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延迟首次投喂对南方鲇(Silurus meridionalis Chen)仔鱼身体含能量、体长及游泳能力的影响 被引量:22
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作者 张怡 曹振东 付世建 《生态学报》 CAS CSCD 北大核心 2007年第3期1161-1167,共7页
在(22.0±0.5)℃条件下,将人工孵化的南方鲇仔鱼分别于出膜后4、5、6、7天进行首次投喂(其中4d的为对照组),首次投喂前(出膜后4d)取样测量体长、体重、身体含能量作为初始值,于出膜后7d(延迟投喂实验)和21d(继续喂养实验)分别测定... 在(22.0±0.5)℃条件下,将人工孵化的南方鲇仔鱼分别于出膜后4、5、6、7天进行首次投喂(其中4d的为对照组),首次投喂前(出膜后4d)取样测量体长、体重、身体含能量作为初始值,于出膜后7d(延迟投喂实验)和21d(继续喂养实验)分别测定体长、体重、身体所含能量和临界游泳速度。结果显示:延迟投喂实验结束时各处理组的体重、身体含能量和体长随首次投喂时间的延迟均呈下降趋势,相对临界游泳速度随首次投喂时间的延迟表现为先提高后降低的趋势,绝对临界游泳速度在延迟投喂2d以内无显著差异;继续喂养实验结束时处理组各指标逐渐接近对照组水平,两种临界游泳速度表现为同步变化趋势;另外,体长特定生长率相对百分比(SGRL%)的变化幅度小于身体含能量特定生长率相对百分比(SGRE%)的变化幅度,而绝对临界游泳速度相对百分比(Ucrit%)的变化又小于体长特定生长率相对百分比的变化。结果表明:早期食物资源的短缺会导致南方鲇仔鱼体重、身体含能量产生明显变化,体长生长速度的变化则相对较小,而短期饥饿不会显著降低南方鲇仔鱼的游泳能力。 展开更多
关键词 延迟首次投喂 体长 身体含能量 临界游泳速度 仔鱼 南方鲇(Silurus MERIDIONALIS Chen)
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浮游动物生物量和能量研究中的一些转换系数 被引量:1
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作者 张武昌 王 克 肖 天 《海洋科学》 CAS CSCD 北大核心 2002年第1期33-36,共4页
浮游动物的生物量是海洋浮游动物研究的重要内容.浮游动物的生物量包括以下内容:沉降体积(SV)、无水体积(DV)、湿重(WM)、干重(DM)、无灰干重(AFDM)、含碳(或氮)量和主要有机物(蛋白质、脂类和碳水化合物)的含量.在一些研究中,含能量比... 浮游动物的生物量是海洋浮游动物研究的重要内容.浮游动物的生物量包括以下内容:沉降体积(SV)、无水体积(DV)、湿重(WM)、干重(DM)、无灰干重(AFDM)、含碳(或氮)量和主要有机物(蛋白质、脂类和碳水化合物)的含量.在一些研究中,含能量比生物量更受重视. 展开更多
关键词 海洋 浮游动物生物量 含能量
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Influence of Si Content on the Mechanical and Tribological Properties of Laser Cladding FeCoNiBSiNb Amorphous Alloy Composite Materials
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作者 DU Xian YU Dongxin +3 位作者 LIU Jian CAI Zhihai HE Dongyu WANG Xiaolong 《材料导报》 北大核心 2025年第12期156-162,共7页
Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and... Aseries of [(Fe_(0.6)Co_(0.2)Ni_(0.2))_(0.75-0.03x)B_(0.2)Si_(0.05+0.03x)]_(96)Nb_(4) amorphous alloy composite coatings were prepared by adjusting the silicon content(x=0,1,2,3,4,5,and 6)and their microstructures and tribological properties were investigated by laser cladding technique.Additionally,the effect of Si on the glass forming ability(GFA)of the layers was understood.Results show that an appropriate Si content can refine the microstructure of the FeCoNiBSiNb laser cladding layers and improve the mechanical and tribological properties.The hardness of the coating layer increases monotonically with the Si content.At the Si content of 4.8at%(x=0),the coating layer exhibits a relatively low hardness(734.2HV 0.1).Conversely,at the silicon content of 13.44at%(x=3),the coating layer exhibits the highest hardness(1106HV 0.1).The non-crystalline content and tensile strength exhibit an initial increase,followed by a subsequent decrease.At x=2,the coating exhibits its maximum fracture strength(2880 MPa).However,when x>2,the fracture strength of the coating decreases with an increase in x.Conversely,with an increase in Si content,the wear volume loss initially decreases and then increases.At a Si content of 10.56at%(x=2),the coating exhibits the highest non-crystalline content(42%),the highest tensile strength(2880 MPa),and the most favorable dry friction performance. 展开更多
关键词 laser cladding FeCoNiBSiNb composite layer tribological property Si content
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中国家庭消费的能源环境代价 被引量:12
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作者 李静 刘丽雯 《中国人口·资源与环境》 CSSCI CSCD 北大核心 2017年第12期31-39,共9页
