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用实验解习题的教学体会
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作者 杨留华 《化学教学》 CAS 北大核心 1997年第1期36-38,共3页
关键词 实验解 演示实验 实验操作能力 教学能力 CUSO4 归纳总结 教学体会 实验设计能力 碱金属元素 教学方法
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准噶尔盆地沙湾凹陷油裂解生气动力学实验研究与油裂解生气转化率预测
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作者 米巨磊 李二庭 +6 位作者 张宇 白海枫 蔡航新 边圆圆 张泽伟 于双 潘长春 《地球化学》 北大核心 2025年第4期504-514,共11页
准噶尔盆地沙湾凹陷油裂解气资源日益受到石油公司的高度重视。本研究对沙湾凹陷沙排3井湖相油样进行裂解生气动力学模拟实验及重复实验,两次实验甲烷最高产率分别为420.8 mg/g和425.5 mg/g,总气态烃(∑C_(1~5))最高产率分别为482.5 mg/... 准噶尔盆地沙湾凹陷油裂解气资源日益受到石油公司的高度重视。本研究对沙湾凹陷沙排3井湖相油样进行裂解生气动力学模拟实验及重复实验,两次实验甲烷最高产率分别为420.8 mg/g和425.5 mg/g,总气态烃(∑C_(1~5))最高产率分别为482.5 mg/g和489.1 mg/g。依据两次实验的产率数据,应用生烃动力学软件Kinetic 2000,求取油裂解生成∑C_(1~5)动力学参数:频率因子均为1.0×10^(15)s^(-1),活化能加权平均值分别为63.05 kcal/mol和63.68 kcal/mol。将油裂解生成∑C_(1~5)转化率10%~80%定义为“裂解窗”,在地质条件下(升温速率1℃/Ma),SP3油样处于“裂解窗”的温度范围为176~207℃,成熟度范围为Easy R_(o)=1.60%~2.42%。依据沙排3井油裂解生气动力学参数,推算准噶尔盆地沙湾凹陷沙湾1井圈闭构造石炭系(C)、二叠系佳木河组(P_(1)j)和风城组(P_(1)f)储层油裂解生气转化率现今均高于80%,越过原油“裂解窗”,只能找到气藏。而中二叠统夏子街组(P_(2)x)和下乌尔禾组(P_(2)w)中间层段储层油裂解生气转化率现今分别为50%和27%,处于原油裂解窗中期和早期,仍以油藏为主。 展开更多
关键词 油裂实验 油裂生气动力学 油裂 准噶尔盆地沙湾凹陷
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Nash谈判解的预测能力——中国被试的实验证据 被引量:7
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作者 李建标 李晓义 +1 位作者 孙娟 祁艳玲 《南开经济研究》 CSSCI 北大核心 2007年第6期33-42,共10页
讨价还价是人们最基本的交易制度之一。在非结构化的讨价还价中,Nash谈判解具有重要的预测意义,但现有的实验研究表明,Nash谈判解的第4公理,即效用线性变换无关性公理,并没有很好地得到实验结果支持。本文的实验表明,信息问题并没有影响... 讨价还价是人们最基本的交易制度之一。在非结构化的讨价还价中,Nash谈判解具有重要的预测意义,但现有的实验研究表明,Nash谈判解的第4公理,即效用线性变换无关性公理,并没有很好地得到实验结果支持。本文的实验表明,信息问题并没有影响Nash谈判解的预测能力,即在完全信息条件下,第4公理仍然是不可拒绝的。但在信息完全框架中加上谈判者不同的效用评价,Nash谈判解的预测能力被折扣掉一部分,这也说明不能笼统地将信息和效用评价放在一起来界定第4公理。 展开更多
关键词 双边讨价还价 Nash谈判实验
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司太立(STELLITE)合金带锯条的实验性锯解
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作者 王文华 肖文辉 +2 位作者 智永林 赵宏奇 李春亭 《林业科技开发》 1994年第1期21-23,共3页
关键词 司太立 合金带锯条 实验性锯
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珠江口盆地白云凹陷原油半开放条件下裂解成气模拟实验 被引量:4
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作者 龙祖烈 石创 +3 位作者 朱俊章 黄玉平 史玉玲 张小龙 《石油实验地质》 CAS CSCD 北大核心 2021年第3期507-512,共6页
为深入研究珠江口盆地白云凹陷原油裂解机制及产物变化特征,选取了白云凹陷渐新统珠海组原油样品,利用高温高压模拟实验,模拟了地下压力、地下流体介质及半开放条件下、不同升温速率的原油裂解过程,分析了气产率和气体组分特征。研究表... 为深入研究珠江口盆地白云凹陷原油裂解机制及产物变化特征,选取了白云凹陷渐新统珠海组原油样品,利用高温高压模拟实验,模拟了地下压力、地下流体介质及半开放条件下、不同升温速率的原油裂解过程,分析了气产率和气体组分特征。研究表明,原油样品在365℃开始裂解,裂解产率随温度增加而增加,在20℃/h的升温速率下,最终(550℃)裂解气体产率、烃气产率和非烃气体产率分别为580.13,394.25,185.88 mg/g;而在60℃/h的升温速率下,最终(550℃)裂解气体产率、烃气产率和非烃气体产率分别为707.68,485.77,221.91 mg/g。不同升温速率下最终产率的差异和烃气的组分差异均与不同温度下原油裂解机制差异有关。从原油裂解成气模拟实验的组分特征来看,大部分原油裂解气具有较高的重烃气含量,而较高重烃含量可作为判识原油裂解气和干酪根裂解气的辅助指标。 展开更多
关键词 原油裂 模拟实验 半开放体系 气产率 天然气 珠海组 白云凹陷 珠江口盆地
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丁烯裂解制取丙烯和乙烯的热力学因素分析及反应性能研究 被引量:10
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作者 刘俊涛 谢在库 +1 位作者 徐春明 钟思青 《石油炼制与化工》 CAS CSCD 北大核心 2005年第8期44-48,共5页
用吉布斯自由能最小原理法对C2~C5烯烃构成的热力学网络进行了平衡状态的计算,并与1丁烯及混合碳四烃在ZSM5分子筛催化剂上的催化裂解实验结果进行了比较。结果表明:在ZSM5分子筛催化剂上,不管进料是1丁烯还是混合碳四烃,裂解产物中C2... 用吉布斯自由能最小原理法对C2~C5烯烃构成的热力学网络进行了平衡状态的计算,并与1丁烯及混合碳四烃在ZSM5分子筛催化剂上的催化裂解实验结果进行了比较。结果表明:在ZSM5分子筛催化剂上,不管进料是1丁烯还是混合碳四烃,裂解产物中C2~C5烯烃收率随温度的变化趋势同热力学规律一致,即随温度升高乙烯产率不断升高,而丙烯的产率在630~650℃达到最大值。推荐实现最大化丙烯收率的温度范围为630~650℃。 展开更多
关键词 丁烯裂 丙烯 乙烯 热力学因素 反应性能 吉布斯自由能最小原理法 催化裂实验
