The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multip...The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.展开更多
The probability distributions of wind speeds and the availability of wind turbines were investigated by considering the vertical wind shear. Based on the wind speed data at the standard height observed at a wind farm,...The probability distributions of wind speeds and the availability of wind turbines were investigated by considering the vertical wind shear. Based on the wind speed data at the standard height observed at a wind farm, the power-law process was used to simulate the wind speeds at a hub height of 60 m. The Weibull and Rayleigh distributions were chosen to express the wind speeds at two different heights. The parameters in the model were estimated via the least square(LS) method and the maximum likelihood estimation(MLE) method, respectively. An adjusted MLE approach was also presented for parameter estimation. The main indices of wind energy characteristics were calculated based on observational wind speed data. A case study based on the data of Hexi area, Gansu Province of China was given. The results show that MLE method generally outperforms LS method for parameter estimation, and Weibull distribution is more appropriate to describe the wind speed at the hub height.展开更多
基金funded by the National Natural Science Foundation of China(Grant No.12272217)。
文摘The aging characteristics of lithium-ion battery(LIB)under fast charging is investigated based on an electrochemical-thermal-mechanical(ETM)coupling model.Firstly,the ETM coupling model is established by COMSOL Multiphysics.Subsequently,a long cycle test was conducted to explore the aging characteristics of LIB.Specifically,the effects of charging(C)rate and cycle number on battery aging are analyzed in terms of nonuniform distribution of solid electrolyte interface(SEI),SEI formation,thermal stability and stress characteristics.The results indicate that the increases in C rate and cycling led to an increase in the degree of nonuniform distribution of SEI,and thus a consequent increase in the capacity loss due to the SEI formation.Meanwhile,the increases in C rate and cycle number also led to an increase in the heat generation and a decrease in the heat dissipation rate of the battery,respectively,which result in a decrease in the thermal stability of the electrode materials.In addition,the von Mises stress of the positive electrode material is higher than that of the negative electrode material as the cycling proceeds,with the positive electrode material exhibiting tensile deformation and the negative electrode material exhibiting compressive deformation.The available lithium ion concentration of the positive electrode is lower than that of the negative electrode,proving that the tensile-type fracture occurring in the positive material under long cycling dominated the capacity loss process.The aforementioned studies are helpful for researchers to further explore the aging behavior of LIB under fast charging and take corresponding preventive measures.
基金Project(51165019)supported by the National Natural Science Foundation of ChinaProject(1308RJYA018)supported by Gansu Provincial Natural Science Fund,ChinaProject(2013-4-110)supported by Lanzhou Technology Development Program,China
文摘The probability distributions of wind speeds and the availability of wind turbines were investigated by considering the vertical wind shear. Based on the wind speed data at the standard height observed at a wind farm, the power-law process was used to simulate the wind speeds at a hub height of 60 m. The Weibull and Rayleigh distributions were chosen to express the wind speeds at two different heights. The parameters in the model were estimated via the least square(LS) method and the maximum likelihood estimation(MLE) method, respectively. An adjusted MLE approach was also presented for parameter estimation. The main indices of wind energy characteristics were calculated based on observational wind speed data. A case study based on the data of Hexi area, Gansu Province of China was given. The results show that MLE method generally outperforms LS method for parameter estimation, and Weibull distribution is more appropriate to describe the wind speed at the hub height.