随着经济进入"新常态"模式,居民家庭消费日益成为拉动经济增长的主要动力。如何更好地引导其尽可能地降低对环境的损害效应,是决定经济绿色可持续性发展的关键问题。利用WIOD(世界投入产出数据库)数据,本文通过投入产出分析... 随着经济进入"新常态"模式,居民家庭消费日益成为拉动经济增长的主要动力。如何更好地引导其尽可能地降低对环境的损害效应,是决定经济绿色可持续性发展的关键问题。利用WIOD(世界投入产出数据库)数据,本文通过投入产出分析法测算了2000—2014年中国家庭消费对能源消耗、CO2排放和SO2排放的影响,采用LMDI分解法研究了家庭消费规模、家庭消费结构和效率变化三个因素对其变化的影响,并对中国家庭消费含能(污)量进行脱钩分析。结果表明,2000—2014年,家庭消费含能量和含碳量都呈现增加趋势,其中煤和油是最主要的家庭能源消费品种,而家庭消费含硫量呈现递减趋势;制造业和服务业是家庭消费含能(污)量的主要引致来源;家庭消费含能(污)量的增加主要是家庭消费规模快速增长带来的规模效应引起的,能耗或排污效率的提高带来的效率效应有效地抑制了规模效应,部门家庭消费结构的变动带来的结构效应影响较小;近年来,中国家庭消费含能(污)量与经济增长之间表现出强脱钩状态,反映出经济增长的同时家庭消费引起的能耗和排污有所下降的向好形势。政策含义表明,要有效控制家庭能耗和排污规模,需进一步优化家庭能源消费结构,加快绿色清洁能源消费的转型;以家庭消费含能(污)量的部门分布为突破口,鼓励居民家庭选择消费较为清洁型的制造业产品或环保型的服务;提高消费品关联的产业部门的能源利用效率或污染治理效率,进而倒逼或引导部门结构的可持续性转变。研究对于发展绿色消费、优化能源结构、促进节能减排都具有重要的现实含义。 展开更多
关键词 投入产出模型+家庭消费含能量 家庭消费污量 LMDI+脱钩
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中国省际贸易的能源流动分析 被引量:1
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作者 胡萌 乔晗 赵震 《中国人口·资源与环境》 CSSCI 北大核心 2012年第S1期253-256,共4页
通过编制我国18个省市的非竞争型混合能源投入产出表和构建投入产出模型,测算了省际贸易引发的内含能源流动。研究发现:我国的省际贸易结构不尽合理,主要的高耗能产品流出省并非都具有能源比较优势,而有些具有明显比较优势的省却是内含... 通过编制我国18个省市的非竞争型混合能源投入产出表和构建投入产出模型,测算了省际贸易引发的内含能源流动。研究发现:我国的省际贸易结构不尽合理,主要的高耗能产品流出省并非都具有能源比较优势,而有些具有明显比较优势的省却是内含能源净流入省。我们提出:各省市应更考虑从省际分工和贸易的角度促进节能减排,按能源的比较优势进行省际分工,同时,国家应重视省际生态补偿机制,对按能源比较优势不仅为本省,也为它省生产高耗能产品的省份进行生态补贴以推动基于能源比较优势的省际分工。 展开更多
关键词 省际贸易 非竞争型混合能源投入产出表 贸易含能量 能源比较优势
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Influence of rare earth element erbium on microstructures and properties of as-cast 8030 aluminum alloy
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作者 TANG Hao-qing LI Hong-ying +3 位作者 JIN Dong HU Xiang-hua XU Jing LI Hua-bin 《Journal of Central South University》 CSCD 2024年第11期4027-4038,共12页
The modification behavior of different Er contents on the microstructures and properties of as-cast 8030 aluminum alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM),X-ray diffraction(XR... The modification behavior of different Er contents on the microstructures and properties of as-cast 8030 aluminum alloy was investigated by optical microscopy(OM),scanning electron microscopy(SEM),X-ray diffraction(XRD),energy dispersive spectroscopy(EDS),transmission electron microscopy(TEM),hardness test,electrical conductivity test and tensile property test.The results show that the addition of Er can refine the grains of as-cast alloy,which mainly promotes the nucleation ofα-Al by causing constitutional supercooling and forming the Al 3 Er nanoparticles as a heterogeneous nucleation core.Er can change the morphology of Al-Al_(6) Fe eutectic structure of the alloy,furthermore,Er can adsorb on the surface of the Al_(6) Fe phase to refine the Al_(6) Fe phase in eutectic structure.Er can improve the tensile properties,especially the elongation of as-cast 8030 aluminum alloy,which is attributed to the modification of Al-Al_(6) Fe eutectic and Al_(6) Fe phase. 展开更多
关键词 8030 aluminum alloy Er addition tensile properties microstructure MODIFICATION
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DNTF/CL-20双组元体系热分解特性及机理研究 被引量:1
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作者 周静静 祝艳龙 +5 位作者 黄蒙 安静 周静 蒙君煚 丁黎 常海 《固体火箭技术》 CAS CSCD 北大核心 2023年第6期893-899,共7页
