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Ti6Al4V合金激光原位合成自润滑复合涂层高温摩擦学性能 被引量:13
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作者 周仲炎 庄宿国 +4 位作者 杨霞辉 王勉 罗迎社 刘煜 刘秀波 《材料工程》 EI CAS CSCD 北大核心 2019年第3期101-108,共8页
为提高Ti6Al4V合金的高温摩擦学性能,采用激光熔覆技术在其表面原位合成多相混杂金属基高温自润滑耐磨复合涂层,熔覆粉末的成分为Ni60-16.8%TiC-23.2%WS_2(质量分数,下同),系统地研究复合涂层的显微组织、物相结构及其在20,300,600,800... 为提高Ti6Al4V合金的高温摩擦学性能,采用激光熔覆技术在其表面原位合成多相混杂金属基高温自润滑耐磨复合涂层,熔覆粉末的成分为Ni60-16.8%TiC-23.2%WS_2(质量分数,下同),系统地研究复合涂层的显微组织、物相结构及其在20,300,600,800℃下的摩擦学性能和相关磨损机理。结果表明:复合涂层的显微硬度(701.88HV_(0.5))约为基体(350 HV_(0.5))的2倍;由于原位合成固体润滑相(Ti_2SC/TiS/NiS/TiO/TiO_2/NiCr_2O_4/Cr_2O_3)和硬质相(W,Ti)C_(1-x)/TiC/Cr_7C_3的协同作用,复合涂层的耐磨减摩性能明显优于基体。随着温度升高,涂层和基体的摩擦因数和磨损率均呈下降趋势,在800℃时复合涂层和基体的摩擦因数分别为0.32和0.43,磨损率分别为1.80×10^(-4),2.92×10^(-5)mm/Nm。在800℃下塑性变形、分层和氧化磨损为基体主要磨损机理,复合涂层以氧化磨损和轻微的黏着磨损为主。 展开更多
关键词 激光熔覆 TI6AL4V 高温耐磨复涂层 固体润滑 原位合
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煤矸石质硅铝基胶凝材料的试验研究 被引量:33
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作者 李化建 孙恒虎 肖雪军 《煤炭学报》 EI CAS CSCD 北大核心 2005年第6期778-782,共5页
为提高煤矸石的综合利用率,以500℃煅烧的煤矸石为主体原料,附以改性硅酸钠溶液为成岩剂,研制煤矸石质硅铝基胶凝材料.利用煤矸石与矿渣、粉煤灰之间的协同效应在常规条件下制备出强度持续增长(62.10 MPa,3 d;93.15 MPa,90 d)、施工性... 为提高煤矸石的综合利用率,以500℃煅烧的煤矸石为主体原料,附以改性硅酸钠溶液为成岩剂,研制煤矸石质硅铝基胶凝材料.利用煤矸石与矿渣、粉煤灰之间的协同效应在常规条件下制备出强度持续增长(62.10 MPa,3 d;93.15 MPa,90 d)、施工性能良好的胶凝材料.通过X射线衍射、IR和MAS NMR对全煤矸石硅铝基胶凝材料进行研究,煤矸石质硅铝基胶凝材料在水化前后Si,A l价键和配位发生了改变,表征有水化产物生成,进一步验证水化产物有水白云母、C-S-H凝胶和类沸石无定性铝硅酸盐凝胶.根据煤矸石硅铝基胶凝材料的特征提出了原位键合的水化机理. 展开更多
关键词 煤矸石 煤矸石质硅铝基胶凝材料 协同效应 原位
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Effects of two modification methods on the mechanical properties of wood flour/recycled plastic blends composites: addition of thermoplastic elastomer SEBS-g-MAH and in-situ grafting MAH 被引量:2
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作者 宋永明 王清文 +2 位作者 韩广平 王海刚 高华 《Journal of Forestry Research》 SCIE CAS CSCD 2010年第3期373-378,399,400,共8页
The effect of maleic anhydride grafted styrene-ethylene- buty-lene-styrene block copolymer (SEBS-g-MAH) and in-situ grafting MAH on mechanical, dynamic mechanical properties of wood flour/recycled plastic blends com... The effect of maleic anhydride grafted styrene-ethylene- buty-lene-styrene block copolymer (SEBS-g-MAH) and in-situ grafting MAH on mechanical, dynamic mechanical properties of wood flour/recycled plastic blends composites was investigated. Recycled plastic polypro-pylene (PP), high-density polyethylene (HDPE) and polystyrene (PS), were mixed with wood flour in a high speed blender and then extruded by a twin/single screw tandem extruder system to form wood flour/recycled plastic blends composites. Results show that the impact properties of the composites were improved more significantly by using SEBS-g-MAH compatibilizer than by using the mixtures of MAH and DCP via reactive blending in situ. However, contrary results were ob-served on the tensile and flexural properties of the corresponding com-posites. In General, the mechanical properties of composites made from recycled plastic blends were inferior to those made from virgin plastic blends, especially in elongation break. The morphological study verified that the interfacial adhesion or the compatibility of plastic blends with wood flour was improved by adding SEBS-g-MAH or in-situ grafting MAH. A better interfacial bonding between PP, HDPE, PS and wood flour was obtained by in-situ grafting MAH than the addition of SEBS-g-MAH. In-situ grafting MAH can be considered as a potential way of increasing the interfacial compatibility between plastic blends and wood flour. The storage modulus and damping factor of composites were also characterized through dynamic mechanical analysis (DMA). 展开更多