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印刷板式微通道换热器流动与传热特性的理论模型 被引量:4
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作者 余智强 吴建泽 +3 位作者 任亚涛 何明键 于喜奎 齐宏 《化工学报》 EI CSCD 北大核心 2022年第12期5324-5342,F0002,共20页
随着能源问题的日益突出,亟需研制高效能源设备,微通道换热器以其优良的性能在热管理系统中备受关注。针对微通道换热器流动与传热特性理论计算提出了一个计算模型,基于文献建立实验数据库,分别对比分析了10种和6种传热与流动计算关联式... 随着能源问题的日益突出,亟需研制高效能源设备,微通道换热器以其优良的性能在热管理系统中备受关注。针对微通道换热器流动与传热特性理论计算提出了一个计算模型,基于文献建立实验数据库,分别对比分析了10种和6种传热与流动计算关联式,并针对一种换热器结构进行了数值仿真与模型求解。研究得出:采用Stephan等、Sarmiento等提出关联式所得关于传热特性的经验解与实验解的吻合度较好;采用Kim等、Muzychka等提出的关联式所得关于流动特性的经验解与实验解的吻合度较好;对换热单元进行数值仿真和模型计算,数值解与经验解中绝大多数点的误差在10%以内,验证了本文提出计算模型在理论求解中的准确性与可信度。 展开更多
关键词 微通道换热器 流动与传热特性 计算模型 数值仿真 数值 实验解 经验
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Complete splitting process of steel fiber reinforced concrete at intermediate strain rate 被引量:1
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作者 罗章 李夕兵 赵伏军 《Journal of Central South University of Technology》 EI 2008年第4期569-573,共5页
The complete splitting process of steel fiber reinforced concrete (SFRC) at intermediate strain rate was studied by experiment. The basic information of a self-developed SFRC dynamic test system matching with lnstro... The complete splitting process of steel fiber reinforced concrete (SFRC) at intermediate strain rate was studied by experiment. The basic information of a self-developed SFRC dynamic test system matching with lnstron 1342 materials testing machine was given, and the experiment principle and the loading mode of cubic split specimen were introduced. During the experiment, 30 cubes of 150 mm×150 mm×150 mm and 36 cubes of 100 mm×100 mm×100 mm, designed and prepared according to C20 class SFRC with different volume fractions of steel fiber (0, 1%, 2%, 3%, 4%) were tested and analyzed. At the same time, the size effect of SFRC at intermediate strain rate was investigated. The experimental study indicates that SFRC size effect is not influenced by the loading speed or strain rate. When the steel fiber content increases from 0 to 4%, the splitting strength of SFRC increases from 100% to 261%, i.e. increasing by 161% compared with that of the common concrete. The loading rate increases from 1.33 kN/s to 80.00 kN/s, and the splitting tensile strength increases by 43.55%. 展开更多
关键词 steel fiber reinforced concrete intermediate strain rate splitting test size effect
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Experimental and field study on dissipation coefficient of supersaturated total dissolved gas 被引量:10
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作者 冯镜洁 李然 +1 位作者 马倩 王乐乐 《Journal of Central South University》 SCIE EI CAS 2014年第5期1995-2003,共9页
The elevated supersaturation of total dissolved gas (TDG) downstream of a high-dam spill has deleterious effects on fish in a large range. A one-dimensional (l-D) longitudinal model is optimal for the prediction o... The elevated supersaturation of total dissolved gas (TDG) downstream of a high-dam spill has deleterious effects on fish in a large range. A one-dimensional (l-D) longitudinal model is optimal for the prediction of supersaturated TDG dissipation over a long distance. The key issue of the model is to determine the dissipation coefficient accurately. In agreement with