A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of t...A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of the AZ91D magnesium alloy against the GCr15 bearing steel under lubrication of rapeseed oil containing BNR were evaluated on a SRV tribotester.The topography and chemical species of the worn surfaces of magnesium alloy were analyzed by a scanning electron microscope (SEM) and an X-ray photoelectron spectroscope (XPS),respectively.The test results indicated that the friction and wear of the magnesium alloy-steel tribomates could be effectively reduced by incorporating BNR into the rapeseed oil lubricant.The friction coefficients and the wear scars of magnesium alloy decreased with an increasing content of BNR.The surface lubricated with the BNR-doped rapeseed oil demonstrated less wear as compared with that lubricated with neat rapeseed oil.The enhanced anti-wear and friction-reducing abilities of rapeseed oil provided by BNR in the lubrication of magnesium alloy against steel were ascribed to the formation of a composite boundary lubrication film due to the strong adsorption of BNR and rapeseed oil onto the lubricated surfaces and their tribochemical reactions with magnesium alloy.展开更多
The friction and wear characteristics of lauroyl glutamine, lauroyl glycine and lauroyl alanine, used as green additives in HVI 350 mineral lubricating oil, were evaluated on a four-ball tribotester. The morphologies ...The friction and wear characteristics of lauroyl glutamine, lauroyl glycine and lauroyl alanine, used as green additives in HVI 350 mineral lubricating oil, were evaluated on a four-ball tribotester. The morphologies and chemical species of the worn surfaces were analyzed by scanning electron microscope （SEM） and X-ray photoelectron spectroscope （XPS）, respectively. The test results indicated that the three fatty acyl amino acids could effectively improve the anti-wear and friction-reducing abilities of the HVI 350 mineral oil. The improvement in anti-wear and friction-reducing abilities of the mineral oil by the related amino acids was mainly ascribed to the formation of a composite boundary lubrication film due to the adsorption of amino acids on the friction surfaces.展开更多
Nano-metric magnesium silicate and zinc silicate with particle size of about 50-70nm were prepared in water by the method of chemical deposition. The antiwear and friction reducing abilities of the nano-silicates, as ...Nano-metric magnesium silicate and zinc silicate with particle size of about 50-70nm were prepared in water by the method of chemical deposition. The antiwear and friction reducing abilities of the nano-silicates, as well as their composites with oleic acid tri-ethanolamine （OATEA）, were evaluated on a four-ball friction tester. The topographies and tribochemical features of the worn surfaces were analyzed by scanning electron microscope （SEM） and X-ray photoelectron spectroscope （XPS）. Results show that nano-silicates alone provide poor antiwear and friction reducing abilities in water, but exhibits excellent synergism with OATEA in reducing friction and wear. The synergism in reducing friction and wear between nano- silicates and OATEA does exist almost regardless of particte sizes and species, and may be attributed, on one hand, to the formation of an adsorption film of OATEA, and, on the other hand, to the formation oftribochemical species of silicon dioxide and iron oxides on the friction surfaces. Tribo-reactions and tribo-adsorptions of nano-silicates and OATEA would produce hereby an effective composite boundary lubrication film, which could efficiently enhance the anti-wear and friction-reducing abilities of water.展开更多
In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scannin...In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron microscope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.展开更多
By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy ...By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.展开更多
基金the financial support from the National Natural Science Foundation of China (project No. 50975282)
文摘A BN-containing additive,the boron and nitrogen modified rapeseed oil (abbreviated as BNR),was prepared by chemical modification of rapeseed oil with boric and nitrous compounds.The friction and wear performances of the AZ91D magnesium alloy against the GCr15 bearing steel under lubrication of rapeseed oil containing BNR were evaluated on a SRV tribotester.The topography and chemical species of the worn surfaces of magnesium alloy were analyzed by a scanning electron microscope (SEM) and an X-ray photoelectron spectroscope (XPS),respectively.The test results indicated that the friction and wear of the magnesium alloy-steel tribomates could be effectively reduced by incorporating BNR into the rapeseed oil lubricant.The friction coefficients and the wear scars of magnesium alloy decreased with an increasing content of BNR.The surface lubricated with the BNR-doped rapeseed oil demonstrated less wear as compared with that lubricated with neat rapeseed oil.The enhanced anti-wear and friction-reducing abilities of rapeseed oil provided by BNR in the lubrication of magnesium alloy against steel were ascribed to the formation of a composite boundary lubrication film due to the strong adsorption of BNR and rapeseed oil onto the lubricated surfaces and their tribochemical reactions with magnesium alloy.
