The properties and thickness of the bubbles in the froth control the flotation process. There is no work showing how to measure bubble film composition and thickness by a straightforward manner. In this work, a novel ...The properties and thickness of the bubbles in the froth control the flotation process. There is no work showing how to measure bubble film composition and thickness by a straightforward manner. In this work, a novel approach, a custom-designed bubble cell associated with layer interferometry(in the UV-vis region) and FT-IR spectroscopy was used to investigate the effect of solid particle type(hydrophilic vs hydrophobic), concentration and bubble diameter on stability of a bubble blown in air. Stability was quantified by measuring bubble lifetime and hydrated film thickness. Kerosene with silicone oil as a foaming agent was used to evaluate the impact of bubble diameter(test series I). Frother solutions(MIBC, Dowfroth 250, Hexanol and F-150) were used for the solid type concentration experiments(test series II). In the first series of experiments, it was determined that as the diameter of a bubble increased from 10 to 25 mm, so did the hydrated film thickness from 350 to 1000 nm. In the second series, as the silica concentration increased(0 to 10%), an increase in bubble lifetime and hydrated film thickness was resulted(130%-250%). An impact of solid hydrophobicity was found but to a lesser degree than expected. It is possible that the small particle size(<0.1 m) of silica was responsible for this behavior. The findings are used to interpret the effect of solids in flotation froth.展开更多
Y_(3)Al_(2)Ga_(3)O_(12):Ce^(3+),Cr^(3+)(YAGG:Ce^(3+),Cr^(3+)),as a persistent luminescent material,has advantages of high initial luminescence intensity and long persistent time,which is promising in persistent lumine...Y_(3)Al_(2)Ga_(3)O_(12):Ce^(3+),Cr^(3+)(YAGG:Ce^(3+),Cr^(3+)),as a persistent luminescent material,has advantages of high initial luminescence intensity and long persistent time,which is promising in persistent luminescent material applications.At present,YAGG:Ce^(3+),Cr^(3+)powders exhibit good persistent performance,but their persistent performance of ceramics still needs to be further improved to meet the new requirements.In this work,(Y_(0.998)Ce_(0.002))_(3)(Al_(1-x)Cr_(x))_(2)Ga_(3)O_(12)ceramics with different Cr^(3+)doping concentrations were prepared by solid-state reaction,including air pre-sintering,hot isostatic pressing(HIP)post-treatment and air annealing,to investigate the effects of Cr^(3+)doping concentration on the microstructure,optical properties and persistent performance of the ceramics.The results showed that as the doping concentration of Cr^(3+)increased from 0.025%to 0.2%(in atom),no significant effect of Cr^(3+)concentration on the morphology of pre-sintered ceramics or HIP post-treatment ceramics was observed,but the in-line transmittance gradually increased while the persistent performance gradually decreased.Among them,YAGG:Ce^(3+),Cr^(3+)ceramics doped with 0.025%Cr^(3+)showed the strongest initial luminescence intensity exceeding 6055 mcd/m^(2)and a persistent time of 1030 min after air pre-sintering combined with HIP post-treatment and air annealing.By optimizing the Cr^(3+)doping concentration and the fabrication process,the persistent luminescence(PersL)performance of the YAGG:Ce^(3+),Cr^(3+)ceramics was obviously improved.展开更多
基金Project(2013BAB14B05)supported by National Key Technology Research and Development Program of the Ministry of Science and Technology of China
文摘The properties and thickness of the bubbles in the froth control the flotation process. There is no work showing how to measure bubble film composition and thickness by a straightforward manner. In this work, a novel approach, a custom-designed bubble cell associated with layer interferometry(in the UV-vis region) and FT-IR spectroscopy was used to investigate the effect of solid particle type(hydrophilic vs hydrophobic), concentration and bubble diameter on stability of a bubble blown in air. Stability was quantified by measuring bubble lifetime and hydrated film thickness. Kerosene with silicone oil as a foaming agent was used to evaluate the impact of bubble diameter(test series I). Frother solutions(MIBC, Dowfroth 250, Hexanol and F-150) were used for the solid type concentration experiments(test series II). In the first series of experiments, it was determined that as the diameter of a bubble increased from 10 to 25 mm, so did the hydrated film thickness from 350 to 1000 nm. In the second series, as the silica concentration increased(0 to 10%), an increase in bubble lifetime and hydrated film thickness was resulted(130%-250%). An impact of solid hydrophobicity was found but to a lesser degree than expected. It is possible that the small particle size(<0.1 m) of silica was responsible for this behavior. The findings are used to interpret the effect of solids in flotation froth.
基金National Key R&D Program of China(2023YFB3506600)。
文摘Y_(3)Al_(2)Ga_(3)O_(12):Ce^(3+),Cr^(3+)(YAGG:Ce^(3+),Cr^(3+)),as a persistent luminescent material,has advantages of high initial luminescence intensity and long persistent time,which is promising in persistent luminescent material applications.At present,YAGG:Ce^(3+),Cr^(3+)powders exhibit good persistent performance,but their persistent performance of ceramics still needs to be further improved to meet the new requirements.In this work,(Y_(0.998)Ce_(0.002))_(3)(Al_(1-x)Cr_(x))_(2)Ga_(3)O_(12)ceramics with different Cr^(3+)doping concentrations were prepared by solid-state reaction,including air pre-sintering,hot isostatic pressing(HIP)post-treatment and air annealing,to investigate the effects of Cr^(3+)doping concentration on the microstructure,optical properties and persistent performance of the ceramics.The results showed that as the doping concentration of Cr^(3+)increased from 0.025%to 0.2%(in atom),no significant effect of Cr^(3+)concentration on the morphology of pre-sintered ceramics or HIP post-treatment ceramics was observed,but the in-line transmittance gradually increased while the persistent performance gradually decreased.Among them,YAGG:Ce^(3+),Cr^(3+)ceramics doped with 0.025%Cr^(3+)showed the strongest initial luminescence intensity exceeding 6055 mcd/m^(2)and a persistent time of 1030 min after air pre-sintering combined with HIP post-treatment and air annealing.By optimizing the Cr^(3+)doping concentration and the fabrication process,the persistent luminescence(PersL)performance of the YAGG:Ce^(3+),Cr^(3+)ceramics was obviously improved.
