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Preparation of ultrafine α-Al_2O_3 powders by catalytic sintering of ammonium aluminum carbonate hydroxide at low temperature 被引量:2
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作者 肖劲 邓华 +2 位作者 万烨 李劼 刘业翔 《Journal of Central South University of Technology》 2006年第4期367-372,共6页
The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate(Al2(SO4)3) and ammonium carbonate((NH4)2CO3). The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and... The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate(Al2(SO4)3) and ammonium carbonate((NH4)2CO3). The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts (AT) on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly. 展开更多
关键词 ammonium aluminum carbonate hydroxide phase transformation temperature Α-AL2O3 agglomerα- tion
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