cost sampled-data control law in the form of linear matrix inequalities (LMIs), especially an optimal state-feedback guaranteed cost sampled-data control law which ensures the minimization of the guaranteed cost was given. The effectiveness of the proposed method was illustrated by a simulation example with the asymptotically stable curves of system state under the initial condition of x(0)=[0.679 6 0].
