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温度对焙烧Mg-Al水滑石体相结构和表面性质的影响 被引量:6
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作者 李大塘 董奇志 +1 位作者 罗娟 郭军 《湘潭大学自然科学学报》 CAS CSCD 2000年第1期42-45,共4页
研究了焙烧温度对焙烧MgAl水滑石体相结构和表面性质的影响 .在 6 73K、873K和 10 73K温度下焙烧样品的MAS2 7Al核磁共振结果呈现显著的物相转变 ,其转变中的过渡态对确定样品表面酸碱性质显得很重要 .
关键词 温度 镁-铝水滑石 表面性质 体相结构
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温度对Mg-Al-O复合氧化物催化剂体相和表面酸碱性质的影响 被引量:1
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作者 李大塘 龙云飞 郭军 《化学研究与应用》 CAS CSCD 2000年第3期273-277,共5页
用 NH3和 CO2 作探针分子 ,采用红外光谱 ,真空原位测定 Mg-Al-O复合氧化物表面酸碱中心的类型结果表明 ,主要存在 L 酸 ,碱中心是氧阴离子 ,而焙烧温度对样品表面碱中心的类型几乎没有影响 ,在 673、873和 1 0 73 K焙烧样品的固态 MAS2... 用 NH3和 CO2 作探针分子 ,采用红外光谱 ,真空原位测定 Mg-Al-O复合氧化物表面酸碱中心的类型结果表明 ,主要存在 L 酸 ,碱中心是氧阴离子 ,而焙烧温度对样品表面碱中心的类型几乎没有影响 ,在 673、873和 1 0 73 K焙烧样品的固态 MAS2 7Al核磁共振结果显示 ,样品呈现显著的物相转变 ,转变中的过渡态对确定它们表面酸碱性质显得非常重要。 XPS测定样品中 Al2 s和 O1s结合能与样品表面酸碱中心的强度相关。 展开更多
关键词 Mg-Al-O复合氧化物 体相结构 酸碱性质 催化剂
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锂离子电池三元层状氧化物正极材料失效模式分析 被引量:16
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作者 陈晓轩 李晟 +6 位作者 胡泳钢 郑时尧 柴云轩 李东江 左文华 张忠如 杨勇 《储能科学与技术》 CAS CSCD 2019年第6期1003-1016,共14页
镍钴锰三元层状氧化物(NCM)正极材料由于其优越的综合性能在动力/储能电池系统(ESS)领域得到广泛应用。虽然Ni含量的增加可提高三元材料的比容量及电池的能量密度,但相关电池体系的容量保持率和安全性将会变差。如何有效解决该矛盾是此... 镍钴锰三元层状氧化物(NCM)正极材料由于其优越的综合性能在动力/储能电池系统(ESS)领域得到广泛应用。虽然Ni含量的增加可提高三元材料的比容量及电池的能量密度,但相关电池体系的容量保持率和安全性将会变差。如何有效解决该矛盾是此类NCM电池所面临的关键问题。本文从NCM电池体系循环过程中常见的体相结构破坏和正极-电解液界面组成改变两方面失效现象出发,结合近年来国内外对NCM失效模式研究中所提出的新理论、方法、应用,从机械破坏、结构演变、电化学极化、化学副反应、正负极协同效应等多个角度对NCM材料的衰退机理提出见解,对指导电池用户合理制定充放电协议、缓解电动汽车(EV)里程焦虑乃至材料设计本身均有重要的指导及借鉴意义。 展开更多
关键词 锂离子电池 三元正极材料 失效现象 老化机理 表界面行为 体相结构
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几何受限下的嵌段共聚物自组装
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作者 曹瑞芳 陆尧 《胶体与聚合物》 2021年第1期45-49,共5页
嵌段共聚物通过自组装可以形成特定的周期性纳米结构,然而这些有限种类的体相结构却无法有效满足实际应用中的众多需求。为丰富嵌段共聚物自组装的纳米结构库,几何受限的引入是最为有效的方法之一。几何受限改变了体相结构的平移对称性... 嵌段共聚物通过自组装可以形成特定的周期性纳米结构,然而这些有限种类的体相结构却无法有效满足实际应用中的众多需求。为丰富嵌段共聚物自组装的纳米结构库,几何受限的引入是最为有效的方法之一。几何受限改变了体相结构的平移对称性,嵌段高分子为了缓解这一破坏带来的结构受挫,从而形成更多的新相结构。本文以AB两嵌段高分子为例,从本体相结构出发,系统总结了两嵌段共聚物在一维、二维和三维受限下各种新相结构的研究进展,以此阐述几何受限下的嵌段共聚物自组装所面临的机遇与挑战。 展开更多
关键词 嵌段共聚物 自组装 几何受限 体相结构
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A CFD Based Investigation of the Unsteady Hydrodynamic Coefficients of 3-D Fins in Viscous Flow 被引量:3
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作者 Nazir Zulfiqar 苏玉民 王兆立 《Journal of Marine Science and Application》 2010年第3期250-255,共6页
The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly ... The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly unsteady, generating vortices and requiring detailed analysis of fluid-structure interactions.An understanding of the complexities of such flows is of interest to engineers developing vehicles capable of high dynamic performance in their propulsion and maneuvering.In the present study, a CFD based RANS simulation of a 3-D fin body moving in a viscous fluid was developed.It investigated hydrodynamic performance by evaluating the hydrodynamic coefficients (lift, drag and moment) at two different oscillating frequencies.A parametric analysis of the factors that affect the hydrodynamic performance of the fin body was done, along with a comparison of results from experiments.The results of the simulation were found in close agreement with experimental results and this validated the simulation as an effective tool for evaluation of the unsteady hydrodynamic coefficients of 3-D fins.This work can be further be used for analysis of the stability and maneuverability of fin actuated underwater vehicles. 展开更多
关键词 oscillating 3-D fin RANS hydrodynamic performance viscous flow
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Investigation of acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure 被引量:3
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作者 WANG San-de YANG De-sen LIU Ning 《Journal of Marine Science and Application》 2007年第1期31-35,共5页
In this paper, the acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure are investigated. The similitude conditions and relations between the similitude model and ... In this paper, the acoustic scale effects and boundary effects for the similitude model of underwater complex shell-structure are investigated. The similitude conditions and relations between the similitude model and its prototype were studied in the references. This paper investigates the acoustic scale effects for the similitude model, which are influenced by loss factor, shear and rotatory inertia. At the same time, the boundary effects which are influenced by surface sound reflection are investigated in the experiment of similitude model. The results show that the acoustic scale effects may be controlled with model designing, the boundary effects can be controlled with experimental designing between the similitude model and its prototype. 展开更多
