Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)an...Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.展开更多
An active protection coating for pH-responsive was prepared.The hollow mesoporous silica microspheres(HMSNs)were loaded with 2-mercaptobenzothiazole(MBT),and then they were coated with chitosan(CS).The composite micro...An active protection coating for pH-responsive was prepared.The hollow mesoporous silica microspheres(HMSNs)were loaded with 2-mercaptobenzothiazole(MBT),and then they were coated with chitosan(CS).The composite microspheres were in the range of 650−750 nm in diameter.CS-HMSN-MBT coating had a faster repair rate under acidic conditions by synergistic effect between CS and MBT.The repair rate under alkaline conditions was slowed down.The active protection performance reached the strongest after 3 d immersion.The corrosion inhibitor release mechanism was optimized to extend the service life of the coating and to achieve long-term service of the copper substrate.展开更多
In order to improve the data transmission reliability of mobile ad hoc network, a routing scheme called integrated forward error correction multipath routing protocol was proposed, which integrates the techniques of p...In order to improve the data transmission reliability of mobile ad hoc network, a routing scheme called integrated forward error correction multipath routing protocol was proposed, which integrates the techniques of packet fragmenting and forward error correction encoding into multipath routing. The scheme works as follows: adding a certain redundancy into the original packets; fragmenting the resulting packets into exclusive blocks of the same size; encoding with the forward error correction technique, and then sending them to the destination node. When the receiving end receives a certain amount of information blocks, the original information will be recovered even with partial loss. The performance of the scheme was evaluated using OPNET modeler. The experimental results show that with the method the average transmission delay is decreased by 20% and the transmission reliability is increased by 30%.展开更多
Short-term forecasting is a difficult problem because of the influence of non-linear factors and irregular events.A novel short-term forecasting method named TIK was proposed,in which ARMA forecasting model was used t...Short-term forecasting is a difficult problem because of the influence of non-linear factors and irregular events.A novel short-term forecasting method named TIK was proposed,in which ARMA forecasting model was used to consider the load time series trend forecasting,intelligence forecasting DESVR model was applied to estimate the non-linear influence,and knowledge mining methods were applied to correct the errors caused by irregular events.In order to prove the effectiveness of the proposed model,an application of the daily maximum load forecasting was evaluated.The experimental results show that the DESVR model improves the mean absolute percentage error(MAPE) from 2.82% to 2.55%,and the knowledge rules can improve the MAPE from 2.55% to 2.30%.Compared with the single ARMA forecasting method and ARMA combined SVR forecasting method,it can be proved that TIK method gains the best performance in short-term load forecasting.展开更多
文摘Hydroxyapatite nanoparticles(HAP NPs)were synthesized by a one‐step hydrothermal method.The surface of HAP NPs was grafted-SH and-COOH chelating groups via in situ surface‐modification with iminodiacetic acid(IDA)and 3‐mercaptopropyl trimethoxysilane(MPS)to afford dual surface‐capped nano‐amendment HAPIDA/MPS.The structure of HAP‐IDA/MPS was characterized,and its adsorption performance for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)was evaluated.The total adsorption capacity of 0.10 g HAP‐IDA/MPS nano‐amendment for Hg^(2+),Cu^(2+),Zn^(2+),Ni^(2+),Co^(2+),and Cd^(2+)with an initial mass concentration of 20 mg·L^(-1) reached 13.7 mg·g^(-1),about 4.3 times as much as that of HAP.Notably,HAP‐IDA/MPS nano‐amendment displayed the highest immobilization rate for Hg^(2+),possibly because of its chemical reaction with-SH to form sulfide,possessing the lowest solubility product constant among a variety of metal sulfides.
基金Project(2023YFC2907304)supported by the National Key R&D Program Projects,ChinaProject(ZR2021ME087)supported by the Natural Science Foundation of Shandong Province,China+1 种基金Project(2022KLMM305)supported by the Shandong Provincial Key Laboratory of Mining Machinery Engineering School Enterprise Joint Fund,ChinaProject(2023CXPT062)supported by the Shandong Key Research and Development Program(Competitive Innovation Platform),China。
文摘An active protection coating for pH-responsive was prepared.The hollow mesoporous silica microspheres(HMSNs)were loaded with 2-mercaptobenzothiazole(MBT),and then they were coated with chitosan(CS).The composite microspheres were in the range of 650−750 nm in diameter.CS-HMSN-MBT coating had a faster repair rate under acidic conditions by synergistic effect between CS and MBT.The repair rate under alkaline conditions was slowed down.The active protection performance reached the strongest after 3 d immersion.The corrosion inhibitor release mechanism was optimized to extend the service life of the coating and to achieve long-term service of the copper substrate.
基金Projects(2003CB314802) supported by the State Key Fundamental Research and Development Programof China project(90104001) supported by the National Natural Science Foundation of China
文摘In order to improve the data transmission reliability of mobile ad hoc network, a routing scheme called integrated forward error correction multipath routing protocol was proposed, which integrates the techniques of packet fragmenting and forward error correction encoding into multipath routing. The scheme works as follows: adding a certain redundancy into the original packets; fragmenting the resulting packets into exclusive blocks of the same size; encoding with the forward error correction technique, and then sending them to the destination node. When the receiving end receives a certain amount of information blocks, the original information will be recovered even with partial loss. The performance of the scheme was evaluated using OPNET modeler. The experimental results show that with the method the average transmission delay is decreased by 20% and the transmission reliability is increased by 30%.
基金Projects(70671039,71071052) supported by the National Natural Science Foundation of ChinaProjects(10QX44,09QX68) supported by the Fundamental Research Funds for the Central Universities in China
文摘Short-term forecasting is a difficult problem because of the influence of non-linear factors and irregular events.A novel short-term forecasting method named TIK was proposed,in which ARMA forecasting model was used to consider the load time series trend forecasting,intelligence forecasting DESVR model was applied to estimate the non-linear influence,and knowledge mining methods were applied to correct the errors caused by irregular events.In order to prove the effectiveness of the proposed model,an application of the daily maximum load forecasting was evaluated.The experimental results show that the DESVR model improves the mean absolute percentage error(MAPE) from 2.82% to 2.55%,and the knowledge rules can improve the MAPE from 2.55% to 2.30%.Compared with the single ARMA forecasting method and ARMA combined SVR forecasting method,it can be proved that TIK method gains the best performance in short-term load forecasting.