field observations and experiment data, dimensional analysis and regression were performed to propose a formula for estimating the dissipation coefficient of supersaturated TDG in various rivers and reservoirs, and it involves the effects of the turbulence intensity, the hydro-pressure and the solid-liquid interface. The friction velocity, water depth, hydraulic radius and Froude number are independent variables in the formula which are easy to determine in practical applications. The 1-D longitudinal model is implemented to calculate the dissipation of TDG in a reach of the Jinsha River. Good agreement is found between the calculated results and field data for both the dissipation coefficient and the dissipation process. 展开更多
关键词 total dissolved gas dissipation coefficient longitudinal model HYDRODYNAMICS
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Experimental study on co-pyrolysis characteristics of typical medical waste compositions 被引量:6
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作者 邓娜 崔文谦 +3 位作者 王维维 张强 张于峰 马洪亭 《Journal of Central South University》 SCIE EI CAS 2014年第12期4613-4622,共10页
Thermal decomposition of 21 kinds of binary mixtures between typical medical compositions was investigated under nitrogen conditions by dynamic thermogravimetric analysis(TGA) at 25–800 °C. The weighed sum metho... Thermal decomposition of 21 kinds of binary mixtures between typical medical compositions was investigated under nitrogen conditions by dynamic thermogravimetric analysis(TGA) at 25–800 °C. The weighed sum method(WSM) coupled with thermal analysis was applied to study the interaction between components. Then, co-pyrolysis kinetic model of the binary mixtures(tube for transfusion(TFT) and gauze) was established to verify the reliability of conclusions. The results show the follows. 1) Strong or weak interactions are shown between binary mixtures containing polyvinyl chloride(PVC), the main ingredient of TFT. The addition of other medical waste could enhance first stage decomposition of TFT. While, the secondary stage pyrolysis may be suppressed or enhanced or not affected by the addition. 2) There exists no interaction between catheter and other component, the DTG peak temperature representing Ca CO3 decomposition in catheter fraction is obviously lower than that of pure catheter; while,the shape of DTG peak keeps unchanged. 3) No evident reaction occurs between the other mix-samples, it is considered that their co-pyrolysis characteristics are linear superposition of mono-component pyrolysis characteristics. 展开更多
关键词 co-pyrolysis medical waste tube for transfusion(TFT) catheter interaction
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Combination of chlorine and magnetic ion exchange resin for drinking water treatment of algae 被引量:2
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作者 韩志刚 陈卫 +1 位作者 李磊 曹喆 《Journal of Central South University》 SCIE EI CAS 2010年第5期979-984,共6页