关键词 acoustic scale effects acoustic boundary effects SIMILITUDE
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Unstructured Grid Immersed Boundary Method for Numerical Simulation of Fluid Structure Interaction 被引量:2
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作者 明平剑 孙扬哲 +1 位作者 段文洋 张文平 《Journal of Marine Science and Application》 2010年第2期181-186,共6页
This paper presents an improved unstructured grid immersed boundary method.The advantages of both immersed boundary method and body fitted grids which are generated by unstructured grid technology are used to enhance ... This paper presents an improved unstructured grid immersed boundary method.The advantages of both immersed boundary method and body fitted grids which are generated by unstructured grid technology are used to enhance the computation efficiency of fluid structure interaction in complex domain.The Navier-Stokes equation was discretized spacially with collocated finite volume method and Euler implicit method in time domain.The rigid body motion was simulated by immersed boundary method in which the fluid and rigid body interface interaction was dealt with VOS(volume of solid) method.A new VOS calculation method based on graph was presented in which both immersed boundary points and cross points were collected in arbitrary order to form a graph.The method is verified with flow past oscillating cylinder. 展开更多
关键词 fluid structure interaction immersed boundary method VOS unstructured grids finite volume method
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Dynamic Adaptive Finite Element Analysis of Acoustic Wave Propagation Due to Underwater Explosion for Fluid-structure Interaction Problems 被引量:4
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作者 Seyed Shahab Emamzadeh Mohammad Taghi Ahmadi +1 位作者 Soheil Mohammadi Masoud Biglarkhani 《Journal of Marine Science and Application》 CSCD 2015年第3期302-315,共14页
In this paper, an investigation into the propagation of far field explosion waves in water and their effects on nearby structures are carried out. For the far field structure, the motion of the fluid surrounding the s... In this paper, an investigation into the propagation of far field explosion waves in water and their effects on nearby structures are carried out. For the far field structure, the motion of the fluid surrounding the structure may be assumed small, allowing linearization of the governing fluid equations. A complete analysis of the problem must involve simultaneous solution of the dynamic response of the structure and the propagation of explosion wave in the surrounding fluid. In this study, a dynamic adaptive finite element procedure is proposed. Its application to the solution of a 2D fluid-structure interaction is investigated in the time domain. The research includes:a) calculation of the far-field scatter wave due to underwater explosion including solution of the time-depended acoustic wave equation, b) fluid-structure interaction analysis using coupled Euler-Lagrangian approach, and c) adaptive finite element procedures employing error estimates, and re-meshing. The temporal mesh adaptation is achieved by local regeneration of the grid using a time-dependent error indicator based on curvature of pressure function. As a result, the overall response is better predicted by a moving mesh than an equivalent uniform mesh. In addition, the cost of computation for large problems is reduced while the accuracy is improved. 展开更多
关键词 adaptive mesh fluid-structure interaction acoustic wave finite element analysis underwater explosion
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Construction of Wave-free Potentials and Multipoles in a Two-layer Fluid Having Free-surface Boundary Condition with Higher-order Derivatives 被引量:1
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作者 Dilip Das 《Journal of Marine Science and Application》 CSCD 2015年第3期270-282,共13页
