文章根据并联同步开关电感收集(parallel synchronized switch harvesting on inductor,P-SSHI)技术,提出一种自供电的压电能量收集系统,实现了在低激励环境下的系统启动和电压输出功能,并基于压电材料分离电极理论设计冷启动电路。该...文章根据并联同步开关电感收集(parallel synchronized switch harvesting on inductor,P-SSHI)技术,提出一种自供电的压电能量收集系统,实现了在低激励环境下的系统启动和电压输出功能,并基于压电材料分离电极理论设计冷启动电路。该系统采用带有有源二极管的P-SSHI整流电路代替传统的整流结构,以减少整流过程的能量损耗,能够在动态范围内调节输出电压,实现多输出负载的功能。基于0.18μm CMOS工艺仿真结果表明,该系统的电压翻转效率达到85%,输出功率是采用传统整流电路的5.8倍,同时能够产生1.2、1.8 V 2种电压,用于不同负载供电。该自供电能量收集系统可用于解决物联网无线传感器网络节点的自供电问题。展开更多
Bioflotation represents one of the growing trends to enhance the selectivity of conventional flotation processes. It utilizes the micro-organisms to replace or to interact with the chemical reagents to increase the ga...Bioflotation represents one of the growing trends to enhance the selectivity of conventional flotation processes. It utilizes the micro-organisms to replace or to interact with the chemical reagents to increase the gap between surface properties of similar minerals and to enhance the separation selectivity. In this work, dolomite-phosphate separation was investigated using amphoteric collector （dodecyl-N-carboxyethyl-N-hyroxyethyl-imidazoline） in presence of bacteria. Two types of bacteria, Corynebacterium- diphtheriae-intermedius （CDI）, and Pseudomonas aeruginosa （PA）, were used. The collector-bacteria interaction was characterized by Fourier transform infra-red （FTIR）, frothing height and Zeta potential. The results show that the collector-bacteria interaction improves the flotation selectivity. Although, the PA positively affects the separation results, the CDI cannot lower the MgO to less than 1%. A phosphate content of 0.7% MgO and 31.77% P205 with a recovery of 68% at pH 11, 3.0 kg/t amphoteric collector, 4× 10^7 cells of PA is obtained.展开更多
Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structu...Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structures and characteristics of the carbon materials were determined by X-ray diffraction, Brunauer-Emmer-Teller surface area analysis and electrochemical measurements. With the increase of pyrolyzing temperature and soaking time, the resin carbon material has larger crystallite sizes of L_c and L_a, lower specific surface area, smaller irreversible capacity and higher initial coulombic efficiency. The pyrolyzing temperature and soaking time are optimized to be 1050℃ and 2h. The resin carbon anode obtained under the optimum conditions shows good electrochemical performances with reversible capacity of 387mA·h/g and initial coulombic efficiency of 69.1%.展开更多
Electrochimcal behaviors of rusticyanin （Rus.） isolated from Acidithiobacillus ferrooxidans were investigated through Rus.-ZnS-QDs/L-Cys/Au electrode. The cyclic voltammetric results indicate that rusticyanin immobi...Electrochimcal behaviors of rusticyanin （Rus.） isolated from Acidithiobacillus ferrooxidans were investigated through Rus.-ZnS-QDs/L-Cys/Au electrode. The cyclic voltammetric results indicate that rusticyanin immobilized on the surface of Rus.-ZnS-QDs/L-Cys/Au electrode can undergo a direct quasi-reversible electrochemical reaction. The immobilized rusticyanin is not denatured and still retains its activity in the temperature range of 19-43 ℃. The reduction ability of the protein increases and its oxidation ability becomes weak with the increase of pH from 6.0 to 7.8. Fe^2＋ ions in the solution can promote the electron transfer kinetics of the immobilized rusticyanin and make its peak potentials （φp） markedly move negatively.展开更多
文摘文章根据并联同步开关电感收集(parallel synchronized switch harvesting on inductor,P-SSHI)技术,提出一种自供电的压电能量收集系统,实现了在低激励环境下的系统启动和电压输出功能,并基于压电材料分离电极理论设计冷启动电路。该系统采用带有有源二极管的P-SSHI整流电路代替传统的整流结构,以减少整流过程的能量损耗,能够在动态范围内调节输出电压,实现多输出负载的功能。基于0.18μm CMOS工艺仿真结果表明,该系统的电压翻转效率达到85%,输出功率是采用传统整流电路的5.8倍,同时能够产生1.2、1.8 V 2种电压,用于不同负载供电。该自供电能量收集系统可用于解决物联网无线传感器网络节点的自供电问题。
文摘Bioflotation represents one of the growing trends to enhance the selectivity of conventional flotation processes. It utilizes the micro-organisms to replace or to interact with the chemical reagents to increase the gap between surface properties of similar minerals and to enhance the separation selectivity. In this work, dolomite-phosphate separation was investigated using amphoteric collector （dodecyl-N-carboxyethyl-N-hyroxyethyl-imidazoline） in presence of bacteria. Two types of bacteria, Corynebacterium- diphtheriae-intermedius （CDI）, and Pseudomonas aeruginosa （PA）, were used. The collector-bacteria interaction was characterized by Fourier transform infra-red （FTIR）, frothing height and Zeta potential. The results show that the collector-bacteria interaction improves the flotation selectivity. Although, the PA positively affects the separation results, the CDI cannot lower the MgO to less than 1%. A phosphate content of 0.7% MgO and 31.77% P205 with a recovery of 68% at pH 11, 3.0 kg/t amphoteric collector, 4× 10^7 cells of PA is obtained.
文摘Pyrolytic resin carbon anode for lithoum ion batteries was prepared from thermosetting phenolic resin. Pyrolysis of the primary phenolic resin and the dewatered one was studied by thermal gravimetric analysis. Structures and characteristics of the carbon materials were determined by X-ray diffraction, Brunauer-Emmer-Teller surface area analysis and electrochemical measurements. With the increase of pyrolyzing temperature and soaking time, the resin carbon material has larger crystallite sizes of L_c and L_a, lower specific surface area, smaller irreversible capacity and higher initial coulombic efficiency. The pyrolyzing temperature and soaking time are optimized to be 1050℃ and 2h. The resin carbon anode obtained under the optimum conditions shows good electrochemical performances with reversible capacity of 387mA·h/g and initial coulombic efficiency of 69.1%.
基金Project(2010CB630903) supported by the National Basic Research Program of ChinaProject(50621063) supported by the National Natural Science Foundation of China
文摘Electrochimcal behaviors of rusticyanin （Rus.） isolated from Acidithiobacillus ferrooxidans were investigated through Rus.-ZnS-QDs/L-Cys/Au electrode. The cyclic voltammetric results indicate that rusticyanin immobilized on the surface of Rus.-ZnS-QDs/L-Cys/Au electrode can undergo a direct quasi-reversible electrochemical reaction. The immobilized rusticyanin is not denatured and still retains its activity in the temperature range of 19-43 ℃. The reduction ability of the protein increases and its oxidation ability becomes weak with the increase of pH from 6.0 to 7.8. Fe^2＋ ions in the solution can promote the electron transfer kinetics of the immobilized rusticyanin and make its peak potentials （φp） markedly move negatively.