六硝基六氮杂异伍兹烷(CL-20)在3,4-二硝基呋咱基氧化呋咱(DNTF)基熔铸炸药中应用前景广阔,从实验分析和动力学模拟两方面入手,研究了DNTF/CL-20双组元体系(1∶1,质量比)热分解特性及机理。采用高压差示扫描量热(PDSC)技术考察了双组元... 六硝基六氮杂异伍兹烷(CL-20)在3,4-二硝基呋咱基氧化呋咱(DNTF)基熔铸炸药中应用前景广阔,从实验分析和动力学模拟两方面入手,研究了DNTF/CL-20双组元体系(1∶1,质量比)热分解特性及机理。采用高压差示扫描量热(PDSC)技术考察了双组元体系的热分解特性,并通过Kissinger方程得到了其热分解动力学参数;采用同步热分析-红外-质谱(TG/DSC-FTIR-MS)联用技术研究了双组元体系热分解产物的组成及种类,推测了其热分解机理;采用耐驰热动力学软件获得了1.0 MPa下双组元体系的热分解动力学参数。结果表明:DNTF/CL-20双组元体系在1.0 MPa下的热分解过程中,CL-20会因低共熔导致分解峰温降低,产生的气相产物会促进DNTF的分解,进而引起其峰温前移;DNTF/CL-20双组元体系热分解的初始步骤为CL-20中的N—NO_(2)断裂,产生具有催化作用的气相分子,致使其笼状结构裂解,并引起DNTF的呋咱环和氧化呋咱环于N—O键处断裂,最终生成后续生成NO、CO、CO_(2)、N_(2)O、H_(2)O、NH_(3)、NO_(2)等小分子产物。另外,借助动力学模拟验证了对该机理的推测,为DNTF/CL-20双组元体系热分解释能规律的研究提供了理论基础,并对未来CL-20应用于DNTF基熔铸炸药提供了数据参考。 展开更多
关键词 DNTF/CL-20 能量密度能材料 熔铸炸药 热分解 分解机理 动力学模拟
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压力作用下DNTF的热分解动力学及机理研究
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作者 周静静 祝艳龙 +5 位作者 黄蒙 安静 周静 禄旭 丁黎 常海 《固体火箭技术》 CAS CSCD 北大核心 2023年第4期581-587,共7页
为了研究压力对3,4-二硝基呋咱基氧化呋咱(DNTF)热分解的影响机制,从实验测试分析和动力学模拟两方面探究了不同压力下DNTF的热分解特性和分解机理。采用高压差示扫描量热(PDSC)技术在0.1、1.0、2.0、4.0、6.0 MPa下考察了DNTF的热分解... 为了研究压力对3,4-二硝基呋咱基氧化呋咱(DNTF)热分解的影响机制,从实验测试分析和动力学模拟两方面探究了不同压力下DNTF的热分解特性和分解机理。采用高压差示扫描量热(PDSC)技术在0.1、1.0、2.0、4.0、6.0 MPa下考察了DNTF的热分解特性,并通过Kissinger方程得到了其热分解动力学参数;采用同步热分析-红外-质谱(TG/DSC-FTIR-MS)联用技术研究了DNTF的热分解产物组成及种类,推测了DNTF的热分解机理;采用耐驰热动力学软件获得了不同压力下DNTF的热分解动力学参数。结果表明:压力增大时,DNTF的分解峰温会略向高温方向移动,热分解气相产物对凝聚相产物分解的促进作用更加显著;DNTF在热分解过程中环内N—O键先断裂,产生具有催化作用的气态氮氧化物(NO、N_(2)O),经自催化反应使C—NO_(2)键断裂、呋咱环碎片和氧化呋咱环碎片进一步分解,生成CO_(2)、NO、NO_(2)及N_(2)O等气态小分子,并借助动力学模拟验证了对DNTF热分解机理的推测。 展开更多
关键词 DNTF 能量密度能材料 氧化剂 压力 分子动力学模拟 热分解 分解机理
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Effects of minor Zn content on microstructure and corrosion properties of Al-Mg alloy 被引量:4
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作者 赵经纬 罗兵辉 +3 位作者 何克坚 柏振海 李彬 陈维 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第12期3051-3059,共9页
The effects of different Zn contents in Al-Mg alloy on the microstructure characterizations were observed by advanced electron microscopy and the corrosion properties were investigated by the inter-granular corrosion ... The effects of different Zn contents in Al-Mg alloy on the microstructure characterizations were observed by advanced electron microscopy and the corrosion properties were investigated by the inter-granular corrosion tests,the exfoliation corrosion tests,and the Potentiodynamic polarizaion tests.The τ phase(Mg_(32)(Al,Zn)_(49)) forms on the pre-existing Mn-rich particles and at the grain boundaries.According to the theory of binding energy,the formation of τ phase is much easier than that of β phase(Al_3Mg_2),somehow replacing β phase and reducing the possibility of β phase precipitation.This change dramatically decreases the susceptibility of corrosion.The Zn addition increases the corrosion resistance of Al-Mg alloy with an optimal value of 0.31%.When the Zn addition is increased to 0.78%,however,the corrosion resistance of alloy decreases once again but it is still better than that of the alloy without Zn addition. 展开更多
关键词 Al-Mg alloy Zn addition r phase (Mg32 (Al Zn)49 CORROSION
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Effect of magnetite content on Bond work index and preconditioning: Case study on Chadormalu iron ore mine
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作者 Hossein INANLOO ARABI SHAD F SERESHKI +1 位作者 M ATAEI M KARAMOOZIAN 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第4期795-804,共10页
