A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and sho...A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.展开更多
A new tripodal complex (ClO4)2 (C26H31Cl2N7O8Zn) was synthesized by Schiff base condensation of 2-aminoethyl-bi(3-aminopropyl)amine with 2-pyridinecarbaldehyde in the presence of Zn2+ and characterized by X-ray diffra...A new tripodal complex (ClO4)2 (C26H31Cl2N7O8Zn) was synthesized by Schiff base condensation of 2-aminoethyl-bi(3-aminopropyl)amine with 2-pyridinecarbaldehyde in the presence of Zn2+ and characterized by X-ray diffraction and ES mass spectral analysis. It crystallized in the Monoclinic system, space group P21/c with a=1.088 5(4) nm, b=1.614 6(6) nm, c=1.783 0(5) nm, a=94.405(2) the four test bacterial organisms. CCDC: 231275.展开更多
An O-Vanillin-methionine Schiff Base complex with copper(Ⅱ) has been synthesized under a mild condition. The complex has been characterized by elemental analysis, UV, FT-IR, TG-DTA and XRD. The crystal structure of t...An O-Vanillin-methionine Schiff Base complex with copper(Ⅱ) has been synthesized under a mild condition. The complex has been characterized by elemental analysis, UV, FT-IR, TG-DTA and XRD. The crystal structure of the complex belongs to monoclinic, with space group C2/C, a=2.070 4(12) nm, b=1.431 9(8) nm, c=2.812 9(11) nm, β=133.15(2)°, V=6.084(5) nm 3, Z=8, D c= 0.998 Mg/m 3, F(000)=1 836, final R=0.121 8. The results revealed it is a tetranuclear copper(Ⅱ) complex.展开更多
文摘A planar metal complex NiL, H2L=acenaphthenequinone bis(S benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z scan measurements show that 1 is a transition metal complex exhibiting high third order nonlinear optical effect.
文摘A new tripodal complex (ClO4)2 (C26H31Cl2N7O8Zn) was synthesized by Schiff base condensation of 2-aminoethyl-bi(3-aminopropyl)amine with 2-pyridinecarbaldehyde in the presence of Zn2+ and characterized by X-ray diffraction and ES mass spectral analysis. It crystallized in the Monoclinic system, space group P21/c with a=1.088 5(4) nm, b=1.614 6(6) nm, c=1.783 0(5) nm, a=94.405(2) the four test bacterial organisms. CCDC: 231275.
文摘An O-Vanillin-methionine Schiff Base complex with copper(Ⅱ) has been synthesized under a mild condition. The complex has been characterized by elemental analysis, UV, FT-IR, TG-DTA and XRD. The crystal structure of the complex belongs to monoclinic, with space group C2/C, a=2.070 4(12) nm, b=1.431 9(8) nm, c=2.812 9(11) nm, β=133.15(2)°, V=6.084(5) nm 3, Z=8, D c= 0.998 Mg/m 3, F(000)=1 836, final R=0.121 8. The results revealed it is a tetranuclear copper(Ⅱ) complex.
