Thermal decomposition of waste epoxy PCBs was performed in different atmospheres （nitrogen, argon, air and vacuum） at a heating rate of 10 ℃/rain by DSC-TGA, and the pyrolysis characteristic was analyzed. The gases...Thermal decomposition of waste epoxy PCBs was performed in different atmospheres （nitrogen, argon, air and vacuum） at a heating rate of 10 ℃/rain by DSC-TGA, and the pyrolysis characteristic was analyzed. The gases volatilized from the experiment were qualitatively analyzed by TG-FTIR. Kinetics study shows that pyrolysis reaction takes place between 300 and 400℃, and the activation energies are 256, 212 and 186.2 kJ/mol in nitrogen, argon and vacuum, respectively. There are two mass-loss processes in the decomposition under air atmosphere. In the first mass-loss process, the decomposition is the main reaction, and in the second process, the oxidation is the main reaction. The activation energy of the second mass-loss process is 99.6 kJ/mol by isothermal heat-treatments. TG-FTIR analysis shows carbon dioxide, carbon monoxide, hydrogen bromide, phenol and substituent phenol are given off during the pyrolysis of waste epoxy PCBs.展开更多
An analytical approach was presented for estimating the factor of safety(FS) for slope failure, with consideration of the impact of a confined aquifer. An upward-moving wetting front from the confined water was assume...An analytical approach was presented for estimating the factor of safety(FS) for slope failure, with consideration of the impact of a confined aquifer. An upward-moving wetting front from the confined water was assumed and the pore water pressure distribution was then estimated and used to obtain the analytical expression of FS. Then, the validation of the theoretical analysis was applied based on an actual case in Hong Kong. It is shown that the presence of a confined aquifer leads to a lower FS value, and the impact rate of hydrostatic pressure on FS increases as the confined water pressure increases, approaching to a maximum value determined by the ratio of water density to saturated soil density. It is also presented that the contribution of hydrostatic pressure and hydrodynamic pressure to the slope stability vary with the confined aquifer pressure.展开更多
基金Project(2006AA06Z375) supported by the National High-tech Research and Development Program of China
文摘Thermal decomposition of waste epoxy PCBs was performed in different atmospheres （nitrogen, argon, air and vacuum） at a heating rate of 10 ℃/rain by DSC-TGA, and the pyrolysis characteristic was analyzed. The gases volatilized from the experiment were qualitatively analyzed by TG-FTIR. Kinetics study shows that pyrolysis reaction takes place between 300 and 400℃, and the activation energies are 256, 212 and 186.2 kJ/mol in nitrogen, argon and vacuum, respectively. There are two mass-loss processes in the decomposition under air atmosphere. In the first mass-loss process, the decomposition is the main reaction, and in the second process, the oxidation is the main reaction. The activation energy of the second mass-loss process is 99.6 kJ/mol by isothermal heat-treatments. TG-FTIR analysis shows carbon dioxide, carbon monoxide, hydrogen bromide, phenol and substituent phenol are given off during the pyrolysis of waste epoxy PCBs.
基金Project(R5110012)supported by Special Foundation for Distinguished Young Scholars of Zhejiang Province,ChinaProject(2009C33117)supported by The General Program of Natural Science Foundation of Zhejiang Province,China
文摘An analytical approach was presented for estimating the factor of safety(FS) for slope failure, with consideration of the impact of a confined aquifer. An upward-moving wetting front from the confined water was assumed and the pore water pressure distribution was then estimated and used to obtain the analytical expression of FS. Then, the validation of the theoretical analysis was applied based on an actual case in Hong Kong. It is shown that the presence of a confined aquifer leads to a lower FS value, and the impact rate of hydrostatic pressure on FS increases as the confined water pressure increases, approaching to a maximum value determined by the ratio of water density to saturated soil density. It is also presented that the contribution of hydrostatic pressure and hydrodynamic pressure to the slope stability vary with the confined aquifer pressure.
