In order to obtain high-density dual-scale ceramic particles(8.5 wt.%SiC+1.5 wt.%TiC)reinforced Al-Mg Sc-Zr composites with uniform microstructure,50 nm TiC and 7μm SiC particles were pre-dispersed into 15−53μm alum...In order to obtain high-density dual-scale ceramic particles(8.5 wt.%SiC+1.5 wt.%TiC)reinforced Al-Mg Sc-Zr composites with uniform microstructure,50 nm TiC and 7μm SiC particles were pre-dispersed into 15−53μm aluminum alloy powders by low-speed ball milling and mechanical mixing technology,respectively.Then,the effects of laser energy density,power and scanning rate on the density of the composites were investigated based on selective laser melting(SLM)technology.The effect of micron-sized SiC and nano-sized TiC particles on solidification structure,mechanical properties and fracture behaviors of the composites was revealed and analyzed in detail.Interfacial reaction and phase variations in the composites with varying reinforced particles were emphatically considered.Results showed that SiC-TiC particles could significantly improve forming quality and density of the SLMed composites,and the optimal relative density was up to 100%.In the process of laser melting,a strong chemical reaction occurs between SiC and aluminum matrix,and micron-scale acicular Al_(4)SiC_(4) bands were formed in situ.There was no interfacial reaction between TiC particles and aluminum matrix.TiC/Al semi-coherent interface had good bonding strength.Pinning effect of TiC particles in grain boundaries could prevent the equiaxial crystals from growing and transforming into columnar crystals,resulting in grain refinement.The optimal ultimate tensile strength(UTS),yield strength(YS),elongation(EL)and elastic modulus of the SiC-TiC/Al-Mg-Sc-Zr composite were~394 MPa,~262 MPa,~8.2%and~86 GPa,respectively.The fracture behavior of the composites included ductile fracture of Al matrix and brittle cleavage fracture of Al_(4)SiC_(4) phases.A large number of cross-distributed acicular Al_(4)SiC_(4) bands were the main factors leading to premature failure and fracture of SiC-TiC/Al-Mg-Sc-Zr composites.展开更多
近几年,电动汽车市场的飞速发展对锂离子电池的能量密度和安全性提出了更高的要求.然而,过去近30年,在应用终端市场的大力推动下,锂离子电池的电极材料、电池结构设计和生产工艺都已经发展得比较成熟,容量提升空间已经比较小,想要进一...近几年,电动汽车市场的飞速发展对锂离子电池的能量密度和安全性提出了更高的要求.然而,过去近30年,在应用终端市场的大力推动下,锂离子电池的电极材料、电池结构设计和生产工艺都已经发展得比较成熟,容量提升空间已经比较小,想要进一步提高现有锂离子电池的能量密度,需要对锂离子电池的整个系统和工作原理有更深刻和全面的理解.存在于锂离子电池电极材料和电解液之间的固态电解质中间相(solid electrolyte interphase,SEI)已被证明是一个影响电池性能的重要因素,目前学术界和产业界对其认识还不是很全面,尤其是高分辨、工况下以及多技术联合的界面表征工作较少见到报道.原子力显微镜(atomic force microscopy,AFM)通过探测针尖与样品之间的相互作用力,能够在原子尺度上原位表征液态电池界面的形貌以及力学特性,对于电极界面的理解和调控非常重要.本文作者通过总结近几年AFM在锂离子电池SEI研究的中的应用,并结合本课题组在该领域的工作,对AFM技术在锂离子电池SEI研究中的应用做了总结和展望,对加深锂离子电池界面的理解,以及构建稳定锂电池界面的相关研究有参考意义.展开更多
Straightening machine is widely used for improving the quality of the defective mild steel plates.In general,the capacity of straightening machine is affected by material properties,the initial shape of the incoming p...Straightening machine is widely used for improving the quality of the defective mild steel plates.In general,the capacity of straightening machine is affected by material properties,the initial shape of the incoming plate and the plastic ratio.The mechanics model describing the capacity of the machine was developed.The deviation of the straightening capacity curves was studied.Then,the presented model was evaluated by comparative study to filed production data.Finally,the influences of overstretch,straightening speed,strengthening coefficient,elastic modulus,width of the plate on the straightening capacity were studied.It is convenient to determine whether the plate can be straightened or not by a series of straightening capacity curves.The straightening speed,width of the plate and elastic modulus of the material are more sensitive to the straightening capacity than the strengthening coefficient.展开更多
