Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
硬度是指水中二价及多价金属离子含量的总和,其中构成天然水硬度的主要离子是Ca2＋和Mg2＋。因此,一般都以Ca2＋和Mg2＋离子含量为计算硬度。水的硬度采用两种方法表示：一是以度计：以每升水含10mg Ca O为1度,也称德国度;二是用Ca CO3...硬度是指水中二价及多价金属离子含量的总和,其中构成天然水硬度的主要离子是Ca2＋和Mg2＋。因此,一般都以Ca2＋和Mg2＋离子含量为计算硬度。水的硬度采用两种方法表示：一是以度计：以每升水含10mg Ca O为1度,也称德国度;二是用Ca CO3含量表示单位mg/L。展开更多
The development of InGaAs/InP single-photon avalanche photodiodes(SPADs)necessitates the utiliza-tion of a two-element diffusion technique to achieve accurate manipulation of the multiplication width and the dis-tribu...The development of InGaAs/InP single-photon avalanche photodiodes(SPADs)necessitates the utiliza-tion of a two-element diffusion technique to achieve accurate manipulation of the multiplication width and the dis-tribution of its electric field.Regarding the issue of accurately predicting the depth of diffusion in InGaAs/InP SPAD,simulation analysis and device development were carried out,focusing on the dual diffusion behavior of zinc atoms.A formula of X_(j)=k√t-t_(0)+c to quantitatively predict the diffusion depth is obtained by fitting the simulated twice-diffusion depths based on a two-dimensional(2D)model.The 2D impurity morphologies and the one-dimensional impurity profiles for the dual-diffused region are characterized by using scanning electron micros-copy and secondary ion mass spectrometry as a function of the diffusion depth,respectively.InGaAs/InP SPAD devices with different dual-diffusion conditions are also fabricated,which show breakdown behaviors well consis-tent with the simulated results under the same junction geometries.The dark count rate(DCR)of the device de-creased as the multiplication width increased,as indicated by the results.DCRs of 2×10^(6),1×10^(5),4×10^(4),and 2×10^(4) were achieved at temperatures of 300 K,273 K,263 K,and 253 K,respectively,with a bias voltage of 3 V,when the multiplication width was 1.5µm.These results demonstrate an effective prediction route for accu-rately controlling the dual-diffused zinc junction geometry in InP-based planar device processing.展开更多
In allusion to the limitations of the traditional attitude measurement system consisting of a three-axis magnetic sensor and two accelerometers on high-spinning projectile, a new scheme comprised of two magnetic senso...In allusion to the limitations of the traditional attitude measurement system consisting of a three-axis magnetic sensor and two accelerometers on high-spinning projectile, a new scheme comprised of two magnetic sensors and two accelerometers installed in a particular way is given. The configuration of the sensors is described. The calculation method and the mathematical model of the projectile attitude based on the sensor configuration are discussed. The basic calculation method including the Magsonde Window, the proof of the ratios of maximums and minimums and the calculation of the attitude angles are analyzed in theory. Finally, the system is simulated under the given conditions. The simulation result indicates that the estimated attitude angles are in agreement with the true attitude angles.展开更多
One-class support vector machine （OCSVM） and support vector data description （SVDD） are two main domain-based one-class （kernel） classifiers. To reveal their relationship with density estimation in the case of t...One-class support vector machine （OCSVM） and support vector data description （SVDD） are two main domain-based one-class （kernel） classifiers. To reveal their relationship with density estimation in the case of the Gaussian kernel, OCSVM and SVDD are firstly unified into the framework of kernel density estimation, and the essential relationship between them is explicitly revealed. Then the result proves that the density estimation induced by OCSVM or SVDD is in agreement with the true density. Meanwhile, it can also reduce the integrated squared error （ISE）. Finally, experiments on several simulated datasets verify the revealed relationships.展开更多
The coherent anti Stokes Raman spectrum (CARS) technology, as a new temperature measurement method, is paid more and more attention to recently. The theoretical CARS spectra of nitrogen Q branch are calculated, the ...The coherent anti Stokes Raman spectrum (CARS) technology, as a new temperature measurement method, is paid more and more attention to recently. The theoretical CARS spectra of nitrogen Q branch are calculated, the spectra at different temperatures are obtained and the effect on the CARS spectra of Raman line width is also discussed. The results show that CARS spectra are sensitive to temperature and spectrum solution is good when the Raman line width is narrow enough. The accuracy of detonation temperature measurement with this technology will reach high level.展开更多
Conventional techniques to control variations within one plate have been based on preset models and constant automatic position control (APC or pressure feedback automatic gauge control(PAGC).However.because of the r...Conventional techniques to control variations within one plate have been based on preset models and constant automatic position control (APC or pressure feedback automatic gauge control(PAGC).However.because of the rolling force prediction error in the preset models and of the inadequate response speed of dynamic system and of the eccentricity, etc.,the conventional method has not given satisfactory results, the statistics'variations within one plate are in range of 0.25-0.60 mm The authors have developed the techniques to control the variations, which are dynamic intelligent control of hydraulic screwdown system. synchronism control of hydraulic screwdown, eccentricity control method by rotary encoder and the curve of modulus of mill measured automatically, etc., The techniques were fully and successfully industrialized in The Plate Mill of Maanshan Iron and Steel Company and good results that variations are in range of 0.08-0.15min hare been obtained in that mill.展开更多
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
基金Supported by Shanghai Natural Science Foundation(22ZR1472600).
