Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composi...Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.展开更多
Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry frictio...Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry friction damping was established.Then,the incremental harmonic balance method was used to analyze the effects of the parameters of bladed disks,such as the mistuning strength of dry friction force,coupled strength,viscous damping ratio and friction strength,on the forced response of the bladed disks.The results show that the vibrational energy localization phenomenon turns up in the tuned bladed disks if the nonlinear friction damping exists,and the random mistuning of the dry friction force intensifies this kind of vibration localization.展开更多
For acquiring the details in aluminum holding furnace with bottom porous brick purging system,efforts were performed to try to find out the potential optimal operation schemes.By adopting transient analysis scheme and...For acquiring the details in aluminum holding furnace with bottom porous brick purging system,efforts were performed to try to find out the potential optimal operation schemes.By adopting transient analysis scheme and constant boundary temperature,combustion in the furnace was investigated numerically using computational fluid dynamics(CFD).The predicted gas temperature shows good agreement with the measured results,and the predicted energy distribution of the furnace is consistent with that obtained from energy balance experiment,which confirms the reliability of the numerical solution.The results show that as the fuel-air mixture temperature rises up from 300 K to 500 K,the energy utilization of the furnace could increase from 34.55% to 37.14%.However,as the excess air coefficient increases from 1.0 to 1.4,energy utilization drops from 34.55% to 29.56%.Increasing the combustion temperature is the most effective way to improve the energy efficiency of the furnace.High reactant temperature and medium excess air coefficient are recommended for high operation performance,and keeping the furnace jamb sealed well for avoiding leakage has to be emphasized.展开更多
基金Projects(5117916851308310)supported by the National Natural Science Foundation of China+1 种基金Project(LQ13E080007)supported by Zhejiang Provincial Natural Science Foundation,ChinaProject supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Jiangsu Province,China
文摘Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.
基金Project(2007CB707706) supported by the National Basic Research Program of China
文摘Aimed at the difficulty in revealing the vibration localization mechanism of mistuned bladed disks by using simple non-linear model,a mechanical model of the bladed disk with random mistuning of hysteretic dry friction damping was established.Then,the incremental harmonic balance method was used to analyze the effects of the parameters of bladed disks,such as the mistuning strength of dry friction force,coupled strength,viscous damping ratio and friction strength,on the forced response of the bladed disks.The results show that the vibrational energy localization phenomenon turns up in the tuned bladed disks if the nonlinear friction damping exists,and the random mistuning of the dry friction force intensifies this kind of vibration localization.
基金Project(2009GK2009) supported by the Science and Technology Program of Hunan Province,China
文摘For acquiring the details in aluminum holding furnace with bottom porous brick purging system,efforts were performed to try to find out the potential optimal operation schemes.By adopting transient analysis scheme and constant boundary temperature,combustion in the furnace was investigated numerically using computational fluid dynamics(CFD).The predicted gas temperature shows good agreement with the measured results,and the predicted energy distribution of the furnace is consistent with that obtained from energy balance experiment,which confirms the reliability of the numerical solution.The results show that as the fuel-air mixture temperature rises up from 300 K to 500 K,the energy utilization of the furnace could increase from 34.55% to 37.14%.However,as the excess air coefficient increases from 1.0 to 1.4,energy utilization drops from 34.55% to 29.56%.Increasing the combustion temperature is the most effective way to improve the energy efficiency of the furnace.High reactant temperature and medium excess air coefficient are recommended for high operation performance,and keeping the furnace jamb sealed well for avoiding leakage has to be emphasized.