The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),trans...The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.展开更多
A viscoelastic micromechanical model is presented to predict the dynamic modulus of asphalt concrete （AC） and investigate the effect of imperfect interface between asphalt mastic and aggregates on the overall viscoe...A viscoelastic micromechanical model is presented to predict the dynamic modulus of asphalt concrete （AC） and investigate the effect of imperfect interface between asphalt mastic and aggregates on the overall viscoelastic characteristics of AC. The linear spring layer model is introduced to simulate the interface imperfection. Based on the effective medium theory, the viscoelastic micromechanical model is developed by two equivalence processes. The present prediction is compared with available experimental data to verify the developed framework. It is found that the proposed model has the capability to predict the dynamic modulus of AC. Interface effect on the dynamic modulus of AC is discussed using the developed model. It is shown that the interfacial bonding strength has a significant influence on the global mechanical performance of AC, and that continued improvement in surface fimctionalization is necessary to realize the full potential of aggregates reinforcement.展开更多
Based on fluid mechanics, thermodynamics and damage mechanics, thermal-hydro-mechanical （THM） coupling damage model of brittle rock is established by analyzing THM coupling mechanism, where THM coupling damage varia...Based on fluid mechanics, thermodynamics and damage mechanics, thermal-hydro-mechanical （THM） coupling damage model of brittle rock is established by analyzing THM coupling mechanism, where THM coupling damage variable DTHM is dominated by TH coupling damage variable DTH, TM coupling damage variable DTM and HM coupling damage variable DHM, and DTH is firstly expressed in term of dimensionless total thermal conductivity of the water Nu. Permeability test, uni-axial compression test and THM coupling test are conducted to measure the permeability, elastic modulus and THM coupling stress-strain curves of brittle rock. The tested values of THM coupling elastic modulus E＇HM are in good agreement with the predicted values of THM coupling elastic modulus ETHM, which can verify the newly established THM coupling damage model.展开更多
The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibr...The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibrium isotherms and a kinetic model.Additionally,the removal of Pb(Ⅱ) in leachate of litchi pericarps was also evaluated.The results show that litchi pericarps exhibit a high adsorption capacity to Pb(Ⅱ),with the maximum removal efficiency occurring at a temperature of 25 ℃,a pH of 6.0-7.0 and an adsorbent dosage of 10 g/L.Langmuir and Freundlich isotherms and the pseudo-second-order kinetic model can all fit the equilibrium adsorption satisfactorily,with correlation coefficients(R^2) of 0.9935,0.9918 and 1.0,respectively.An average removal efficiency of 66.65% is found for Pb(Ⅱ) in leachate of litchi pericarps.展开更多
In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characte...In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characteristics of the working processes in the TRPE, corresponding differential equations were established and then simplified by period features of the TRPE. Finally, the major boundary conditions were figured out. The changing trends of mass, pressure and temperature of working fuel in the working chamber during a complete engine cycle were presented. The simulation results are consistent with the trends of an actual working cycle in the TRPE, which indicates that the method of simulation is feasible. As the pressure in the working chamber is calculated, all the performance parameters of the TRPE can be obtained. The major performance indicators, such as the indicated mean effective pressure, power to weight ratio and the volume power, are also acquired. Compared with three different types of conventional engines, the TRPE has a bigger utilization ratio of cylinder volume, a higher power to weight ratio and a more compact structure. This indicates that TRPE is superior to conventional engines.展开更多
