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杂质对化成过程影响的初步研究 被引量:1
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作者 蔡惠群 金明钢 +2 位作者 董全峰 尤金跨 林祖赓 《电池》 CAS CSCD 北大核心 2003年第3期129-130,共2页
讨论聚合物锂离子电池在化成时出现充电异常的主要影响因素。通过实验表明:在生产中残留在电池中的DBP、CH3OH、H2O是造成电池化成过程充电异常的主要杂质并可能影响SEI层的性质。
关键词 聚合物锂离子电池 化成过程 杂质 电极 电解液
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磷酸铁锂锂离子电池化成产气的机理 被引量:8
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作者 夏玉佳 朱振东 《电池》 CAS CSCD 北大核心 2020年第6期534-537,共4页
应用气相色谱和傅里叶变换红外光谱仪,分析磷酸铁锂(LiFePO 4)正极锂离子电池化成过程中的产气种类和负极表面的固体电解质相界面(SEI)膜,探讨产气来源和反应机理。气体主要在SEI膜形成阶段产生,成分为H 2、乙烯(C 2H 4)、CO、甲烷(CH 4... 应用气相色谱和傅里叶变换红外光谱仪,分析磷酸铁锂(LiFePO 4)正极锂离子电池化成过程中的产气种类和负极表面的固体电解质相界面(SEI)膜,探讨产气来源和反应机理。气体主要在SEI膜形成阶段产生,成分为H 2、乙烯(C 2H 4)、CO、甲烷(CH 4)和乙烷(C 2H 6);成膜后气体量无明显增加,在后续充放电过程中出现CO 2。通过对称电池的分析,证明H 2和烃类气体主要在负极侧产生,CO 2主要在正极侧产生。 展开更多
关键词 锂离子电池 磷酸铁锂(LiFePO 4) 化成过程 产气 对称电池
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Chemical process dynamic optimization based on hybrid differential evolution algorithm integrated with Alopex 被引量:5
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作者 范勤勤 吕照民 +1 位作者 颜学峰 郭美锦 《Journal of Central South University》 SCIE EI CAS 2013年第4期950-959,共10页
To solve dynamic optimization problem of chemical process (CPDOP), a hybrid differential evolution algorithm, which is integrated with Alopex and named as Alopex-DE, was proposed. In Alopex-DE, each original individua... To solve dynamic optimization problem of chemical process (CPDOP), a hybrid differential evolution algorithm, which is integrated with Alopex and named as Alopex-DE, was proposed. In Alopex-DE, each original individual has its own symbiotic individual, which consists of control parameters. Differential evolution operator is applied for the original individuals to search the global optimization solution. Alopex algorithm is used to co-evolve the symbiotic individuals during the original individual evolution and enhance the fitness of the original individuals. Thus, control parameters are self-adaptively adjusted by Alopex to obtain the real-time optimum values for the original population. To illustrate the whole performance of Alopex-DE, several varietal DEs were applied to optimize 13 benchmark functions. The results show that the whole performance of Alopex-DE is the best. Further, Alopex-DE was applied to solve 4 typical CPDOPs, and the effect of the discrete time degree on the optimization solution was analyzed. The satisfactory result is obtained. 展开更多
关键词 evolutionary computation dynamic optimization differential evolution algorithm Alopex algorithm self-adaptivity
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Numerical study on forming complex fitting body on end of integrated stainless steel pipe without welds 被引量:2
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作者 张大伟 赵升吨 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第2期269-276,共8页
It is necessary to use the integrated stainless steel pipe having two fitting bodies without welds while train travelling at high speed. In order to form this type of integrated stainless steel pipe, the method of pre... It is necessary to use the integrated stainless steel pipe having two fitting bodies without welds while train travelling at high speed. In order to form this type of integrated stainless steel pipe, the method of preforming combined finish forming process is developed. The preforming process is characterized by flaring combined upsetting for left fitting body which is like a flange, and is characterized by tube axial compressive process under die constraint for right fitting body which is like a double-wall pipe. The finite element simulations of the processes are carried out by software package DEFORM, and the results indicate that: 1) left or right fitting body can be formed by a two-step forming process without folding and under-filling defects; 2) by using two-step forming, strain and stress in left fitting body are larger than those in right fitting body, and deformation in right fitting body is more homogenous than the deformation in left fitting body; 3) two or more preforming steps may be needed for left fitting body considering the distributions of strain and stress. 展开更多
关键词 plastic forming hot forming flange joint integrated steel pipe finite element analysis
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Multi Boost with ENN-based ensemble fault diagnosis method and its application in complicated chemical process 被引量:1
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作者 夏崇坤 苏成利 +1 位作者 曹江涛 李平 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第5期1183-1197,共15页
Fault diagnosis plays an important role in complicated industrial process.It is a challenging task to detect,identify and locate faults quickly and accurately for large-scale process system.To solve the problem,a nove... Fault diagnosis plays an important role in complicated industrial process.It is a challenging task to detect,identify and locate faults quickly and accurately for large-scale process system.To solve the problem,a novel Multi Boost-based integrated ENN(extension neural network) fault diagnosis method is proposed.Fault data of complicated chemical process have some difficult-to-handle characteristics,such as high-dimension,non-linear and non-Gaussian distribution,so we use margin discriminant projection(MDP) algorithm to reduce dimensions and extract main features.Then,the affinity propagation(AP) clustering method is used to select core data and boundary data as training samples to reduce memory consumption and shorten learning time.Afterwards,an integrated ENN classifier based on Multi Boost strategy is constructed to identify fault types.The artificial data sets are tested to verify the effectiveness of the proposed method and make a detailed sensitivity analysis for the key parameters.Finally,a real industrial system—Tennessee Eastman(TE) process is employed to evaluate the performance of the proposed method.And the results show that the proposed method is efficient and capable to diagnose various types of faults in complicated chemical process. 展开更多
