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光响应性偶氮聚电解质自组装研究 被引量:16
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作者 庹新林 陈峥 +2 位作者 吴立峰 王晓工 刘德山 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2001年第2期329-333,共5页
将 3种侧链带有不同偶氮生色团的聚电解质 ,用逐层浸渍的方法使其组装成多层膜 .利用原子力显微镜 (AFM)研究了自组装膜的表面形貌以及随着组装层数增加的变化 .详细研究了在紫外光的照射下 ,薄膜内偶氮生色团由反式到顺式构型的光响应... 将 3种侧链带有不同偶氮生色团的聚电解质 ,用逐层浸渍的方法使其组装成多层膜 .利用原子力显微镜 (AFM)研究了自组装膜的表面形貌以及随着组装层数增加的变化 .详细研究了在紫外光的照射下 ,薄膜内偶氮生色团由反式到顺式构型的光响应转变 ,以及在暗室中由顺式回复到反式构型的回复特性 .与自组装膜的光响应性和相应的旋涂膜进行比较发现 ,其中的PNAPE/PDAC自组装膜没有明显的光色效应 ,而PEAPE/PDAC ,PPAPE/PDAC具有明显的光色效应 .在暗室中 ,随生色团的结构不同和在不同的凝集态中 ,由顺式回复到反式构型的速率明显不同 . 展开更多
关键词 偶氮聚电解质 自组装膜 顺反异构 光响应性 原子力量微镜 表面形貌
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Sensorless control for hysteresis compensation of AFM scanner by modified Rayleigh model
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作者 PARK J K MOON W K 《Journal of Central South University》 SCIE EI CAS 2010年第6期1243-1246,共4页
A novel modified Rayleigh model was developed for compensating hysteresis problem of an atomic force microscope(AFM) scanner.In high driving fields,piezoelectric actuators that integrated a scanner have severe hystere... A novel modified Rayleigh model was developed for compensating hysteresis problem of an atomic force microscope(AFM) scanner.In high driving fields,piezoelectric actuators that integrated a scanner have severe hysteresis,which can cause serious displacement errors.Piezoelectric hysteresis is from various origins including movement of defects,grain boundary effects,and displacement of interfaces.Furthermore,because its characteristic is stochastic,it is almost impossible to predict the piezoelectric hysteresis analytically.Therefore,it was predicted phenomenologically,which means that the relationship between inputs and outputs is formulated.The typical phenomenological approach is the Rayleigh model.However,the model has the discrepancy with experiment result as the fields increase.To overcome the demerit of the Rayleigh model,a modified Rayleigh model was proposed.In the modified Rayleigh model,each coefficient should be defined differently according to the field direction due to the increase of the asymmetry in the high fields.By applying an inverse form of this modified Rayleigh model to an AFM scanner,it is proved that hysteresis can be compensated to a position error of less than 5%.This model has the merits of reducing complicated fitting procedures and saving computation time compared with the Preisach model. 展开更多
关键词 piezoelectric stack actuator hysteresis compensation Rayleigh model atomic force microscopy
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