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一种通过定向化学沉积在碳纳米管表面高密度负载金属铂的方法
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《石油化工》 CAS CSCD 北大核心 2005年第4期387-387,共1页
该专利报道了一种通过定向沉积在碳纳米管表面负载金属铂的新方法,按每1L的多元醇混合液中含有0.1~10g碳纳米管、1~100g表面活性剂、0.05~10g铂(以金属盐中的含铂量计),将碳纳米管与铂的氯化物及表面活性剂在多元醇中反应,实现... 该专利报道了一种通过定向沉积在碳纳米管表面负载金属铂的新方法,按每1L的多元醇混合液中含有0.1~10g碳纳米管、1~100g表面活性剂、0.05~10g铂(以金属盐中的含铂量计),将碳纳米管与铂的氯化物及表面活性剂在多元醇中反应,实现铂纳米粒子在碳纳米管表面的定向化学沉积,解决了金属颗粒发生自身团聚这一难题;铂的负载率高,分布均匀;在较高的负载率(50%以上)下可以得到致密的铂纳米粒子层,其颗粒尺寸平均为5nm, 展开更多
关键词 定向化学沉积 碳纳米管 金属铂 表面活性剂 负载率 电催化性能 燃料电池
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Microstructure and mechanical property of additively manufactured NiTi alloys:A comparison between selective laser melting and directed energy deposition 被引量:14
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作者 ZHENG Dan LI Rui-di +4 位作者 YUAN Tie-chui XIONG Yi SONG Bo WANG Jia-xing SU Ya-dong 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第4期1028-1042,共15页
NiTi shape memory alloy(SMA)with nominal composition of Ni 50.8 at%and Ti 49.2 at%was additively manufactured(AM)by selective laser melting(SLM)and laser directed energy deposition(DED)for a comparison study,with emph... NiTi shape memory alloy(SMA)with nominal composition of Ni 50.8 at%and Ti 49.2 at%was additively manufactured(AM)by selective laser melting(SLM)and laser directed energy deposition(DED)for a comparison study,with emphasis on its phase composition,microstructure,mechanical property and deformation mechanism.The results show that the yield strength and ductility obtained by SLM are 100 MPa and 8%,respectively,which are remarkably different from DED result with 700 MPa and 2%.The load path of SLM sample presents shape memory effect,corresponding to martensite phase detected by XRD;while the load path of DED presents pseudo-elasticity with austenite phase.In SLM sample,fine grain and hole provide a uniform deformation during tensile test,resulting in a better elongation.Furthermore,the nonequilibrium solidification was studied by a temperature field simulation to understand the difference of the two 3D printing methods.Both temperature gradient G and growth rate R determine the microstructure and phase in the SLM sample and DED sample,which leads to similar grain morphologies because of similar G/R.While higher G×R of SLM leads to a finer grain size in SLM sample,providing enough driving force for martensite transition and subsequently changing texture compared to DED sample. 展开更多
关键词 Ni50.8Ti49.2 shape memory alloy additive manufacturing selective laser melting laser directed energy deposition mechanical properties
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