The complex Cu（teta）（NO3）2 （teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane）was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-cr...The complex Cu（teta）（NO3）2 （teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane）was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with α=12.992（9）, b=11.639（7）, c=15.838（10）*!, β=116.802（8）°, V=2138（2）*!3, Z=4, Gcalc=1.467g/cm3,F（000）=1004. The complex has the centrosymmertric copper（Ⅱ） ion in square planar co-ordination with four nitrogens of the macrocycle.展开更多
The undrained mechanical behavior of unsaturated completely weathered granite(CWG)is highly susceptible to alterations in the hydraulic environment,particularly under uniaxial loading conditions,due to the unique natu...The undrained mechanical behavior of unsaturated completely weathered granite(CWG)is highly susceptible to alterations in the hydraulic environment,particularly under uniaxial loading conditions,due to the unique nature of this soil type.In this study,a series of unconfined compression tests were carried out on unsaturated CWG soil in an underground engineering site,and the effects of varying the environmental variables on the main undrained mechanical properties were analyzed.Based on the experimental results,a novel constitutive model was then established using the damage mechanics theory and the undetermined coefficient method.The results demonstrate that the curves of remolded CWG specimens with different moisture contents and dry densities exhibited diverse characteristics,including brittleness,significant softening,and ductility.As a typical indicator,the unconfined compression strength of soil specimens initially increased with an increase in moisture content and then decreased.Meanwhile,an optimal moisture content of approximately 10.5%could be observed,while a critical moisture content value of 13.0%was identified,beyond which the strength of the specimen decreases sharply.Moreover,the deformation and fracture of CWG specimens were predominantly caused by shear failure,and the ultimate failure modes were primarily influenced by moisture content rather than dry density.Furthermore,by comparing several similar models and the experimental data,the proposed model could accurately replicate the undrained mechanical characteristics of unsaturated CWG soil,and quantitatively describe the key mechanical indexes.These findings offer a valuable reference point for understanding the underlying mechanisms,anticipating potential risks,and implementing effective control measures in similar underground engineering projects.展开更多
This study aimed to address the challenge of accurately and reliably detecting tomatoes in dense planting environments,a critical prerequisite for the automation implementation of robotic harvesting.However,the heavy ...This study aimed to address the challenge of accurately and reliably detecting tomatoes in dense planting environments,a critical prerequisite for the automation implementation of robotic harvesting.However,the heavy reliance on extensive manually annotated datasets for training deep learning models still poses significant limitations to their application in real-world agricultural production environments.To overcome these limitations,we employed domain adaptive learning approach combined with the YOLOv5 model to develop a novel tomato detection model called as TDA-YOLO(tomato detection domain adaptation).We designated the normal illumination scenes in dense planting environments as the source domain and utilized various other illumination scenes as the target domain.To construct bridge mechanism between source and target domains,neural preset for color style transfer is introduced to generate a pseudo-dataset,which served to deal with domain discrepancy.Furthermore,this study combines the semi-supervised learning method to enable the model to extract domain-invariant features more fully,and uses knowledge distillation to improve the model's ability to adapt to the target domain.Additionally,for purpose of promoting inference speed and low computational demand,the lightweight FasterNet network was integrated into the YOLOv5's C3 module,creating a modified C3_Faster module.The experimental results demonstrated that the proposed TDA-YOLO model significantly outperformed original YOLOv5s model,achieving a mAP(mean average precision)of 96.80%for tomato detection across diverse scenarios in dense planting environments,increasing by 7.19 percentage points;Compared with the latest YOLOv8 and YOLOv9,it is also 2.17 and 1.19 percentage points higher,respectively.The model's average detection time per image was an impressive 15 milliseconds,with a FLOPs(floating point operations per second)count of 13.8 G.After acceleration processing,the detection accuracy of the TDA-YOLO model on the Jetson Xavier NX development board is 90.95%,the mAP value is 91.35%,and the detection time of each image is 21 ms,which can still meet the requirements of real-time detection of tomatoes in dense planting environment.The experimental results show that the proposed TDA-YOLO model can accurately and quickly detect tomatoes in dense planting environment,and at the same time avoid the use of a large number of annotated data,which provides technical support for the development of automatic harvesting systems for tomatoes and other fruits.展开更多