基金the financial support from National Natural Science Foundation of China(project No.50975282)Chongqing Science Foundation for Outstanding Youth(project No. CSTC2008,BA4037)
文摘The friction and wear characteristics of lauroyl glutamine, lauroyl glycine and lauroyl alanine, used as green additives in HVI 350 mineral lubricating oil, were evaluated on a four-ball tribotester. The morphologies and chemical species of the worn surfaces were analyzed by scanning electron microscope （SEM） and X-ray photoelectron spectroscope （XPS）, respectively. The test results indicated that the three fatty acyl amino acids could effectively improve the anti-wear and friction-reducing abilities of the HVI 350 mineral oil. The improvement in anti-wear and friction-reducing abilities of the mineral oil by the related amino acids was mainly ascribed to the formation of a composite boundary lubrication film due to the adsorption of amino acids on the friction surfaces.
基金supported by the National Natural Science Foundation of China (No. 50275147)the Program for New Century Excellent Talents in Chinese University (No. NCET-04-1002)
文摘Nano-metric magnesium silicate and zinc silicate with particle size of about 50-70nm were prepared in water by the method of chemical deposition. The antiwear and friction reducing abilities of the nano-silicates, as well as their composites with oleic acid tri-ethanolamine （OATEA）, were evaluated on a four-ball friction tester. The topographies and tribochemical features of the worn surfaces were analyzed by scanning electron microscope （SEM） and X-ray photoelectron spectroscope （XPS）. Results show that nano-silicates alone provide poor antiwear and friction reducing abilities in water, but exhibits excellent synergism with OATEA in reducing friction and wear. The synergism in reducing friction and wear between nano- silicates and OATEA does exist almost regardless of particte sizes and species, and may be attributed, on one hand, to the formation of an adsorption film of OATEA, and, on the other hand, to the formation oftribochemical species of silicon dioxide and iron oxides on the friction surfaces. Tribo-reactions and tribo-adsorptions of nano-silicates and OATEA would produce hereby an effective composite boundary lubrication film, which could efficiently enhance the anti-wear and friction-reducing abilities of water.
基金Projects 2008BAB31B01 supported by the National Key Technology R&D Program in the 11th Five-Year Plan of China50834006 by the National Natural Science Foundation of China
文摘In our study we investigated a refractory copper-nickel sulfide ore separation by using a cyclonic-static micro-bubble flotation column (FCSMC). The process mineralogy of the main products was studied. Using a scanning electron microscope-energy dispersive system (SEM-EDS) and an X-ray spectrometer the mineral category and content of samples were analyzed. By using a mineral liberation analyzer (MLA) the mineral liberation characteristics were revealed. It is shown that in roughing feed the monomers liberation degree of nickel pyrite and chalcopyrite take up 84.11% and 88.82%, respectively. In tailings, the lost nickel pyrite and chalcopyrite are mainly monomers. Therefore, strengthening the micro-fine particle recovery capacity is the key to increase recovery.
基金Financial support from the SINOPEC Research Program(No.ST13164-19]) is gratefully acknowledged
文摘By using PAO-10 as the base oil, the tribological behavior of 11 additives under high vacuum condition was evaluated. By adopting some surface analytical instruments, such as scanning electron microscopy(SEM), energy dispersive spectroscopy(EDS) and X-ray photoelectron spectroscopy(XPS), the tribological mechanisms of these additives were studied. In air, O_2 can react with metal to form metal oxide that can protect the surfaces of rubbing pair during the tribological tests. According to the theory of the competitive adsorption, the function of some active elements is weakened. In a vacuum environment, the additives contributed more to the lubrication performance. The sulfur-containing additives could react with Fe to produce Fe Sx and "M—C" bonds("M" represents metal). They both had contributions to the lubrication. As for the phosphorus-containing additives, they only generated the phosphates during the tests. When the sulfur and phosphorus-containing additives were applied, the generated phosphates and Fe Sx had the primary contribution to the lubrication performance during the tests.
