The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplore...The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplored challenge of substantial electrochemical overpotential,surface reconstruction has emerged as a necessary strategy.Focusing on key aspects such as Janus structures,overflow effects,the d-band center displacement hypothesis,and interface coupling related to electrochemical reactions is essential for water electrolysis.Emerging as frontrunners among next-generation electrocatalysts,Mott-Schottky(M-S)catalysts feature a heterojunction formed between a metal and a semiconductor,offering customizable and predictable interfacial synergy.This review offers an in-depth examination of the processes driving the hydrogen and oxygen evolution reactions(HER and OER),highlighting the benefits of employing nanoscale transition metal nitrides,carbides,oxides,and phosphides in M-S heterointerface catalysts.Furthermore,the challenges,limitations,and future prospects of employing M-S heterostructured catalysts for water splitting are thoroughly discussed.展开更多
TN201 2001053441半导体异质结及其在光电子学中的应用-2000年诺贝尔物理奖评述=Semiconductor heterojunction and ib application to optoelectronics:The 2000 Nobel price for physics[刊,中]/陈良惠(中科院半导体所.北京(100083))/...TN201 2001053441半导体异质结及其在光电子学中的应用-2000年诺贝尔物理奖评述=Semiconductor heterojunction and ib application to optoelectronics:The 2000 Nobel price for physics[刊,中]/陈良惠(中科院半导体所.北京(100083))//物理.—2001,30(4).—200-202,229评述了两位诺贝尔物理奖获得者在异质结及其在光电子学中的应用方面的贡献。图1参12(李瑞琴)展开更多
基金supported by the Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2021L574)the Guizhou Provincial Science and Technology Foundation([2024]ZK General 425 and 438)+1 种基金the National Natural Science Foundation of China(22309033)the Academic Young Talent Foundation of Guizhou Normal University([2022]B05 and B06)。
文摘The electron configuration of the active sites can be effectively modulated by regulating the inherent nanostructure of the electrocatalysts,thereby enhancing their electrocatalytic performance.To tackle the unexplored challenge of substantial electrochemical overpotential,surface reconstruction has emerged as a necessary strategy.Focusing on key aspects such as Janus structures,overflow effects,the d-band center displacement hypothesis,and interface coupling related to electrochemical reactions is essential for water electrolysis.Emerging as frontrunners among next-generation electrocatalysts,Mott-Schottky(M-S)catalysts feature a heterojunction formed between a metal and a semiconductor,offering customizable and predictable interfacial synergy.This review offers an in-depth examination of the processes driving the hydrogen and oxygen evolution reactions(HER and OER),highlighting the benefits of employing nanoscale transition metal nitrides,carbides,oxides,and phosphides in M-S heterointerface catalysts.Furthermore,the challenges,limitations,and future prospects of employing M-S heterostructured catalysts for water splitting are thoroughly discussed.
文摘TN201 2001053441半导体异质结及其在光电子学中的应用-2000年诺贝尔物理奖评述=Semiconductor heterojunction and ib application to optoelectronics:The 2000 Nobel price for physics[刊,中]/陈良惠(中科院半导体所.北京(100083))//物理.—2001,30(4).—200-202,229评述了两位诺贝尔物理奖获得者在异质结及其在光电子学中的应用方面的贡献。图1参12(李瑞琴)