The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electro...The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electrolyte,Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3),utilizing cyclic voltammetry and square wave voltammetry techniques.The results show that Fe(Ⅲ)reduction occurs in two steps:Fe(Ⅲ)+e^(−)→Fe(Ⅱ),Fe(Ⅱ)+2e^(−)→Fe,and that the redox process of Fe(Ⅲ)/Fe(Ⅱ)at the tungsten electrode is an irreversible reaction controlled by diffusion.The diffusion coefficients of Fe(Ⅲ)in the molten Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3)in the temperature range of 1248–1278 K are between 1.86×10^(−6)cm^(2)/s and 1.58×10^(−4)cm^(2)/s.The diffusion activation energy of Fe(Ⅲ)in the molten salt is 1825.41 kJ/mol.As confirmed by XRD analysis,potentiostatic electrolysis at−0.857 V(vs.O_(2)/O_(complex)^(2-))for 6 h produces metallic iron on the cathode.展开更多
In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the ...In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the anticorrosion performance was investigated.The experimental results show that the epoxy-amine ring-open addition reaction mainly exists in the curing process,and the activation energies of the reaction for the two coatings are 55.84 and 53.29 kJ/mol,respectively.For the coatings cured at the low temperature,almost no pores could be detected on the fracture surface,but the presentence of the rough regions reflects the poor curing state.As compared with the samples cured at the high temperature,the anticorrosion performance of the coatings with the low curing temperature is worse,and the decrease rate of the anticorrosion performance is slower,because of the poor curing state and low adhesion obtained at the low temperature.展开更多
In order to study the strength failure and crack coalescence characteristics of cracked rocks, uniaxial compression experiments were conducted on cylindrical sandstone specimens, sampled from Longyou Grottoes of Zheji...In order to study the strength failure and crack coalescence characteristics of cracked rocks, uniaxial compression experiments were conducted on cylindrical sandstone specimens, sampled from Longyou Grottoes of Zhejiang Province, China, with a single pre-cut crack soaking in different chemical solutions. Based on the results of uniaxial compressive test under different chemical solutions and velocities of flow, the effect of strength and deformation characteristics and main modes of crack coalescence for cracked rocks under chemical corrosion were analyzed. The results show that the pH value and velocity of the chemical solutions both have great influence on the sandstone sample's uniaxial compressive strength and deformation characteristics. Cracked sandstone samples are tension-destructed under uniaxial compression, and the crack propagation directions are consistent with the loading direction. The phenomena of crack initiation, propagation and coalescence of sandstone are well observed. Four different crack types are identified based on the crack propagation mechanism by analyzing the ultimate failure modes of sandstone containing a single pre-cut fissure. The failure process of specimen in air is similar with the specimen under chemical solutions, however, the initial time of crack occuring in specimen under chemical solutions is generally earlier than that in the natural specimen, and the crack propagation and coalescence process of specimen under chemical solutions are longer than those of the natural specimen due to softening of structure of rock caused by hydro-chemical action. Immersion velocity of flow and chemical solutions does not have influence on the ultimate modes of crack coalescence.展开更多
Despite the presence of a large area of andesite in the Sayaburi Province of Laos, it has received very little attention. Based on a combination of detailed field investigations, geochronology and geochemical analysis...Despite the presence of a large area of andesite in the Sayaburi Province of Laos, it has received very little attention. Based on a combination of detailed field investigations, geochronology and geochemical analysis, this study aims to explore the geochemical, Sr-Nd isotopic, and source rock characteristics, as well as the genesis and tectonic setting of the andesite in this region. In the Sayaburi Province, the andesite zircon U-Pb age is(241.2±1.2) Ma. The andesite rock is classified in the metaluminous-weak peraluminous calc-alkaline series. The light rare-earth elements(LREEs) are enriched and characterized by clear fractionation, whereas heavy rare-earth elements(HREEs) are relatively depleted and have no signs of