A novel modified Rayleigh model was developed for compensating hysteresis problem of an atomic force microscope(AFM) scanner.In high driving fields,piezoelectric actuators that integrated a scanner have severe hystere...A novel modified Rayleigh model was developed for compensating hysteresis problem of an atomic force microscope(AFM) scanner.In high driving fields,piezoelectric actuators that integrated a scanner have severe hysteresis,which can cause serious displacement errors.Piezoelectric hysteresis is from various origins including movement of defects,grain boundary effects,and displacement of interfaces.Furthermore,because its characteristic is stochastic,it is almost impossible to predict the piezoelectric hysteresis analytically.Therefore,it was predicted phenomenologically,which means that the relationship between inputs and outputs is formulated.The typical phenomenological approach is the Rayleigh model.However,the model has the discrepancy with experiment result as the fields increase.To overcome the demerit of the Rayleigh model,a modified Rayleigh model was proposed.In the modified Rayleigh model,each coefficient should be defined differently according to the field direction due to the increase of the asymmetry in the high fields.By applying an inverse form of this modified Rayleigh model to an AFM scanner,it is proved that hysteresis can be compensated to a position error of less than 5%.This model has the merits of reducing complicated fitting procedures and saving computation time compared with the Preisach model.展开更多
Surface effects play an important role in the mechanical behavior of nanosized structural elements owing to the increased ratio of surface area to volume. The surface effects on the large deflection of nanowires were ...Surface effects play an important role in the mechanical behavior of nanosized structural elements owing to the increased ratio of surface area to volume. The surface effects on the large deflection of nanowires were considered. Both geometric nonlinearity in finite deformation and surface effects at nanoscale were taken into account to analyze the bending of nanowires subjected to a concentrated force. For simply supported beams and clamped-clamped beams, the influence of surface effects and geometric nonlinearity were discussed in detail. It is found that both surface effects and geometric nonlinearity tend to decrease the deflection of bending nanowires and thus increase the effective elastic modulus of nanowires. Surface effects yield the size dependent behavior of nanowires.展开更多
Abstract： With the substitution of part Mg in LaMg3 by Cu, the elastic constants CH and C12 increase while C44 decreases, implying an enhanced Poisson effect and smaller resistance to 〈001〉（100） shear. Furthermor...Abstract： With the substitution of part Mg in LaMg3 by Cu, the elastic constants CH and C12 increase while C44 decreases, implying an enhanced Poisson effect and smaller resistance to 〈001〉（100） shear. Furthermore, the bulk modulus B increases, while the shear modulus G, elastic modulus E and anisotropie ratio A are reduced. The calculated Debye temperature of LaCuMg2 is lower, implying the weaker interaction between atoms in LaCuMg2. Then, the stress-strain curves in entire range and the ideal strength at critical strain are studied. The present results show that the lowest ideal tensile strength for LaMg3 and LaCuMg2 is in the 〈100〉 direction. The ideal shear strength on the 〈 1 ^-1 0〉（110） slip system of LaMg3 is greater than LaCuMg2. The density of states and charge density distribution are further studied to understand the inherent mechanism of the mechanical properties.展开更多
