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氧浓度振荡操作下的丙烯氨氧化反应动态动力学模型 被引量:1
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作者 陈丰秋 詹晓力 魏小明 《高校化学工程学报》 EI CAS CSCD 北大核心 2002年第6期638-642,共5页
针对Mo-Bi系催化剂作用下的丙烯氨氧化反应过程,采用氧浓度的强制周期振荡操作,根据理论推导和所定义的催化剂表面活性中心分率a,得到了丙烯转化率X及丙烯腈选择性SAN的动态动力学模型如下: X =K×a ?00% SAN=nCa× 100% ()1112... 针对Mo-Bi系催化剂作用下的丙烯氨氧化反应过程,采用氧浓度的强制周期振荡操作,根据理论推导和所定义的催化剂表面活性中心分率a,得到了丙烯转化率X及丙烯腈选择性SAN的动态动力学模型如下: X =K×a ?00% SAN=nCa× 100% ()111211221211exp11ppKpKatbpppKpa轾骣骣犏琪=+-+?琪琪犏琪桫+搓?进而结合在不同振荡操作周期、不同振幅条件下所采集到的实验数据,确定了模型参数,并进行优化计算得到最佳的振荡操作条件,丙烯腈周期平均收率达81.1%,比非振荡操作时提高了3.09个百分点。 展开更多
关键词 氧浓度 丙烯氨 氧化反应 动态动力学模型 强制振荡 丙烯腈
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SA508 Gr.3Cl.1钢动态再结晶行为研究 被引量:3
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作者 马璟 刘建生 郭桢 《河南科技大学学报(自然科学版)》 CAS 北大核心 2022年第3期1-8,M0002,共9页
通过在热模拟试验机Gleeble-1500上对SA508 Gr.3Cl.1钢进行变形温度为950~1 200℃、应变速率为0.001~1 s;的等温压缩试验,研究了其在高温热变形时的动态再结晶行为。基于P-J法确定了临界应力和临界应变,建立了其与热变形参数Z之间的数... 通过在热模拟试验机Gleeble-1500上对SA508 Gr.3Cl.1钢进行变形温度为950~1 200℃、应变速率为0.001~1 s;的等温压缩试验,研究了其在高温热变形时的动态再结晶行为。基于P-J法确定了临界应力和临界应变,建立了其与热变形参数Z之间的数学模型。基于改进的Avrami方程建立了SA508 Gr.3Cl.1钢的动态再结晶动力学模型。以变形温度和应变速率为变量建立了动态再结晶尺寸模型。研究结果表明:SA508 Gr.3Cl.1钢在高温低应变速率下,更容易发生动态再结晶。在动态再结晶进行充分的情况下,温度越高,应变速率越低,动态再结晶晶粒尺寸越大。动态再结晶尺寸模型计算值与试验值之间的相关系数达0.97。 展开更多
关键词 SA508 Gr.3Cl.1 热变形 动态再结晶动力学模型 动态再结晶晶粒尺寸模型
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Improving cam profile design optimization based on classical splines and dynamic model 被引量:8
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作者 夏必忠 刘新成 +1 位作者 尚欣 任世远 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第8期1817-1825,共9页
Cam profiles play an important part in the performance of cam mechanisms. Syntheses of cam profile designs and dynamics of cam designs are studied at first. Then, a cam profile design optimization model based on the s... Cam profiles play an important part in the performance of cam mechanisms. Syntheses of cam profile designs and dynamics of cam designs are studied at first. Then, a cam profile design optimization model based on the six order classical spline and single DOF(degree of freedom) dynamic model of single-dwell cam mechanisms is developed. And dynamic constraints such as jumps and vibrations of followers are considered. This optimization model, with many advantages such as universalities of applications, conveniences to operations and good performances in improving kinematic and dynamic properties of cam mechanisms, is good except for the discontinuity of jerks at the end knots of cam profiles which will cause vibrations of cam systems. However, the optimization is improved by combining the six order classical spline with general polynomial spline which is the so-called "trade-offs". Finally, improved optimization is proven to have a better performance in designing cam profiles. 展开更多
关键词 cam profile design spline optimization trade-off
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Modeling of metadynamic recrystallization kinetics after hot deformation of low-alloy steel Q345B 被引量:3
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作者 马博 彭艳 +1 位作者 刘云飞 贾斌 《Journal of Central South University》 SCIE EI CAS 2010年第5期911-917,共7页
Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic re... Based on the steady-state strain measured by single-pass hot compression tests,the method by a double-pass hot compression testing was developed to measure the metadynamic-recrystallization kinetics.The metadynamic recrystallization behavior of low-alloy steel Q345B during hot compression deformation was investigated in the temperature range of 1 000-1 100℃,the strain rate range of 0.01-0.10 s -1 and the interpass time range of 0.5-50 s on a Gleeble-3500 thermo-simulation machine.The results show that metadynamic recrystallization during the interpass time can be observed.As the deformation temperature and strain rate increase,softening caused by metadynamic recrystallization is obvious.According to the data of thermo-simulation,the metadynamic recrystallization activation energy is obtained to be Qmd=100.674 kJ/mol and metadynamic recrystallization kinetics model is set up.Finally,the error analysis of metadynamic recrystallization kinetics model proves that the model has high accuracy(correlation coefficient R=0.988 6). 展开更多
关键词 low-alloy steel kinetics model hot deformation metadynamic recrystallization activation energy
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Features of pipe transportation of paste-like backfilling in deep mine 被引量:10
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作者 王新民 赵建文 +1 位作者 薛俊华 余国锋 《Journal of Central South University》 SCIE EI CAS 2011年第5期1413-1417,共5页
Based on the pipe transportation of paste-like backfilling system of a certain deep coal mine,its dynamics process was simulated and analyzed.A two-dimensional dynamic model of extraordinary deep and lone pipe was bui... Based on the pipe transportation of paste-like backfilling system of a certain deep coal mine,its dynamics process was simulated and analyzed.A two-dimensional dynamic model of extraordinary deep and lone pipe was built by GAMBIT,on the basis of which the simulation was done by implicit solver of FLUENT 2ddp.The results show that hydraulic loss of pipe transportation is less than the pressure produced by gravity,which means the backfilling material can flow by itself.When the inlet velocity is 3.2 m/s,the maximum velocity of 4.10 m/s is at the elbow and the maximum velocity in the horizontal pipe is 3.91 m/s,which can both meet the stability requirement.The results of the simulation are proved to be reliable by the residual monitor plotting of related parameter,so it can be concluded that the system of pipe transportation is safe. 展开更多
关键词 BACKFILLING deep mine paste-like slurry pipe transportation flow
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