The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate(Al2(SO4)3) and ammonium carbonate((NH4)2CO3). The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and...The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate(Al2(SO4)3) and ammonium carbonate((NH4)2CO3). The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts (AT) on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.展开更多
文摘The precursor of ammonium aluminum carbonate hydroxide was synthesized by using aluminum sulfate(Al2(SO4)3) and ammonium carbonate((NH4)2CO3). The effects of α-Al2O3 seeds and mixture composed of α-Al2O3 and ammonium nitrate, as well as multiplex catalysts (AT) on phase transformation of alumina in sintering process were investigated respectively. The results show that the α-Al2O3 seeds and the mixture of α-Al2O3 and ammonium nitrate can lower the phase transformation temperature of α-Al2O3 to different extents while the particles obtained agglomerate heavily. AT has great potential synergistic effects on the phase transformation of alumina and reduces the phase transformation temperature of α-Al2O3 and the trends of necking-formation between particles. Therefore the dispersion of powder particles is improved significantly.