基金Project(2022J318)supported by the Natural Science Foundation of Ningbo,ChinaProject(2021A1515110525)supported by the Guangdong Basic and Applied Basic Research Foundation,ChinaProject(2022QN05023)supported by the Inner Mongolia Natural Science Foundation Youth Project,China。
文摘In order to obtain high-density dual-scale ceramic particles(8.5 wt.%SiC+1.5 wt.%TiC)reinforced Al-Mg Sc-Zr composites with uniform microstructure,50 nm TiC and 7μm SiC particles were pre-dispersed into 15−53μm aluminum alloy powders by low-speed ball milling and mechanical mixing technology,respectively.Then,the effects of laser energy density,power and scanning rate on the density of the composites were investigated based on selective laser melting(SLM)technology.The effect of micron-sized SiC and nano-sized TiC particles on solidification structure,mechanical properties and fracture behaviors of the composites was revealed and analyzed in detail.Interfacial reaction and phase variations in the composites with varying reinforced particles were emphatically considered.Results showed that SiC-TiC particles could significantly improve forming quality and density of the SLMed composites,and the optimal relative density was up to 100%.In the process of laser melting,a strong chemical reaction occurs between SiC and aluminum matrix,and micron-scale acicular Al_(4)SiC_(4) bands were formed in situ.There was no interfacial reaction between TiC particles and aluminum matrix.TiC/Al semi-coherent interface had good bonding strength.Pinning effect of TiC particles in grain boundaries could prevent the equiaxial crystals from growing and transforming into columnar crystals,resulting in grain refinement.The optimal ultimate tensile strength(UTS),yield strength(YS),elongation(EL)and elastic modulus of the SiC-TiC/Al-Mg-Sc-Zr composite were~394 MPa,~262 MPa,~8.2%and~86 GPa,respectively.The fracture behavior of the composites included ductile fracture of Al matrix and brittle cleavage fracture of Al_(4)SiC_(4) phases.A large number of cross-distributed acicular Al_(4)SiC_(4) bands were the main factors leading to premature failure and fracture of SiC-TiC/Al-Mg-Sc-Zr composites.
文摘近几年,电动汽车市场的飞速发展对锂离子电池的能量密度和安全性提出了更高的要求.然而,过去近30年,在应用终端市场的大力推动下,锂离子电池的电极材料、电池结构设计和生产工艺都已经发展得比较成熟,容量提升空间已经比较小,想要进一步提高现有锂离子电池的能量密度,需要对锂离子电池的整个系统和工作原理有更深刻和全面的理解.存在于锂离子电池电极材料和电解液之间的固态电解质中间相(solid electrolyte interphase,SEI)已被证明是一个影响电池性能的重要因素,目前学术界和产业界对其认识还不是很全面,尤其是高分辨、工况下以及多技术联合的界面表征工作较少见到报道.原子力显微镜(atomic force microscopy,AFM)通过探测针尖与样品之间的相互作用力,能够在原子尺度上原位表征液态电池界面的形貌以及力学特性,对于电极界面的理解和调控非常重要.本文作者通过总结近几年AFM在锂离子电池SEI研究的中的应用,并结合本课题组在该领域的工作,对AFM技术在锂离子电池SEI研究中的应用做了总结和展望,对加深锂离子电池界面的理解,以及构建稳定锂电池界面的相关研究有参考意义.
文摘Straightening machine is widely used for improving the quality of the defective mild steel plates.In general,the capacity of straightening machine is affected by material properties,the initial shape of the incoming plate and the plastic ratio.The mechanics model describing the capacity of the machine was developed.The deviation of the straightening capacity curves was studied.Then,the presented model was evaluated by comparative study to filed production data.Finally,the influences of overstretch,straightening speed,strengthening coefficient,elastic modulus,width of the plate on the straightening capacity were studied.It is convenient to determine whether the plate can be straightened or not by a series of straightening capacity curves.The straightening speed,width of the plate and elastic modulus of the material are more sensitive to the straightening capacity than the strengthening coefficient.
