A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O c...A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O crystal crystallizes in the monoclinic system, space group C2/m , with M=128.13, a =0\^994 7(2) nm, b =1.321 7(3) nm; c =0.463 6(1) nm; β=104.80(3)°, V =0.589 3(2) nm 3, Z=2, R=0.027 2 and wR =0.057 5. The network structure consists of vertex sharing which results in the formation of undulating 4 ring chains and 8 ring sheets.展开更多
文摘A new two dimensional 8 ring network nickle phosphate Ni 3(PO 4) 2·8H 2O was synthesized hydrothermally and its structure was determined by means of single crystal X ray diffraction. The Ni 3(PO 4) 2·8H 2O crystal crystallizes in the monoclinic system, space group C2/m , with M=128.13, a =0\^994 7(2) nm, b =1.321 7(3) nm; c =0.463 6(1) nm; β=104.80(3)°, V =0.589 3(2) nm 3, Z=2, R=0.027 2 and wR =0.057 5. The network structure consists of vertex sharing which results in the formation of undulating 4 ring chains and 8 ring sheets.
