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烃源岩热模拟分子标志物演化特征及分子解析 被引量:4
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作者 魏彩云 张斌 +4 位作者 胡国艺 帅燕华 陈琰 张静 刘玉娥 《地球化学》 CAS CSCD 北大核心 2021年第6期602-611,共10页
为了研究地质体中分子标志物随热成熟度的演化规律,开展了烃源岩热模拟实验,并对产物进行了分子标志物定量及分子解析。结果表明,随着模拟温度的增高,三环萜烷和藿烷含量均逐渐降低,但降低幅度有差异,藿烷和高相对分子质量的三环萜烷降... 为了研究地质体中分子标志物随热成熟度的演化规律,开展了烃源岩热模拟实验,并对产物进行了分子标志物定量及分子解析。结果表明,随着模拟温度的增高,三环萜烷和藿烷含量均逐渐降低,但降低幅度有差异,藿烷和高相对分子质量的三环萜烷降低幅度大于低相对分子质量的三环萜烷,导致在热模拟温度升至370℃的情况下,低相对分子质量三环萜烷的峰高高于藿烷;高相对分子质量甾烷含量降低幅度大于低相对分子质量甾烷,相同相对分子质量不同构型化合物甾烷热解速率不一致,同碳数ααα甾烷热解速率大于αββ甾烷,低相对分子质量的甾烷定量结果随热模拟温度升高先降低后升高再降低;低碳数的芳烃含量随热模拟温度升高先降低后升高,高碳数芳烃含量则一直处于降低状态。分子解析认为,C_(19)和C_(20)三环萜烷主要来自于高碳数三环萜烷的裂解,藿烷的贡献极低;17α(H)C_(27)三降藿烷(Tm)来自高碳数藿烷的贡献,18α(H)C;三降藿烷(Ts)没有其他化合物加入;相同质量前提下,C_(29)甾烷裂解速率为:C_(29)ααS>C_(29)ααR>C_(29)ββS>C_(29)ββR;孕甾烷和升孕甾烷含量升高来自高碳数甾烷的裂解;低碳数的芳烃含量随温度升高来源广泛,高碳数芳烃主要起裂解作用。 展开更多
关键词 热模拟 分子标志物 分子解析 定量结果 热解速率
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一株高耐受粗甘油枯草芽孢杆菌的分子机制研究
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作者 贾晨阳 张帆 +2 位作者 刘兰茜 王光路 杨雪鹏 《轻工学报》 2025年第5期44-54,共11页
选取高耐受粗甘油的枯草芽孢杆菌为研究对象,利用全基因组和转录组测序技术解析其对高质量浓度粗甘油的耐受机制。结果表明:进化菌株中检测到23个突变基因,涉及ABC转运系统、烟酸与烟酰胺代谢、群体感应、芽孢生成等关键途径。相比出发... 选取高耐受粗甘油的枯草芽孢杆菌为研究对象,利用全基因组和转录组测序技术解析其对高质量浓度粗甘油的耐受机制。结果表明:进化菌株中检测到23个突变基因,涉及ABC转运系统、烟酸与烟酰胺代谢、群体感应、芽孢生成等关键途径。相比出发菌株,进化菌株在甘油(酯)代谢、三羧酸循环、嘌呤代谢、ABC转运系统、能量代谢等途径中的基因表达显著上调,脂肪酸和生物素合成代谢也明显增强;部分丧失芽孢生成能力,稳定中期和后期的芽孢生成率分别下降了38.0%和52.3%;细胞膜新增6种成分,脂肪酸种类和质量浓度均显著增加,磷脂双分子层稳定性增强,这是其高粗甘油耐受性和快速生长的关键原因。 展开更多
关键词 枯草芽孢杆菌 粗甘油耐受 分子机制解析 全基因组测序 转录组测序
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System failure analysis based on DEMATEL–ISM and FMECA 被引量:2
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作者 申桂香 孙曙光 +3 位作者 张英芝 王志琼 陈炳锟 马闯 《Journal of Central South University》 SCIE EI CAS 2014年第12期4518-4525,共8页
A new method of system failure analysis was proposed. First, considering the relationships between the failure subsystems,the decision making trial and evaluation laboratory(DEMATEL) method was used to calculate the d... A new method of system failure analysis was proposed. First, considering the relationships between the failure subsystems,the decision making trial and evaluation laboratory(DEMATEL) method was used to calculate the degree of correlation between the failure subsystems, analyze the combined effect of related failures, and obtain the degree of correlation by using the directed graph and matrix operations. Then, the interpretative structural modeling(ISM) method was combined to intuitively show the logical relationship of many failure subsystems and their influences on each other by using multilevel hierarchical structure model and obtaining the critical subsystems. Finally, failure mode effects and criticality analysis(FMECA) was used to perform a qualitative hazard analysis of critical subsystems, determine the critical failure mode, and clarify the direction of reliability improvement.Through an example, the result demonstrates that the proposed method can be efficiently applied to system failure analysis problems. 展开更多
关键词 system failure analysis related failure decision making and evaluation laboratory-interpretative structural modeling(DEMATEL-ISM) failure mode effects and criticality analysis(FMECA)
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Pyrolysis and combustion kinetics of lycopodium particles in thermogravimetric analysis 被引量:1
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作者 Seyed Alireza Mostafavi Sadjad Salavati +1 位作者 Hossein Beidaghy Dizaji Mehdi Bidabadi 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第9期3409-3417,共9页
Biomass is a kind of renewable energy which is used increasingly in different types of combustion systems or in the production of fuels like bio-oil. Lycopodium is a cellulosic particle, with good combustion propertie... Biomass is a kind of renewable energy which is used increasingly in different types of combustion systems or in the production of fuels like bio-oil. Lycopodium is a cellulosic particle, with good combustion properties, of which microscopic images show that these particles have spherical shapes with identical diameters of 31 μm. The measured density of these particles is 1.0779 g/cm2. Lycopodium particles contain 64.06% carbon, 25.56% oxygen, 8.55% hydrogen and 1.83% nitrogen, and no sulfur. Thermogravimetric analysis in the nitrogen environment indicates that the maximum of particle mass reduction occurs in the temperature range of 250-550 ℃ where the maximum mass reduction in the DTG diagrams also occurs in. In the oxygen environment, an additional peak can also be observed in the temperature range of 500-600 ℃, which points to solid phase combustion and ignition temperature of lycopodium particles. The kinetics of reactions is determined by curve fitting and minimization of error. 展开更多
关键词 lycopodium dust particles thermogravimetric analysis PYROLYSIS COMBUSTION ignition temperature chemical kinetics
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