fractionation. The average δEu is 0.96 with weak-or-no Eu anomalies. It is enriched in large ion lithophile elements such as Rb and K, while depleted in high field-strength elements such as Nb, Ta, P and Ti. For andesites in the Sayaburi Province, the(87Rb/86Sr)t value ranges in 0.702849-0.704687, the εNd(t) value is between 3.53 and 4.77, the tDM(t) value ranges in 633-835 Ma, and the tDM2(t) ranges in 625–724 Ma. The results based on the synthesis of petrology, geochemistry, and regional tectonic background studies show that 1) the andesitic magma source in the study area is an enriched mantle, which is modified by subduction zone fluids;2) the geotectonic background environment of the andesite in Sayaburi area is the continental island arc environment and related to the tectonic evolution of Jinghong–Nan–Uttaradit back-arc basin, which reflects that the magmatic source is enriched with a mantle wedge component modified by a subduction zone fluid(or melt).展开更多
The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone betwe...The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone between the Early Cretaceous granodiorite and the late Permian Xiala Formation limestone.In this study,we achieved detailed zircon U-Pb-Hf isotopes and mineral chemistry for the Early Cretaceous granodiorite.Zircon U-Pb dating results indicate that the Early Cretaceous granodiorite emplaced at ca.119 Ma.Based on the trace elements in zircons and the mineral chemical composition of amphibole and biotite,the Early Cretaceous granodiorite was believed to form under condition of high temperature(>700°C),low pressure(100400 MPa),and relatively high oxygen fugacity(lgfO2)(13.6 to 13.9)and H2O content(4%8%).Zircon trace elements,Hf isotope and biotite chemistry collectively reveal that significant juvenile mantle-derived magmas contributed to the source of the granodiorite.The relatively high logfO2 and shallow magma chamber are beneficial for skarn iron mineralization,implying remarkable potential for further prospecting in the Lunggar iron deposit.展开更多
The effect of electrochemical chloride extraction （ECE） on bond strength between steel bar and freeze-thaw concrete contaminated by chloride was experimentally investigated for beam specimens with dimensions of 100 ...The effect of electrochemical chloride extraction （ECE） on bond strength between steel bar and freeze-thaw concrete contaminated by chloride was experimentally investigated for beam specimens with dimensions of 100 mm × 100 mm × 400 ram. During the experiment, 3% NaC1 （vs mass of cement, mass fraction） was mixed into concrete to simulate chloride contamination, and the specimens experienced 0, 25, 50, 75 freeze-thaw cycles before ECE. In the process of ECE, different current densities and durations were adopted. It is indicated that the bond strength between reinforcement and concrete decreases with the increase of freeze-thaw cycles; the more the current and the electric quantity of ECE are, the more the loss of bond strength is; and the largest loss is up to 58.7%. So, it is important to choose proper parameters of ECE for the reinforced concrete structures contaminated by chloride and subjected to freeze-thaw cycles.展开更多
Heat strain experienced by individuals wearing chemical protective clothing(CPC)is severe and dangerous especially in hot-humid environment.The development of material science and interdisciplinary studies including e...Heat strain experienced by individuals wearing chemical protective clothing(CPC)is severe and dangerous especially in hot-humid environment.The development of material science and interdisciplinary studies including ergonomics,physiology and heat transfer is urgently required for the reduction of heat strain.The aim of this paper was to study the relationship among clothing thermal properties,physiological responses and environmental conditions.Three kinds of CPC were selected.Eight participants wore CPC and walked(4 km/h,two slopes with 5%and 10%)on a treadmill in an environment with(35±0.5)℃ and RH of(60±5)%.Core temperature,mean skin temperature,heart rate,heat storage and tolerance time were recorded and analyzed.Physiological responses were significantly affected by the clothing thermal properties and activity intensity in hot-humid environment.The obtained results can help further development of heat strain model.New materials with lower evaporative resistance and less weight are necessary to release the heat strain in hot-humid environments.展开更多
文摘The complex Cu（teta）（NO3）2 （teta=meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane）was synthesized and characterized by elementary analysis, IR and UV and the structure was determined by single-crystal X-ray diffraction. The crystal belongs to monoclinic, space group C2/c with α=12.992（9）, b=11.639（7）, c=15.838（10）*!, β=116.802（8）°, V=2138（2）*!3, Z=4, Gcalc=1.467g/cm3,F（000）=1004. The complex has the centrosymmertric copper（Ⅱ） ion in square planar co-ordination with four nitrogens of the macrocycle.