Grinding is one of the most costly operations in the mechanical breaking and mining.Determination of the breakage characteristics and preconditioning is important to increase the grinding efficiency.Investigations of ... Grinding is one of the most costly operations in the mechanical breaking and mining.Determination of the breakage characteristics and preconditioning is important to increase the grinding efficiency.Investigations of the seismic,mechanical and breakage properties of iron oxides are very important parameters for investigating the rock fragmentation by blasting and comminution processes in iron ore mines.In this paper,at first,geomechanical and seismic properties of the oxide ores(magnetite and hematite)in the Chadormalu iron ore mine were studied.The results showed that the percentage of magnetite has a direct relationship with uniaxial compressive strength,tensile strength and P and S wave’s velocities and has an inverse relationship with Poisson ratio and porosity.Moreover,to study breakage and preconditioning characteristics in the iron ores,two samples with different magnetite percents were blasted by detonation cord.The results showed that with higher percentage of magnetite,the number of fractures induced by blasting increased.Bond work index and magnetite percent were investigated in the 430 blasts in the mine.This investigation not only confirmed the small scale blasting results,but also showed that increasing the magnetite percent up to 50%noticeably reduces Bond work index and energy consumption in the grinding process.Also,the relationship between muck pile fragmentation and magnetite percentage were studied for several blasts that had the same blast pattern parameters and similar geology conditions.These results also confirmed precedents conclusions regarding magnetite percent and preconditioning relationship. 展开更多
关键词 iron oxides geomchanical parameter PRECONDITIONING magnetite percent energy consumption
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Reduction of Panzhihua titanium-bearing oxidized pellets by CO-N_2-H_2 gas
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作者 张建良 郑常乐 +1 位作者 汤云腾 柴轶凡 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第5期1015-1022,共8页
The effect of H_2 gas content on the reduction of Panzhihua titanomagnetite concentrate pellets by carbon monoxide was investigated by isothermal reduction experiment using CO-N_2-H_2 gas mixtures in a vertical electr... The effect of H_2 gas content on the reduction of Panzhihua titanomagnetite concentrate pellets by carbon monoxide was investigated by isothermal reduction experiment using CO-N_2-H_2 gas mixtures in a vertical electric resistance furnace.The morphology and phase transformation of reduced samples obtained were detected by scanning electron microscopy,energy disperse spectroscopy analysis and X-ray diffractometry respectively.The results show that increasing H_2 content will enhance the initial stage of reduction rate apparently.There are two reasons responsible for this effect,one is that H_2 accelerates the chemical reaction,and the other is that the addition of H_2 gas can improve the porosity of pellet intensively.It is noteworthy that this effect is more obvious when the reduction temperature reaches 1473 K with sticking phenomenon happening.There are no crystalline phases which can be found such as ulvospinle,ilmenite,ferrous-pseudobrookite and any titanium oxide except titanomagnetite(TTM).The reduction progress is suggested as follows:1) Fe_2O_3→Fe_3O_4→FeO→Fe;2) Fe_2TiO_5→Fe_2TiO_4+Fe_3O_4→TTM.Element Al migrates and gets enriched in high titanium content iron ores,and eventually Al to Ti molar ratio is 1:3.Al is likely to dissolve in titanium iron oxides to form a kind of composite iron compound,which results in the restrain of reduction. 展开更多
