Power generation is one of the most essential functions of any plant for continuous functioning without any interruption. A marine power plant (MPP) is the same section. In the present paper, the authors have tried ...Power generation is one of the most essential functions of any plant for continuous functioning without any interruption. A marine power plant (MPP) is the same section. In the present paper, the authors have tried to find the various reliability characteristics of an MPR A marine power plant which is a composition of two generators and in which one of them is located at the stern and another at the bow, both associated to the main switchboard (MSB). The distribution switchboards (DSB) receive power from the MSB through cables and their respective junctions. Given that arrangement, a working based transition state diagram has been generated. With the help of the Markov process, a number of intro-differential equations are formed and solved by Laplace transform. Various reliability characteristics are calculated and discussed with the help of graphs.展开更多
The basic-nitrogen aromatic compounds in feedstocks and liquid products from the micro-reactor and soluble components of coke obtained during fluid catalytic cracking (FCC) process were analyzed by the micro-electro...The basic-nitrogen aromatic compounds in feedstocks and liquid products from the micro-reactor and soluble components of coke obtained during fluid catalytic cracking (FCC) process were analyzed by the micro-electrospray ioniza- tion (ESI) 9.4T Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) with an average mass resolving power of 300 000 at a mass range of 100--1 200. The analytical results revealed that the coker gas oil (CGO) contained a higher abundance of basic-nitrogen aromatic compounds with the type of-SN to -9N compared with those in deasphalted oil (DAO) and mixed FCC feedstock. After catalytic cracking, the abundance of lowly condensed basic-nitrogen aromatic compounds was much less than those of highly condensed aromatics in the liquid products, with the carbon number mainly ranging from 6 to 25 and the average carbon number of the side-chains equating to 1--5. On the contrary, with respect to the soluble components of coke, the abundance of lowly condensed basic-nitrogen aromatic compounds was more than those of highly condensed aromatics, and the carbon number ranged from 12 to 30, which was much smaller than that of the mixed FCC feedstock but slightly larger than that of the cracked liquid products. These results have provided some fundamental information on FCC process.展开更多
The time evolution of coal structure during low temperature oxidation was investigated by oxidizing coal samples in air at 120℃ for periods of up to 14 days. The structure of the oxidized coal samples was char- acter...The time evolution of coal structure during low temperature oxidation was investigated by oxidizing coal samples in air at 120℃ for periods of up to 14 days. The structure of the oxidized coal samples was char- acterized by Fourier transform infrared spectroscopy (FFIR) and curve fitting analysis. The results show that carboxyl and ether groups are the main oxygen containing moieties in oxidized coal. Ethers are most abundant during the first 3 days of oxidation, thereafter carboxyl groups predominate. The content of carboxyl and ester functionality increases with oxidation time. The other oxygen containing groups vary in concentration over time. The amount of hydroxyl groups first decreases then increases and finally decrease again during the oxidation. The aliphatic structure and the degree of branching of the aliphatic chains is reduced as the oxidation proceeds. The proportion of aromatic structure increases with oxida- tion time. Obvious decomposition of aromatic rings occurs after about 9 days of oxidation. The aryl ester bands and the CH3/CH2 ratio both have a good linear relationship to oxidation time.展开更多
文摘Power generation is one of the most essential functions of any plant for continuous functioning without any interruption. A marine power plant (MPP) is the same section. In the present paper, the authors have tried to find the various reliability characteristics of an MPR A marine power plant which is a composition of two generators and in which one of them is located at the stern and another at the bow, both associated to the main switchboard (MSB). The distribution switchboards (DSB) receive power from the MSB through cables and their respective junctions. Given that arrangement, a working based transition state diagram has been generated. With the help of the Markov process, a number of intro-differential equations are formed and solved by Laplace transform. Various reliability characteristics are calculated and discussed with the help of graphs.
基金supported by the National Basic Research Program of China (2010CB226901)
文摘The basic-nitrogen aromatic compounds in feedstocks and liquid products from the micro-reactor and soluble components of coke obtained during fluid catalytic cracking (FCC) process were analyzed by the micro-electrospray ioniza- tion (ESI) 9.4T Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) with an average mass resolving power of 300 000 at a mass range of 100--1 200. The analytical results revealed that the coker gas oil (CGO) contained a higher abundance of basic-nitrogen aromatic compounds with the type of-SN to -9N compared with those in deasphalted oil (DAO) and mixed FCC feedstock. After catalytic cracking, the abundance of lowly condensed basic-nitrogen aromatic compounds was much less than those of highly condensed aromatics in the liquid products, with the carbon number mainly ranging from 6 to 25 and the average carbon number of the side-chains equating to 1--5. On the contrary, with respect to the soluble components of coke, the abundance of lowly condensed basic-nitrogen aromatic compounds was more than those of highly condensed aromatics, and the carbon number ranged from 12 to 30, which was much smaller than that of the mixed FCC feedstock but slightly larger than that of the cracked liquid products. These results have provided some fundamental information on FCC process.
基金supported by the Shaanxi Provincial Project of Special Foundation of Key Disciplinesthe Scientific Research Program Funded by Shaanxi Provincial Education Commission (No. 09JK583)the Seed Fund of Xi’an University of Science and Technology (No. 200745)
文摘The time evolution of coal structure during low temperature oxidation was investigated by oxidizing coal samples in air at 120℃ for periods of up to 14 days. The structure of the oxidized coal samples was char- acterized by Fourier transform infrared spectroscopy (FFIR) and curve fitting analysis. The results show that carboxyl and ether groups are the main oxygen containing moieties in oxidized coal. Ethers are most abundant during the first 3 days of oxidation, thereafter carboxyl groups predominate. The content of carboxyl and ester functionality increases with oxidation time. The other oxygen containing groups vary in concentration over time. The amount of hydroxyl groups first decreases then increases and finally decrease again during the oxidation. The aliphatic structure and the degree of branching of the aliphatic chains is reduced as the oxidation proceeds. The proportion of aromatic structure increases with oxida- tion time. Obvious decomposition of aromatic rings occurs after about 9 days of oxidation. The aryl ester bands and the CH3/CH2 ratio both have a good linear relationship to oxidation time.