基金Project(42202318)supported by the National Natural Science Foundation of ChinaProject(252300421199)supported by the Natural Science Foundation of Henan Province,ChinaProject(2024JJ6219)supported by the Hunan Provincial Natural Science Foundation of China。
文摘The undrained mechanical behavior of unsaturated completely weathered granite(CWG)is highly susceptible to alterations in the hydraulic environment,particularly under uniaxial loading conditions,due to the unique nature of this soil type.In this study,a series of unconfined compression tests were carried out on unsaturated CWG soil in an underground engineering site,and the effects of varying the environmental variables on the main undrained mechanical properties were analyzed.Based on the experimental results,a novel constitutive model was then established using the damage mechanics theory and the undetermined coefficient method.The results demonstrate that the curves of remolded CWG specimens with different moisture contents and dry densities exhibited diverse characteristics,including brittleness,significant softening,and ductility.As a typical indicator,the unconfined compression strength of soil specimens initially increased with an increase in moisture content and then decreased.Meanwhile,an optimal moisture content of approximately 10.5%could be observed,while a critical moisture content value of 13.0%was identified,beyond which the strength of the specimen decreases sharply.Moreover,the deformation and fracture of CWG specimens were predominantly caused by shear failure,and the ultimate failure modes were primarily influenced by moisture content rather than dry density.Furthermore,by comparing several similar models and the experimental data,the proposed model could accurately replicate the undrained mechanical characteristics of unsaturated CWG soil,and quantitatively describe the key mechanical indexes.These findings offer a valuable reference point for understanding the underlying mechanisms,anticipating potential risks,and implementing effective control measures in similar underground engineering projects.
基金The National Natural Science Foundation of China (32371993)The Natural Science Research Key Project of Anhui Provincial University(2022AH040125&2023AH040135)The Key Research and Development Plan of Anhui Province (202204c06020022&2023n06020057)。
文摘This study aimed to address the challenge of accurately and reliably detecting tomatoes in dense planting environments,a critical prerequisite for the automation implementation of robotic harvesting.However,the heavy reliance on extensive manually annotated datasets for training deep learning models still poses significant limitations to their application in real-world agricultural production environments.To overcome these limitations,we employed domain adaptive learning approach combined with the YOLOv5 model to develop a novel tomato detection model called as TDA-YOLO(tomato detection domain adaptation).We designated the normal illumination scenes in dense planting environments as the source domain and utilized various other illumination scenes as the target domain.To construct bridge mechanism between source and target domains,neural preset for color style transfer is introduced to generate a pseudo-dataset,which served to deal with domain discrepancy.Furthermore,this study combines the semi-supervised learning method to enable the model to extract domain-invariant features more fully,and uses knowledge distillation to improve the model's ability to adapt to the target domain.Additionally,for purpose of promoting inference speed and low computational demand,the lightweight FasterNet network was integrated into the YOLOv5's C3 module,creating a modified C3_Faster module.The experimental results demonstrated that the proposed TDA-YOLO model significantly outperformed original YOLOv5s model,achieving a mAP(mean average precision)of 96.80%for tomato detection across diverse scenarios in dense planting environments,increasing by 7.19 percentage points;Compared with the latest YOLOv8 and YOLOv9,it is also 2.17 and 1.19 percentage points higher,respectively.The model's average detection time per image was an impressive 15 milliseconds,with a FLOPs(floating point operations per second)count of 13.8 G.After acceleration processing,the detection accuracy of the TDA-YOLO model on the Jetson Xavier NX development board is 90.95%,the mAP value is 91.35%,and the detection time of each image is 21 ms,which can still meet the requirements of real-time detection of tomatoes in dense planting environment.The experimental results show that the proposed TDA-YOLO model can accurately and quickly detect tomatoes in dense planting environment,and at the same time avoid the use of a large number of annotated data,which provides technical support for the development of automatic harvesting systems for tomatoes and other fruits.