关键词 titanomagnetite pellet carbon monoxide hydrogen REDUCTION blast furnace
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An improved joint method for onset picking of acoustic emission signals with noise 被引量:5
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作者 ZHOU Zi-long CHENG Rui-shan +2 位作者 CHEN Lian-jun ZHOU Jing CAI Xin 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第10期2878-2890,共13页
The onset times of acoustic signals with spikes,heavy bodies and unclear takeoffs are difficult to be picked accurately by the automatic method at present.To deal with this problem,an improved joint method based on th... The onset times of acoustic signals with spikes,heavy bodies and unclear takeoffs are difficult to be picked accurately by the automatic method at present.To deal with this problem,an improved joint method based on the discrete wavelet transform(DWT),modified energy ratio(MER)and Akaike information criterion(AIC)pickers,has been proposed in this study.First,the DWT is used to decompose the signal into various components.Then,the joint application of MER and AIC pickers is carried out to pick the initial onset times of all selected components,where the minimum AIC position ahead of MER onset time is regarded as the initial onset time.Last,the average for initial onset times of all selected components is calculated as the final onset time of this signal.This improved joint method is tested and validated by the acoustic signals with different signal to noise ratios(SNRs)and waveforms.The results show that the improved joint method is not affected by the variations of SNR,and the onset times picked by this method are always accurate in different SNRs.Moreover,the onset times of all acoustic signals with spikes,heavy bodies and unclear takeoffs can be accurately picked by the improved joint method.Compared to some other methods including MER,AIC,DWT-MER and DWT-AIC,the improved joint method has better SNR stabilities and waveform adaptabilities. 展开更多
关键词 Akaike information criterion(AIC) modified energy ratio(MER) discrete wavelet transform(DWT) acoustic signals with noise
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Elevated-temperature mechanical properties and thermal stability of Al-Cu-Mg-Ag heat-resistant alloy 被引量:3
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作者 宋艳芳 潘清林 +2 位作者 王迎 李晨 丰雷 《Journal of Central South University》 SCIE EI CAS 2014年第9期3434-3441,共8页
The elevated-temperature mechanical properties and thermal stability of Al-Cu-Mg-Ag heat-resistant alloy were studied by tensile test, transmission electron microscopy(TEM) and scanning electron microscopy(SEM), respe... The elevated-temperature mechanical properties and thermal stability of Al-Cu-Mg-Ag heat-resistant alloy were studied by tensile test, transmission electron microscopy(TEM) and scanning electron microscopy(SEM), respectively. The results show that with the increase of Ag content, the tensile strength and yield strength increase, which is attributed to the increase of the precipitations number and the decrease of the size. The same conclusions are drawn in the study of increasing Mg content. The alloy possesses excellent thermal stability. At 100-150 °C, the strength of the under-aged alloy increases at the initial stage, and after reaching the peak strength, it remains the same. The secondary precipitation of the under-aged alloy occurs in the process of exposure at 150℃, and it distributes diffusely after thermal exposed for 20 h. Then, the tensile strength decreases gradually with increasing the thermal exposure time at 200-250 °C. The strength of the peak-aged alloy decreases gradually, and the precipitation grows up, but the number decreases gradually with prolonging the exposure time at 100-250 °C. The strength of two kinds of alloys decreases with elevating of exposure temperature. 展开更多
