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LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)/Si-C软包装电池循环失效分析 被引量:2
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作者 郑舒 李保鹏 +1 位作者 常艳 蔡洪波 《电池》 CAS 北大核心 2021年第2期173-177,共5页
以LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)/硅-石墨(Si-C)软包装电池作为研究对象,通过平均电压、d Q/d U曲线、SEM、透射电子显微镜(TEM)、XRD和X射线能谱仪(EDS)等方法,研究软包装电池常温循环失效的原因。NCM622/Si-C软包装电池以... 以LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)(NCM622)/硅-石墨(Si-C)软包装电池作为研究对象,通过平均电压、d Q/d U曲线、SEM、透射电子显微镜(TEM)、XRD和X射线能谱仪(EDS)等方法,研究软包装电池常温循环失效的原因。NCM622/Si-C软包装电池以1 C在3.0~4.3 V循环300次,容量保持率为79.1%,循环过程中电池整体厚度逐渐增大,全荷电态下循环300次,厚度较循环前增加11.25%,主要由负极膨胀引起。在循环过程中,NCM622正极材料晶体结构保持完整,但有活性物质颗粒出现微裂纹;Si-C负极嵌锂膨胀、脱锂收缩,使硅颗粒破碎,负极材料表面固体电解质相界面(SEI)膜不断修复生长,从而消耗可逆的活性锂,这是电池循环容量衰减的主要原因。 展开更多
关键词 LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2) 硅-石墨(Si-C)负极 平均电压法 失效
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Online model identification of lithium-ion battery for electric vehicles 被引量:3
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作者 胡晓松 孙逢春 邹渊 《Journal of Central South University》 SCIE EI CAS 2011年第5期1525-1531,共7页
In order to characterize the voltage behavior of a lithium-ion battery for on-board electric vehicle battery management and control applications,a battery model with a moderate complexity was established.The battery o... In order to characterize the voltage behavior of a lithium-ion battery for on-board electric vehicle battery management and control applications,a battery model with a moderate complexity was established.The battery open circuit voltage (OCV) as a function of state of charge (SOC) was depicted by the Nernst equation.An equivalent circuit network was adopted to describe the polarization effect of the lithium-ion battery.A linear identifiable formulation of the battery model was derived by discretizing the frequent-domain description of the battery model.The recursive least square algorithm with forgetting was applied to implement the on-line parameter calibration.The validation results show that the on-line calibrated model can accurately predict the dynamic voltage behavior of the lithium-ion battery.The maximum and mean relative errors are 1.666% and 0.01%,respectively,in a hybrid pulse test,while 1.933% and 0.062%,respectively,in a transient power test.The on-line parameter calibration method thereby can ensure that the model possesses an acceptable robustness to varied battery loading profiles. 展开更多
关键词 battery model on-line parameter identification lithium-ion battery electric vehicle
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