基金Project(52074084)supported by the National Natural Science Foundation of China。
文摘The high-temperature requirement for liquid iron smelting via molten oxide electrolysis presents significant challenges.This study investigates the electrochemical reduction of Fe(Ⅲ)in a novel low-temperature electrolyte,Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3),utilizing cyclic voltammetry and square wave voltammetry techniques.The results show that Fe(Ⅲ)reduction occurs in two steps:Fe(Ⅲ)+e^(−)→Fe(Ⅱ),Fe(Ⅱ)+2e^(−)→Fe,and that the redox process of Fe(Ⅲ)/Fe(Ⅱ)at the tungsten electrode is an irreversible reaction controlled by diffusion.The diffusion coefficients of Fe(Ⅲ)in the molten Na_(2)SiO_(3)-SiO_(2)-Fe_(2)O_(3)in the temperature range of 1248–1278 K are between 1.86×10^(−6)cm^(2)/s and 1.58×10^(−4)cm^(2)/s.The diffusion activation energy of Fe(Ⅲ)in the molten salt is 1825.41 kJ/mol.As confirmed by XRD analysis,potentiostatic electrolysis at−0.857 V(vs.O_(2)/O_(complex)^(2-))for 6 h produces metallic iron on the cathode.
基金Project(U2106216)supported by the National Natural Science Foundation of China。
文摘In this manuscript,the neat epoxy(EP)and functionalized Fe_(3)O_(4)(G-Fe_(3)O_(4))reinforced epoxy(G-Fe_(3)O_(4)/EP)coatings were cured under different temperatures,and the effect of the low curing temperature on the anticorrosion performance was investigated.The experimental results show that the epoxy-amine ring-open addition reaction mainly exists in the curing process,and the activation energies of the reaction for the two coatings are 55.84 and 53.29 kJ/mol,respectively.For the coatings cured at the low temperature,almost no pores could be detected on the fracture surface,but the presentence of the rough regions reflects the poor curing state.As compared with the samples cured at the high temperature,the anticorrosion performance of the coatings with the low curing temperature is worse,and the decrease rate of the anticorrosion performance is slower,because of the poor curing state and low adhesion obtained at the low temperature.
基金Projects(10472130,41202225) supported by the National Natural Science Foundation of China
文摘In order to study the strength failure and crack coalescence characteristics of cracked rocks, uniaxial compression experiments were conducted on cylindrical sandstone specimens, sampled from Longyou Grottoes of Zhejiang Province, China, with a single pre-cut crack soaking in different chemical solutions. Based on the results of uniaxial compressive test under different chemical solutions and velocities of flow, the effect of strength and deformation characteristics and main modes of crack coalescence for cracked rocks under chemical corrosion were analyzed. The results show that the pH value and velocity of the chemical solutions both have great influence on the sandstone sample's uniaxial compressive strength and deformation characteristics. Cracked sandstone samples are tension-destructed under uniaxial compression, and the crack propagation directions are consistent with the loading direction. The phenomena of crack initiation, propagation and coalescence of sandstone are well observed. Four different crack types are identified based on the crack propagation mechanism by analyzing the ultimate failure modes of sandstone containing a single pre-cut fissure. The failure process of specimen in air is similar with the specimen under chemical solutions, however, the initial time of crack occuring in specimen under chemical solutions is generally earlier than that in the natural specimen, and the crack propagation and coalescence process of specimen under chemical solutions are longer than those of the natural specimen due to softening of structure of rock caused by hydro-chemical action. Immersion velocity of flow and chemical solutions does not have influence on the ultimate modes of crack coalescence.