关键词 evaluated-temperature mechanical properties thermal stability A1-Cu-Mg-Ag alloy
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Microstructure and microwave dielectric properties of lead borosilicate glass ceramics with Al_2O_3 被引量:4
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作者 韦鹏飞 周洪庆 +2 位作者 王杰 张一源 曾凤 《Journal of Central South University》 SCIE EI CAS 2011年第6期1838-1843,共6页
The effects of Al2O3 addition on both the sintering behavior and microwave dielectric properties of PbO-B203-SiO2 glass ceramics were investigated by Fourier transform infrared spectroscope (FTIR), differential ther... The effects of Al2O3 addition on both the sintering behavior and microwave dielectric properties of PbO-B203-SiO2 glass ceramics were investigated by Fourier transform infrared spectroscope (FTIR), differential thermal analysis (DTA), X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results show that with the increase of Al2O3 content the bands assigned to [SiO4] nearly disappear. Aluminum replaces silicon in the glass network, which is helpful for the formation of boron-oxygen rings. The increase of the transition temperature Tg and softening temperature Tf of PbO-B2O3-SiO2 glass ceramics leads to the increase of liquid phase precipitation temperature and promotes the structure stability in the glasses, and consequently contributes to the decreasing trend of crystallization. Densification and dielectric constants increase with the increase of Al2O3 content, but the dielectric loss is worsened. By contrast, the 3% (mass fraction) Al2O3-doped glass ceramics sintered at 725℃ have better properties of density p=2.72 g/cm3, dielectric constant Er=6.78, dielectric loss tan8=2.6×10^-3 (measured at 9.8 GHz), which suggest that the glass ceramics can be applied in multilayer microwave devices requiring low sintering temperatures. 展开更多
关键词 PbO-B203-SiO2 glass ceramics AL2O3 Fourier transform infrared spectroscope MICROSTRUCTURE dielectric properties
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多硝基3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷的合成与性能 被引量:2
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作者 杨童童 刘洋 +2 位作者 侯晓文 孟子晖 徐志斌 《含能材料》 EI CAS CSCD 北大核心 2020年第7期657-663,I0008,共8页
为了探索三氟甲基对含能材料性能的影响,以偕二氨基六氟丙烷和乙二醛为原料构建了氮杂稠环类含能材料的硝化前体——3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷,通过改进的合成路线,用发烟硝酸多步硝化分别得到2,6-二硝基-3,3... 为了探索三氟甲基对含能材料性能的影响,以偕二氨基六氟丙烷和乙二醛为原料构建了氮杂稠环类含能材料的硝化前体——3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷,通过改进的合成路线,用发烟硝酸多步硝化分别得到2,6-二硝基-3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷(4)、2,4,6-三硝基-3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷(5)和2,4,6,8-四硝基6-3,3,7,7-四(三氟甲基)-2,4,6,8-四氮杂双环[3.3.0]辛烷(6)。利用核磁共振氢谱、碳谱和氮谱表征了产物结构;采用排惰性气体法测试了三种硝化产物的密度,其中6的密度最大,高达2.08 g·cm^-3;分别用落锤升降法和BAM法测得三种产物的撞击感度均大于30 J、摩擦感度均大于360 N;热重-微商热重(TG-DTG)分析发现三种产物的质量损失均大于90%,其热稳定性随硝基的增加而下降;利用Gaussian 09计算包,通过Monte-Carlo统计学方法以及Kamlet-Jacbos方程和VLW爆轰产物状态方程等理论模型预估了产物的爆速、爆压,其中化合物6的爆速为11937 m·s^-1,爆压为74.3 GPa。与四硝基甘脲(TNGU)的性能及感度对比发现,在含能材料的分子结构中引入具有更高密度和更大电负性的三氟甲基,可在维持较高密度和良好爆轰性能的同时降低感度。 展开更多
