The new imidazole schiff base C 11 N 4H 10 and its three intermediates,as well as four complexes of Mn(C 11 N 4H 10 ) 2(ClO 4) 2·6H 2O,Mn(C 11 N 4H 10 ) 3(ClO 4) 2·2H 2O,[Mn 3(μ 3 O)(CH 3COO) 6(C 4H 6N 2) 3...The new imidazole schiff base C 11 N 4H 10 and its three intermediates,as well as four complexes of Mn(C 11 N 4H 10 ) 2(ClO 4) 2·6H 2O,Mn(C 11 N 4H 10 ) 3(ClO 4) 2·2H 2O,[Mn 3(μ 3 O)(CH 3COO) 6(C 4H 6N 2) 3]CH 3COO·2H 2O·C 2H 5OH and [Mn 3O(O 2CC 6H 5) 6(C 4H 6N 2) 3]ClO 4·2H 2O were synthesized and characterized by the means of FTIR,UB VIS and EA.展开更多
Twelve new Schiff bases of thiadiazole have been synthesized for the first time. Their physical constants, UV, IR, 1H NMR and elementary analysis were originally characterized, biological activity were originally stud...Twelve new Schiff bases of thiadiazole have been synthesized for the first time. Their physical constants, UV, IR, 1H NMR and elementary analysis were originally characterized, biological activity were originally studied. It is found from the results of biological activity tests that some compounds have a remarkable activity on plant growth hormone. Compounds Ⅲa and Ⅲk have a good activity on cytokinin, compounds Ⅲe and Ⅲj and Ⅲl have an excellent activity on auxin.展开更多
Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and e...Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and electronic spectra.The anti-bacterium activity of the complexes were tested.展开更多
A Series of mono and di-nuclear Zn Ni complexes with 5 - chlorosalicylaldehyde -ethylenediamine Schiff base have been synthesized. Theirs compositions and structures were characterized by the elemental analysis.UV.IR ...A Series of mono and di-nuclear Zn Ni complexes with 5 - chlorosalicylaldehyde -ethylenediamine Schiff base have been synthesized. Theirs compositions and structures were characterized by the elemental analysis.UV.IR spectra and 1H NMR. The Dismutation to O2 free radical has also been investigated.展开更多
Two of new Schiff bases,3-nitrobenzaldehyde salicyloyl hydrazone(C14H11N3O4),vanillic salicyloyl hydrazone(C15H14N2O4),were synthesized and characterized by the melting point,elemental analysis,UV,IR,MS and （）1H NMR...Two of new Schiff bases,3-nitrobenzaldehyde salicyloyl hydrazone(C14H11N3O4),vanillic salicyloyl hydrazone(C15H14N2O4),were synthesized and characterized by the melting point,elemental analysis,UV,IR,MS and （）1H NMR.The results,based on indexing the cell parameters of XRD,showed that they belonged to orthorhombic system.And the result peoved that the Schiff bases had selective antibacterial property.展开更多
文摘The new imidazole schiff base C 11 N 4H 10 and its three intermediates,as well as four complexes of Mn(C 11 N 4H 10 ) 2(ClO 4) 2·6H 2O,Mn(C 11 N 4H 10 ) 3(ClO 4) 2·2H 2O,[Mn 3(μ 3 O)(CH 3COO) 6(C 4H 6N 2) 3]CH 3COO·2H 2O·C 2H 5OH and [Mn 3O(O 2CC 6H 5) 6(C 4H 6N 2) 3]ClO 4·2H 2O were synthesized and characterized by the means of FTIR,UB VIS and EA.
文摘Twelve new Schiff bases of thiadiazole have been synthesized for the first time. Their physical constants, UV, IR, 1H NMR and elementary analysis were originally characterized, biological activity were originally studied. It is found from the results of biological activity tests that some compounds have a remarkable activity on plant growth hormone. Compounds Ⅲa and Ⅲk have a good activity on cytokinin, compounds Ⅲe and Ⅲj and Ⅲl have an excellent activity on auxin.
文摘Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and electronic spectra.The anti-bacterium activity of the complexes were tested.
文摘A Series of mono and di-nuclear Zn Ni complexes with 5 - chlorosalicylaldehyde -ethylenediamine Schiff base have been synthesized. Theirs compositions and structures were characterized by the elemental analysis.UV.IR spectra and 1H NMR. The Dismutation to O2 free radical has also been investigated.
文摘Two of new Schiff bases,3-nitrobenzaldehyde salicyloyl hydrazone(C14H11N3O4),vanillic salicyloyl hydrazone(C15H14N2O4),were synthesized and characterized by the melting point,elemental analysis,UV,IR,MS and （）1H NMR.The results,based on indexing the cell parameters of XRD,showed that they belonged to orthorhombic system.And the result peoved that the Schiff bases had selective antibacterial property.