基金Projects(DD20160107,DD20150742)supported by the China Geological SurveyProject supported by the International Scientific Plan of the Qinghai-Xizang(Tibet)Plateau of Chengdu Center,China Geological Survey
文摘Despite the presence of a large area of andesite in the Sayaburi Province of Laos, it has received very little attention. Based on a combination of detailed field investigations, geochronology and geochemical analysis, this study aims to explore the geochemical, Sr-Nd isotopic, and source rock characteristics, as well as the genesis and tectonic setting of the andesite in this region. In the Sayaburi Province, the andesite zircon U-Pb age is(241.2±1.2) Ma. The andesite rock is classified in the metaluminous-weak peraluminous calc-alkaline series. The light rare-earth elements(LREEs) are enriched and characterized by clear fractionation, whereas heavy rare-earth elements(HREEs) are relatively depleted and have no signs of fractionation. The average δEu is 0.96 with weak-or-no Eu anomalies. It is enriched in large ion lithophile elements such as Rb and K, while depleted in high field-strength elements such as Nb, Ta, P and Ti. For andesites in the Sayaburi Province, the(87Rb/86Sr)t value ranges in 0.702849-0.704687, the εNd(t) value is between 3.53 and 4.77, the tDM(t) value ranges in 633-835 Ma, and the tDM2(t) ranges in 625–724 Ma. The results based on the synthesis of petrology, geochemistry, and regional tectonic background studies show that 1) the andesitic magma source in the study area is an enriched mantle, which is modified by subduction zone fluids;2) the geotectonic background environment of the andesite in Sayaburi area is the continental island arc environment and related to the tectonic evolution of Jinghong–Nan–Uttaradit back-arc basin, which reflects that the magmatic source is enriched with a mantle wedge component modified by a subduction zone fluid(or melt).
基金Project(2018YSJS14)supported by the Open Research Fund Program of Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring(Central South University),Ministry of Education,China
文摘The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone between the Early Cretaceous granodiorite and the late Permian Xiala Formation limestone.In this study,we achieved detailed zircon U-Pb-Hf isotopes and mineral chemistry for the Early Cretaceous granodiorite.Zircon U-Pb dating results indicate that the Early Cretaceous granodiorite emplaced at ca.119 Ma.Based on the trace elements in zircons and the mineral chemical composition of amphibole and biotite,the Early Cretaceous granodiorite was believed to form under condition of high temperature(>700°C),low pressure(100400 MPa),and relatively high oxygen fugacity(lgfO2)(13.6 to 13.9)and H2O content(4%8%).Zircon trace elements,Hf isotope and biotite chemistry collectively reveal that significant juvenile mantle-derived magmas contributed to the source of the granodiorite.The relatively high logfO2 and shallow magma chamber are beneficial for skarn iron mineralization,implying remarkable potential for further prospecting in the Lunggar iron deposit.
基金Project(IRT0518) supported by the Program of Innovative Team of the Ministry of Education of China
文摘The effect of electrochemical chloride extraction （ECE） on bond strength between steel bar and freeze-thaw concrete contaminated by chloride was experimentally investigated for beam specimens with dimensions of 100 mm × 100 mm × 400 ram. During the experiment, 3% NaC1 （vs mass of cement, mass fraction） was mixed into concrete to simulate chloride contamination, and the specimens experienced 0, 25, 50, 75 freeze-thaw cycles before ECE. In the process of ECE, different current densities and durations were adopted. It is indicated that the bond strength between reinforcement and concrete decreases with the increase of freeze-thaw cycles; the more the current and the electric quantity of ECE are, the more the loss of bond strength is; and the largest loss is up to 58.7%. So, it is important to choose proper parameters of ECE for the reinforced concrete structures contaminated by chloride and subjected to freeze-thaw cycles.
文摘Heat strain experienced by individuals wearing chemical protective clothing(CPC)is severe and dangerous especially in hot-humid environment.The development of material science and interdisciplinary studies including ergonomics,physiology and heat transfer is urgently required for the reduction of heat strain.The aim of this paper was to study the relationship among clothing thermal properties,physiological responses and environmental conditions.Three kinds of CPC were selected.Eight participants wore CPC and walked(4 km/h,two slopes with 5%and 10%)on a treadmill in an environment with(35±0.5)℃ and RH of(60±5)%.Core temperature,mean skin temperature,heart rate,heat storage and tolerance time were recorded and analyzed.Physiological responses were significantly affected by the clothing thermal properties and activity intensity in hot-humid environment.The obtained results can help further development of heat strain model.New materials with lower evaporative resistance and less weight are necessary to release the heat strain in hot-humid environments.