关键词 能量密度化合物 能材料 偕二氨基六氟丙烷 氮杂环 2 4 6 8-四硝基3 3 7 7-四(三氟甲基)-2 4 6 8-四氮杂双环[3.3.0]辛烷
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Synthesis of modified polyacrylamide with high content of hydroxamate groups and settling performance of red mud 被引量:2
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作者 刘锦伟 胡慧萍 +3 位作者 王梦 陈湘攀 陈启元 丁治英 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第6期2073-2080,共8页
Hydroxamated polyacrylamide(HPAM) was synthesized from polyacrylamide(PAM) with high relative molecular mass under the optimum reaction conditions(p H 12 and a molar ratio of hydroxylamine to amide groups of 1.5 ... Hydroxamated polyacrylamide(HPAM) was synthesized from polyacrylamide(PAM) with high relative molecular mass under the optimum reaction conditions(p H 12 and a molar ratio of hydroxylamine to amide groups of 1.5 at 50 ℃for 12 h). The hydroxamate groups of HPAM were verified by Fourier transform infrared spectrum(FT-IR). 46%(molar fration) hydroxamate groups and 23%(molar fraction) carbonyl groups on HPAM were determined by conductometric titration combined with Kjeldahl's microanalysis method. The settling performance achieved at different flocculant dosages was investigated with high goethite-containing red mud slurry of simulated Bayer process synthesized in laboratory. It turns out that the settling performance of high goethite-containing red mud was better with HPAM. The average settling rate of red mud in the first 5 min and the turbidity of supernatant after settling for 30 min are 2.36 m/h and 507 NTU, respectively, at a flocculant dosage of 120 g/t, which is similar to that achieved with Hx-600. 展开更多
关键词 hydroxamated polyacrylamide symhesis red mud settling performance
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Microstructure and dielectric properties of Ca-Al-B-Si-O glass/Al_2O_3 composites with various alkali oxides contents 被引量:1
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作者 刘明 周洪庆 +2 位作者 朱海奎 岳振星 赵建新 《Journal of Central South University》 SCIE EI CAS 2012年第10期2733-2739,共7页
The effects of alkali oxides (Na2O and K2O addition on both the sintering behavior and dielectric properties of Ca-AI-B-Si-O glass/Al2O3 composites were investigated by Fourier transform infrared spectroscopy (FTIR... The effects of alkali oxides (Na2O and K2O addition on both the sintering behavior and dielectric properties of Ca-AI-B-Si-O glass/Al2O3 composites were investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). The results show that the increasing amount of alkali oxides in the glass causes the decrease of [SiO4], which results in the decrease of the continuity of glass network, and leads to the decrease of the softening temperature Tf of the samples and the increasing trend of crystallization. And that deduces corresponding rise of densification, dielectric constant, dielectric loss of the low temperature co-fired ceramic (LTCC) materials and the decrease of its thermal conductivity. By contrast, the borosilicate glass/A1203 composites with 1.5% (mass fraction) alkali oxides sintered at 875 ℃ for 30 rain exhibit better properties of a bulk density of 2.79 g/cm3, a porosity of 0.48%, a 2 value of 2.28 W/(m.K), a er value of 7.82 and a tand value of 9.1 × 10-4 (measured at 10 MHz). 展开更多
关键词 borosilicate glass alkali oxides Ca-AI-B-Si-O glass AL2O3 MICROSTRUCTURE thermal properties dielectric properties
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