文摘The development of InGaAs/InP single-photon avalanche photodiodes(SPADs)necessitates the utiliza-tion of a two-element diffusion technique to achieve accurate manipulation of the multiplication width and the dis-tribution of its electric field.Regarding the issue of accurately predicting the depth of diffusion in InGaAs/InP SPAD,simulation analysis and device development were carried out,focusing on the dual diffusion behavior of zinc atoms.A formula of X_(j)=k√t-t_(0)+c to quantitatively predict the diffusion depth is obtained by fitting the simulated twice-diffusion depths based on a two-dimensional(2D)model.The 2D impurity morphologies and the one-dimensional impurity profiles for the dual-diffused region are characterized by using scanning electron micros-copy and secondary ion mass spectrometry as a function of the diffusion depth,respectively.InGaAs/InP SPAD devices with different dual-diffusion conditions are also fabricated,which show breakdown behaviors well consis-tent with the simulated results under the same junction geometries.The dark count rate(DCR)of the device de-creased as the multiplication width increased,as indicated by the results.DCRs of 2×10^(6),1×10^(5),4×10^(4),and 2×10^(4) were achieved at temperatures of 300 K,273 K,263 K,and 253 K,respectively,with a bias voltage of 3 V,when the multiplication width was 1.5µm.These results demonstrate an effective prediction route for accu-rately controlling the dual-diffused zinc junction geometry in InP-based planar device processing.
文摘In allusion to the limitations of the traditional attitude measurement system consisting of a three-axis magnetic sensor and two accelerometers on high-spinning projectile, a new scheme comprised of two magnetic sensors and two accelerometers installed in a particular way is given. The configuration of the sensors is described. The calculation method and the mathematical model of the projectile attitude based on the sensor configuration are discussed. The basic calculation method including the Magsonde Window, the proof of the ratios of maximums and minimums and the calculation of the attitude angles are analyzed in theory. Finally, the system is simulated under the given conditions. The simulation result indicates that the estimated attitude angles are in agreement with the true attitude angles.
基金Supported by the National Natural Science Foundation of China(60603029)the Natural Science Foundation of Jiangsu Province(BK2007074)the Natural Science Foundation for Colleges and Universities in Jiangsu Province(06KJB520132)~~
文摘One-class support vector machine （OCSVM） and support vector data description （SVDD） are two main domain-based one-class （kernel） classifiers. To reveal their relationship with density estimation in the case of the Gaussian kernel, OCSVM and SVDD are firstly unified into the framework of kernel density estimation, and the essential relationship between them is explicitly revealed. Then the result proves that the density estimation induced by OCSVM or SVDD is in agreement with the true density. Meanwhile, it can also reduce the integrated squared error （ISE）. Finally, experiments on several simulated datasets verify the revealed relationships.
文摘The coherent anti Stokes Raman spectrum (CARS) technology, as a new temperature measurement method, is paid more and more attention to recently. The theoretical CARS spectra of nitrogen Q branch are calculated, the spectra at different temperatures are obtained and the effect on the CARS spectra of Raman line width is also discussed. The results show that CARS spectra are sensitive to temperature and spectrum solution is good when the Raman line width is narrow enough. The accuracy of detonation temperature measurement with this technology will reach high level.
文摘Conventional techniques to control variations within one plate have been based on preset models and constant automatic position control (APC or pressure feedback automatic gauge control(PAGC).However.because of the rolling force prediction error in the preset models and of the inadequate response speed of dynamic system and of the eccentricity, etc.,the conventional method has not given satisfactory results, the statistics'variations within one plate are in range of 0.25-0.60 mm The authors have developed the techniques to control the variations, which are dynamic intelligent control of hydraulic screwdown system. synchronism control of hydraulic screwdown, eccentricity control method by rotary encoder and the curve of modulus of mill measured automatically, etc., The techniques were fully and successfully industrialized in The Plate Mill of Maanshan Iron and Steel Company and good results that variations are in range of 0.08-0.15min hare been obtained in that mill.