基金Project(2016YFB0300802)supported by the National Key Research and Development Program of China。
文摘The effect of Li(2.0 wt%)addition on mechanical properties and ageing precipitation behavior of Al-3.0 Mg 0.5 Si was investigated by tensile test,dynamic elasticity modulus test,scanning electron microscopy(SEM),transmission electron microscopy(TEM)and high-resolution transmission electron microscopy(HRTEM)images.The results show that the tensile strength of the Li-containing alloy can be significantly improved;however,the ductility is sharply decreased and the fracture mechanism changes from ductile fracture to intergranular fracture.The elasticity modulus of the Li-containing alloy increases by 11.6%compared with the base alloy.The microstructure observation shows that the Li addition can absolutely change the precipitation behavior of the base alloy,andδ′-Al_(3)Li phase becomes the main precipitates.Besides,β′′-Mg_(2)Si andδ′-Al_(3)Li dual phases precipitation can be visibly observed at 170℃ ageing for 100 h,although the quantity ofδ′-Al_(3)Li phase is more thanβ′′-Mg_(2)Si phase.The width of the precipitate-free zone(PFZ)of the Li-containing alloy is much wider at the over-ageing state than the base alloy,which has a negative impact on the ductile and results in the decrease of elongation.
基金Project(51408173)supported by the National Natural Science Foundation of China
文摘A viscoelastic micromechanical model is presented to predict the dynamic modulus of asphalt concrete （AC） and investigate the effect of imperfect interface between asphalt mastic and aggregates on the overall viscoelastic characteristics of AC. The linear spring layer model is introduced to simulate the interface imperfection. Based on the effective medium theory, the viscoelastic micromechanical model is developed by two equivalence processes. The present prediction is compared with available experimental data to verify the developed framework. It is found that the proposed model has the capability to predict the dynamic modulus of AC. Interface effect on the dynamic modulus of AC is discussed using the developed model. It is shown that the interfacial bonding strength has a significant influence on the global mechanical performance of AC, and that continued improvement in surface fimctionalization is necessary to realize the full potential of aggregates reinforcement.
基金Project(11072269) supported by the National Natural Science Foundation of ChinaProject(20090162110066) supported by the Research Fund for the Doctoral Program of Higher Education of China
文摘Based on fluid mechanics, thermodynamics and damage mechanics, thermal-hydro-mechanical （THM） coupling damage model of brittle rock is established by analyzing THM coupling mechanism, where THM coupling damage variable DTHM is dominated by TH coupling damage variable DTH, TM coupling damage variable DTM and HM coupling damage variable DHM, and DTH is firstly expressed in term of dimensionless total thermal conductivity of the water Nu. Permeability test, uni-axial compression test and THM coupling test are conducted to measure the permeability, elastic modulus and THM coupling stress-strain curves of brittle rock. The tested values of THM coupling elastic modulus E＇HM are in good agreement with the predicted values of THM coupling elastic modulus ETHM, which can verify the newly established THM coupling damage model.
基金Project(51208173)supported by the National Natural Science Foundation of ChinaProject(ZR2014EEM005)supported by the Natural Science Foundation of Shandong Province,China
文摘The adsorption capacity of Pb(Ⅱ) on litchi pericarps was investigated as a function of temperature,pH,and adsorbent dose using batch experiments.The experimental data obtained were evaluated using adsorption equilibrium isotherms and a kinetic model.Additionally,the removal of Pb(Ⅱ) in leachate of litchi pericarps was also evaluated.The results show that litchi pericarps exhibit a high adsorption capacity to Pb(Ⅱ),with the maximum removal efficiency occurring at a temperature of 25 ℃,a pH of 6.0-7.0 and an adsorbent dosage of 10 g/L.Langmuir and Freundlich isotherms and the pseudo-second-order kinetic model can all fit the equilibrium adsorption satisfactorily,with correlation coefficients(R^2) of 0.9935,0.9918 and 1.0,respectively.An average removal efficiency of 66.65% is found for Pb(Ⅱ) in leachate of litchi pericarps.