关键词 COMPATIBILIZER COMPOSITES in-situ grafting recycled plastic blends wood flour
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Selection of Chelated Fe(Ⅲ)/Fe(Ⅱ) Catalytic Oxidation Agents for Desulfurization Based on Iron Complexation Method 被引量:5
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作者 Luo Ying Liu Youzhi +2 位作者 Qi Guisheng Guo Huidong Zhu Zhengfeng 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2014年第2期50-58,共9页
Optimization of factors influencing the experiments on reactions involving 8 different chelating agents and soluble Fe(III)/Fe(II) salts was carried out to yield chelated iron complexes. A combination of optimized inf... Optimization of factors influencing the experiments on reactions involving 8 different chelating agents and soluble Fe(III)/Fe(II) salts was carried out to yield chelated iron complexes. A combination of optimized influencing factors has resulted in a Fe chelating capacity of the iron-based desulfurization solution to be equal to 6.83—13.56 g/L at a redox potential of 0.185—0.3. The desulfurization performance of Fe(III)/Fe(II) chelating agents was investigated on a simulated sulfur-containing industrial gas composed of H2 S and N2 in a cross-flow rotating packed bed. Test results have revealed that the proposed iron-based desulfurization solution showed a sulfur removal efficiency of over 99% along with a Fe chelating capacity exceeding 1.35 g/L. This desulfurization technology which has practical application prospect is currently in the phase of commercial scale-up study. 展开更多
关键词 hydrogen sulfide chelated iron catalytic oxidation factor analysis redox
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DNA TYPING SYSTEM FOR HLA-A2 ALLELES BY POLYMERASE CHAIN REACTION WITH SEQUENCE- SPECIFIC PRIMERS 被引量:1
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作者 张庆瑞 翟宁 +1 位作者 耿龙 宋芳吉 《Chinese Medical Sciences Journal》 CAS CSCD 2001年第3期161-164,共4页
Objective. To establish a PCR- SSP method for discriminating as many HLA- A* 02 alleles, which could easily be introduced into a routine laboratory. Methods. In this study we typed HLA- A* 02 polymorphisms by a sequen... Objective. To establish a PCR- SSP method for discriminating as many HLA- A* 02 alleles, which could easily be introduced into a routine laboratory. Methods. In this study we typed HLA- A* 02 polymorphisms by a sequence- specific primer (SSP) method, which involved round 1 and round 2 PCR reactions to detect 17 HLA- A* 02 alleles (they are HLA- A* 0201- 0217 alleles) covering exon 2 and exon 3. Results. We have found that DNA sample concentration and purity were the most important variables in determining the quality of the results. For identifying correct band size, the size marker used was important. We noticed that different PCR machines performed differently. By this method, we detected 20 HLA- A* 02 positive genomic DNA samples and found 4 kinds of HLA- A* 02 alleles. They were HLA- A* 0201, 0203, 0206 and 0210. Conclusion. The HLA- A* 02 PCR- SSP method was proven to be a reliable and easily applicable typing method. Our results suggest that the SSP described here provides an optimal HLA- A* 02 typing technique that may be useful in selecting donor- recipient pairs in bone marrow transplantation between unrelated individuals. 展开更多
关键词 DNA typing PCR- SSP HLA- A* 02 alleles
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