The effectiveness of a magnetic ion exchange resin (MIEX) for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter (NOM) removal at various MIEX doses and contact time,... The effectiveness of a magnetic ion exchange resin (MIEX) for the treatment of Hongze Lake water in China was evaluated, The kinetics of natural organic matter (NOM) removal at various MIEX doses and contact time, multiple-loading experiments, impacts of MIEX prior to coagulation on coagulant demands and the effectiveness of combination of MIEX, pre-chlorination and coagulation were investigated. Kinetic experimental results show that more than 80% UV254 and 67% dissolved organic carbon (DOC) from raw water can be removed by the use of MIEX alone. 94% sulfate, 69% nitrate and 98% bromide removals are obtained after the first use of MIEX in multiple-loading experiments. It is suggested that MIEX can be loaded up to 1 250 bed volume (BV, volume ratio of tested water to resin) or more without saturation when regarding organics removal as a target. MIEX can remove organics to a greater extend than coagulation and lower the coagulant demand when combining with coagulation. Chlorination experimental results show that MIEX can remove 57% chlorine demand and 77% trihalomethane formation potential (THMFP) for raw water. Pre-chlorination followed by MIEX and coagulation can give additional organic and THMFP removals. The results suggest that MIEX provides a new method to solve thc problem algae reproduction. 展开更多
关键词 drinking water treatment magnetic ion exchange resin natural organic matter pre-chlorination disinfection byproducts ALGAE
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Degradation behavior of aggregate skeleton in stone matrix asphalt mixture 被引量:1
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作者 马涛 王真 赵永利 《Journal of Central South University》 SCIE EI CAS 2011年第6期2192-2200,共9页
The degradation behavior of aggregate skeleton in stone matrix asphalt mixture was investigated based on theoretical analysis, laboratory test and field materials evaluation. A stress-transfer model was established to... The degradation behavior of aggregate skeleton in stone matrix asphalt mixture was investigated based on theoretical analysis, laboratory test and field materials evaluation. A stress-transfer model was established to provide the fundamental understanding of the stress distribution and degradation mechanism of stone matrix asphalt (SMA) aggregate skeleton. Based on the theoretical analysis, crushing test and superpave gyratory compactor (SGC) test were used to evaluate the degradation behavior of aggregate skeleton of SMA. To verify the laboratory test results, gradation analysis was also conducted for the field materials extracted from SMA pavements after long-time service. The results indicate that the degradation of SMA aggregate skeleton is not random but has fixed internal trend and mechanism. Special rule is found for the graded fine aggregates generated from coarse aggregate breakdown and the variation of 4.75 mm aggregate is found to play a key role in the graded aggregates to form well-balanced skeleton to bear external loading. The variation of 4.75 mm aggregate together with the breakdown ratio of aggregate gradation can be used to characterize the degradation behavior of aggregate skeleton. The crushing test and SGC test are proved to be promising in estimating the degradation behavior of SMA skeleton. 展开更多
关键词 stone matrix asphalt AGGREGATE GRADATION SKELETON DEGRADATION
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