基金Project(7131109)supported by the National Defense Pre-research Foundation of ChinaProject(51175500)supported by the National Natural Science Foundation of China
文摘In order to study the major performance indicators of the twin-rotor piston engine(TRPE), Matlab/simulink was used to simulate the mathematical models of its thermodynamic processes. With consideration of the characteristics of the working processes in the TRPE, corresponding differential equations were established and then simplified by period features of the TRPE. Finally, the major boundary conditions were figured out. The changing trends of mass, pressure and temperature of working fuel in the working chamber during a complete engine cycle were presented. The simulation results are consistent with the trends of an actual working cycle in the TRPE, which indicates that the method of simulation is feasible. As the pressure in the working chamber is calculated, all the performance parameters of the TRPE can be obtained. The major performance indicators, such as the indicated mean effective pressure, power to weight ratio and the volume power, are also acquired. Compared with three different types of conventional engines, the TRPE has a bigger utilization ratio of cylinder volume, a higher power to weight ratio and a more compact structure. This indicates that TRPE is superior to conventional engines.
基金Project supported by the Second Stage of Brain Korea 21 ProjectProject supported by the Korea Science and Engineering Foundation (KOSEF) through the National Research Laboratory Program Funded by the Ministry of Science and TechnologyProject supported by Changwon National University,Korea
文摘A novel modified Rayleigh model was developed for compensating hysteresis problem of an atomic force microscope(AFM) scanner.In high driving fields,piezoelectric actuators that integrated a scanner have severe hysteresis,which can cause serious displacement errors.Piezoelectric hysteresis is from various origins including movement of defects,grain boundary effects,and displacement of interfaces.Furthermore,because its characteristic is stochastic,it is almost impossible to predict the piezoelectric hysteresis analytically.Therefore,it was predicted phenomenologically,which means that the relationship between inputs and outputs is formulated.The typical phenomenological approach is the Rayleigh model.However,the model has the discrepancy with experiment result as the fields increase.To overcome the demerit of the Rayleigh model,a modified Rayleigh model was proposed.In the modified Rayleigh model,each coefficient should be defined differently according to the field direction due to the increase of the asymmetry in the high fields.By applying an inverse form of this modified Rayleigh model to an AFM scanner,it is proved that hysteresis can be compensated to a position error of less than 5%.This model has the merits of reducing complicated fitting procedures and saving computation time compared with the Preisach model.
基金Project(11072186)supported by the National Natural Science Foundation of China
文摘Surface effects play an important role in the mechanical behavior of nanosized structural elements owing to the increased ratio of surface area to volume. The surface effects on the large deflection of nanowires were considered. Both geometric nonlinearity in finite deformation and surface effects at nanoscale were taken into account to analyze the bending of nanowires subjected to a concentrated force. For simply supported beams and clamped-clamped beams, the influence of surface effects and geometric nonlinearity were discussed in detail. It is found that both surface effects and geometric nonlinearity tend to decrease the deflection of bending nanowires and thus increase the effective elastic modulus of nanowires. Surface effects yield the size dependent behavior of nanowires.
基金Project(51071053)supported by the National Natural Science Foundation of ChinaProject(X071117)supported by the Scientific Research Foundation of Guangxi University,ChinaProject(KF0803)supported by the Open Project of Key Laboratory of Materials Design and Preparation Technology of Hunan Province,China
文摘Abstract： With the substitution of part Mg in LaMg3 by Cu, the elastic constants CH and C12 increase while C44 decreases, implying an enhanced Poisson effect and smaller resistance to 〈001〉（100） shear. Furthermore, the bulk modulus B increases, while the shear modulus G, elastic modulus E and anisotropie ratio A are reduced. The calculated Debye temperature of LaCuMg2 is lower, implying the weaker interaction between atoms in LaCuMg2. Then, the stress-strain curves in entire range and the ideal strength at critical strain are studied. The present results show that the lowest ideal tensile strength for LaMg3 and LaCuMg2 is in the 〈100〉 direction. The ideal shear strength on the 〈 1 ^-1 0〉（110） slip system of LaMg3 is greater than LaCuMg2. The density of states and charge density distribution are further studied to understand the inherent mechanism of the mechanical properties.