关键词 extension neural network multi-classifier ensembles margin discriminant projection affinity propagation FAULTDIAGNOSIS TE process
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Fabrication of FeAl/TiC composites through reactive hot pressing 被引量:1
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作者 刘峰晓 刘咏 +2 位作者 黄伯云 贺跃辉 周科朝 《Journal of Central South University of Technology》 2004年第4期343-347,共5页
FeAl/TiC composites were fabricated by reactive hot pressing blended elemental powders. The TiC content was varied from 50% to 80%(volume fraction) and the aluminum content in the binder phase was changed from 40% to ... FeAl/TiC composites were fabricated by reactive hot pressing blended elemental powders. The TiC content was varied from 50% to 80%(volume fraction) and the aluminum content in the binder phase was changed from 40% to 50%(mole fraction). The effects of these compositional changes on the densification process and mechanical properties were studied. The results show that with the increase of TiC content, densities of the composites decrease due to insufficient particle rearrangement aided by (dissolutionreprecipitation) reaction during hot pressing. Closely related with their porosities and defect amount, the hardness and bend strength of the composites show peak values, attaining the highest values with TiC content being 70% and 60%, respectively. Increasing the aluminum content is beneficial to the densification process. But the hardness and bend strength of the composites are reduced to some extent due to the formation of excessive oxides and thermal vacancies. 展开更多
关键词 FeAl/TiC composite densification process mechanical property reactive hot pressing
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Sequence of densification and hydrocarbon charging of Xu2 reservoir in Anyue–Hechuan area,Sichuan Basin,China 被引量:3
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作者 陈聪 徐国盛 +2 位作者 徐昉昊 袁海锋 陈飞 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第6期1439-1448,共10页
The sequence of the densification and hydrocarbon charging of the Xu2 reservoir in the Anyue–Hechuan area of Central Sichuan Basin is discussed.The diagenetic sequence is considered a time line to determine the histo... The sequence of the densification and hydrocarbon charging of the Xu2 reservoir in the Anyue–Hechuan area of Central Sichuan Basin is discussed.The diagenetic sequence is considered a time line to determine the historical relationship between the densification process and the hydrocarbon charging of the Xu2 reservoir in the study area:Early diagenetic stage B(the first stage of hydrocarbon charging,which was about 200–160 Ma ago,with a porosity of about 20%,consolidated and not tight)→middle diagenetic stage A(the second stage of hydrocarbon charging,which was about 140–120 Ma ago,with a porosity of 10%–20%and relatively tight)→middle diagenetic stage B(the third stage of hydrocarbon charging,which was about 20–5 Ma ago,with a porosity of 6%–10%and tight;However,fractures have developed).The study results prove that large-scale hydrocarbon charging and accumulation completed before the densification of the Xu2 reservoir,showing that the Upper Triassic Xujiahe Fm unconventional tight reservoir in the Sichuan Basin is prospective for exploration. 展开更多
关键词 Anyue-Hechuan area Xu2 member diagenetic sequence reservoir densification hydrocarbon charging INCLUSION
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Synthesis, characterization of monodispersed MgO microspheres and thermal decomposition kinetics of its precusor
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作者 袁培 郭雅坤 +1 位作者 谷昆泓 肖奇 《Journal of Central South University》 SCIE EI CAS 2014年第9期3463-3469,共7页
Monodispersed MgO microspheres were successfully synthesized by a simple solvothermal method using PEG-400 as solvent. The samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). Th... Monodispersed MgO microspheres were successfully synthesized by a simple solvothermal method using PEG-400 as solvent. The samples were characterized by X-ray diffraction(XRD) and scanning electron microscopy(SEM). The results reveal that the precusor was monoclinic Mg5(CO3)4(OH)2·4H2O and composed of nanosheets with the thickness of about 250 nm. By calcining the precusor at 500 °C for 5 min, cubic MgO with similar morphology was obtained. According to the SEM images, it is found that the volume ratio of PEG-400 to deionized water is considered as a crucial factor in the evolution of the morphology. Based on the SEM images obtained under different experimental conditions, a possible growth mechanism which involves self-assembly process was proposed. The thermal decomposition process of MgO precusor was studied by thermogravimetry-differential thermogravimetry(TG-DTG) at different heating rates in air. Thermal analysis kinetics results show that the most probale mechanism models of MgO precusor are An and D3, respectively. In addition, isothermal prediction was studied to quantitatively characterize the thermal decomposition process. 展开更多
关键词 PEG-400 monodisphersed MgO thermal decomposition kinetics isothermal prediction
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