The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by e...The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis,IR spectra,NMR (1H,13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system,space group C2/c with a=2.279 4(2) nm,b=0.957 10(10) nm,c=1.335 49(15) nm,β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H …O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC:726039.展开更多
文摘The title complex bis(4-aminophenylacetate)triphenylantimony(V) has been synthesized by the reaction of triphenylantimony dibromide with 4-aminophenylacetic acid in 1∶2 molar ratio. The complex was characterized by elemental analysis,IR spectra,NMR (1H,13C) and X-ray diffraction crystal structure analysis. This complex crystallizes in the monoclinic system,space group C2/c with a=2.279 4(2) nm,b=0.957 10(10) nm,c=1.335 49(15) nm,β=93.781(2)°. The molecular structure adopts a distorted trigonal bipyramidal geometry around the antimony atom. In the crystal structure molecules are connected by intermolecular N-H …O hydrogen-bonding interactions forming a two-dimensional network structure. CCDC:726039.
