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液态银制氧搅拌槽结构优化
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作者 单显祥 刘剑雄 +1 位作者 李天骕 李堪鹏 《化工设备与管道》 北大核心 2025年第2期77-86,共10页
冶金、化工、医疗和航空航天等领域的用氧需求越来越大,为了提高液态银的制氧速率,通过理论推导出制氧腔氧气压力为零时液态银制氧速率最大,1243 K时,制氧速率最大为4.0747×10^(-8)mol·cm^(-2)·s^(-1)。为使液态银中的... 冶金、化工、医疗和航空航天等领域的用氧需求越来越大,为了提高液态银的制氧速率,通过理论推导出制氧腔氧气压力为零时液态银制氧速率最大,1243 K时,制氧速率最大为4.0747×10^(-8)mol·cm^(-2)·s^(-1)。为使液态银中的氧加速扩散,用搅拌装置对银液进行搅拌,以桨叶转速,搅拌槽直径和桨叶间距为考察因素,基于计算流体力学(CFD)技术,采用组分运输模型、多重参考系模型、标准k-ε湍流模型,对制氧搅拌槽进行优化模拟研究,用三因素三水平响应面法进行多因素方差分析。以增大制氧速率为主,兼顾搅拌功率最小为优化目标,优化结果为:桨叶转速为708 r/min,搅拌槽直径为390.3 mm,桨叶间距为484.3 mm,即桨径槽径比为0.77。通过搅拌加快了氧向制氧腔液面的扩散速度,增大了制氧速率。 展开更多
关键词 制氧速率 搅拌槽 数值模拟 响应面优化 速度场
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Effect of ferrite content on dissolution kinetics of gibbsitic bauxite under atmospheric pressure in NaOH solution 被引量:2
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作者 YANG Hui-bin 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第3期489-495,共7页
The dissolution property of high-ferrite gibbsitic bauxite and the effect of ferrite content on the dissolution kinetics of gibbsitic bauxites in sodium hydroxide solution under atmospheric pressure from 50 to 90 ... The dissolution property of high-ferrite gibbsitic bauxite and the effect of ferrite content on the dissolution kinetics of gibbsitic bauxites in sodium hydroxide solution under atmospheric pressure from 50 to 90 °C were systematically investigated.The dissolution property of high-ferrite gibbsitic bauxite is increased by increasing the dissolution temperature and the Na OH concentration or decreasing the particle size of bauxite,which is easy to dissolve under atmospheric pressure.The kinetic equations of gibbsitic bauxites with different ferrite contents during the dissolution process at different temperatures for different times were established,and the corresponding activation energies were calculated.The ferrite in the gibbsitic bauxite reduces the dissolution speed and increases the activation energy of dissolution,the diffusion process of which is the rate-controlling step. 展开更多
关键词 gibbsitic bauxite DISSOLUTION KINETICS FERRITE Bayer process
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