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表面活性剂溶液的动表面张力研究 被引量:1
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作者 张兰辉 赵国玺 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 1992年第5期675-678,共4页
用振荡射流法分别测定了不同温度下全氟辛酸、十二烷基硫酸钠、二聚氯乙烯正辛醇醚溶液(浓度低于CMC)的动表面张力,讨论了它们的表面吸附动力学,研究结果表明都是扩散控制。
关键词 动表面张力 表面吸附 表面活性剂
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聚二甲基二烯丙基氯化铵水溶液的动表面张力(英文)
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作者 莫春生 卡丘洛娃 N N 普杰琳泽娃 M N 《江西师范大学学报(自然科学版)》 CAS 2000年第3期230-234,共5页
发现聚二甲基二烯丙基氯化铵水溶液的表面张力具有独特的时间相关性 .吸附的前期遵从扩散控制机理 ,而在吸附的后期 ,即接近吸附平衡时遵从扩散 动力学控制机理 .
关键词 动表面张力 聚二甲基二烯丙基氯化铵 吸附
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气泡长大技术测定表面活性剂溶液的动表面张力 被引量:1
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作者 王志龙 郭红宇 +2 位作者 李佟茗 程浩军 来可伟 《化工学报》 EI CAS CSCD 北大核心 1999年第4期463-468,共6页
在理论分析的基础上,采用计算机图像采集技术,实时记录气泡的长大过程,用图像分析技术确定气泡边缘形状,即采用局部阈值的边缘跟踪算法识别气泡的边缘井进行优化,建立了根据气泡图像测定动表面张力的实验装置,可直接测量动表面张力随时... 在理论分析的基础上,采用计算机图像采集技术,实时记录气泡的长大过程,用图像分析技术确定气泡边缘形状,即采用局部阈值的边缘跟踪算法识别气泡的边缘井进行优化,建立了根据气泡图像测定动表面张力的实验装置,可直接测量动表面张力随时间的变化.测定了十二烷基硫酸钠溶液的动表面张力. 展开更多
关键词 动表面张力 气泡长大技术 表面活性剂溶液 溶液
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由表面活性物质溶液的动界面张力外推求平衡界面张力的研究
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作者 徐秀坤 王世容 吴树森 《高等学校化学学报》 SCIE EI CAS 1988年第12期1305-1307,共3页
表面活性物质溶液的界面张力往往随时间而变,难以测得平衡界面张力J。Kloubek曾应用经验式:1/(δH_(2)O-δt)=b/(At^(1/2))+1/A,以[1/(δH_(2)O-δt)]对1/t^(1/2)作图外推求得溶液的平衡表面张力,但所得结果仅与文献值大致相符。本文从... 表面活性物质溶液的界面张力往往随时间而变,难以测得平衡界面张力J。Kloubek曾应用经验式:1/(δH_(2)O-δt)=b/(At^(1/2))+1/A,以[1/(δH_(2)O-δt)]对1/t^(1/2)作图外推求得溶液的平衡表面张力,但所得结果仅与文献值大致相符。本文从理论上分析该经验式的由来,以及产生偏离的原因,并寻求了解决的办法。 展开更多
关键词 界面张力 动表面张力 平衡界面张力 平衡表面张力
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Numerical simulation of dynamic process for liquid film spreading by lattice Boltzmann method and its experimental verification 被引量:2
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作者 刘邱祖 寇子明 韩振南 《Journal of Central South University》 SCIE EI CAS 2014年第8期3247-3253,共7页
Combined with the kinetic model of liquid film spreading, a new numerical method of solid-liquid-gas three-phase flow was developed for the moving of contact line, which was a hybrid method of computational fluid dyna... Combined with the kinetic model of liquid film spreading, a new numerical method of solid-liquid-gas three-phase flow was developed for the moving of contact line, which was a hybrid method of computational fluid dynamics and lattice Boltzmalm method (LBM). By taking the effect of molecule force in droplet and the wall surface on liquid film into account, the changing law of contact angle with different surface tensions was analyzed on glass and aluminum foil surfaces. Compared with experimental results, the standard deviation by using LBM is less than 0.5°, which validates the feasibility of LBM simulation on the dynamic process of liquid film spreading. In addition, oscillations are discovered both at the initial and end phases. The phenomenon of retraction is also found and the maximum retraction angle is 7.58°. The obtained result shows that the retraction is proved to be correlative with precursor film by tracking the volume change of liquid film contour. Furthermore, non-dimensional coefficient 2 is introduced to measure the liquid film retraction capacity. 展开更多
关键词 liquid film spreading contact angle lattice Boltzmann method (LBM) retraction phenomenon numerical simulation
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Online dynamic measurement of saturation-capillary pressure relation in sandy medium under water level fluctuation 被引量:1
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作者 李雁 周劲风 +1 位作者 徐军 KAMON M 《Journal of Central South University》 SCIE EI CAS 2010年第1期85-92,共8页
An online dynamic method based on electrical conductivity probe, tensiometer and datataker was presented to measure saturation-capillary pressure (S-p) relation in water-light nonaqueous phase liquid (LNAPL) two-p... An online dynamic method based on electrical conductivity probe, tensiometer and datataker was presented to measure saturation-capillary pressure (S-p) relation in water-light nonaqueous phase liquid (LNAPL) two-phase sandy medium under water level fluctuation. Three-electrode electrical conductivity probe (ECP) was used to measure water saturation. Hydrophobic tensiometer was obtained by spraying waterproof material to the ceramic cup of commercially available hydrophilic tensiometer. A couple of hydrophilic tensiometer and hydrophobic tensiometer were used to measure pore water pressure and pore LNAPL pressure of the sandy medium, respectively. All the signals from ECP and tensiometer were collected by a data taker connected with a computer. The results show that this method can finish the measurement of S-R relation of a complete drainage or imbibition process in less than 60 min. It is much more timesaving compared with 10-40 d of traditional methods. Two cycles of water level fluctuation were produced, and four saturation-capillary pressure relations including two stable residual LNAPL saturations of the sandy medium were obtained during in 350 h. The results show that this method has a good durable performance and feasibility in the porous medium with complicated multiphase flow. Although further studies are needed on the signal stability and accuracy drift of the ECP, this online dynamic method can be used successfully in the rapid characterization of a LNAPL migration in porous media. 展开更多
关键词 water level fluctuation saturation-capillary pressure (S-p) relation online dynamic measurement
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