There is a large class of problems in the field of fluid structure interaction where higher-order boundary conditions arise for a second-order partial differential equation. Various methods are being used to tackle th... There is a large class of problems in the field of fluid structure interaction where higher-order boundary conditions arise for a second-order partial differential equation. Various methods are being used to tackle these kind of mixed boundary-value problems associated with the Laplace’s equation (or Helmholtz equation) arising in the study of waves propagating through solids or fluids. One of the widely used methods in wave structure interaction is the multipole expansion method. This expansion involves a general combination of a regular wave, a wave source, a wave dipole and a regular wave-free part. The wave-free part can be further expanded in terms of wave-free multipoles which are termed as wave-free potentials. These are singular solutions of Laplace’s equation or two-dimensional Helmholz equation. Construction of these wave-free potentials and multipoles are presented here in a systematic manner for a number of situations such as two-dimensional non-oblique and oblique waves, three dimensional waves in two-layer fluid with free surface condition with higher order partial derivative are considered. In particular, these are obtained taking into account of the effect of the presence of surface tension at the free surface and also in the presence of an ice-cover modelled as a thin elastic plate. Also for limiting case, it can be shown that the multipoles and wave-free potential functions go over to the single layer multipoles and wave-free potential. 展开更多
关键词 two-layer fluid wave-free potentials Laplace’s equation modified Helmholtz equations higher order boundary conditions MULTIPOLES
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Two-dimensional Numerical Simulation of an Elastic Wedge Water Entry by a Coupled FDM-FEM Method
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作者 Kangping Liao Changhong Hu Wenyang Duan 《Journal of Marine Science and Application》 2013年第2期163-169,共7页
Hydroelastic behavior of an elastic wedge impacting on calm water surface was investigated. A partitioned approach by coupling finite difference method (FDM) and finite element method (FEM) was developed to analyz... Hydroelastic behavior of an elastic wedge impacting on calm water surface was investigated. A partitioned approach by coupling finite difference method (FDM) and finite element method (FEM) was developed to analyze the fluid structure interaction (FSI) problem. The FDM, in which the Constraint Interpolation Profile (CIP) method was applied, was used for solving the flow field in a fixed regular Cartesian grid system. Free surface was captured by the Tangent of Hyperbola for Interface Capturing with Slope Weighting (THINC/SW) scheme. The FEM was applied for calculating the structural deformation. A volume weighted method, which was based on the immersed boundary (IB) method, was adopted for coupling the FDM and the FEM together. An elastic wedge water entry problem was calculated by the coupled FDM-FEM method. Also a comparison between the current numerical results and the published results indicate that the coupled FDM-FEM method has reasonably good accuracy in predicting the impact force. 展开更多
关键词 elastic wedge water entry coupled FDM-FEM method volume weighted method CIP method THINC/SW scheme hydroelastic behavior
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Study of structure function correlation of chemokine receptor CXCR4
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作者 郑红 朱锡华 《Journal of Medical Colleges of PLA(China)》 CAS 2002年第2期79-84,共6页
Objective: To explore the correlation between structure domains and functions of chemokine receptor CXCR4. Methods: After the establishment of wild type chemokine.receptor CXCR4 and CXCR2 expressing cell lines, 5 CXCR... Objective: To explore the correlation between structure domains and functions of chemokine receptor CXCR4. Methods: After the establishment of wild type chemokine.receptor CXCR4 and CXCR2 expressing cell lines, 5 CXCR4/CXCR2 chimeras, 2 CXCR4 mutants were stably expressed on CHO cell line. Binding activities of all variants with the ligand, recombinant human SDF-1β, signal transduction ability after stimulation and their function as coreceptor for HIV-1 were studied with ligand-binding assay, Cytosensor/ microphysiometry and cell-cell reporter gene fusion assay. Results: Among all 7 changed CXCR4 receptors, 3 chimeras (2444a, 4442, 4122), and 1 mutant (CXCR4-Tr) bond with SDF-1β in varying degrees, of which only 2444a totally and CXCR4-Tr partially maintain signaling. All changed receptors except for 4222 could act as coreceptors for HIV-1 (LAI) in varying degrees. Conclusion: Several structure domains of CXCR4 are involved in the binding with SDF-1β, among which, N-terminal extracellular domain has high affinity of binding with SDF-1β, and the 3rd extracellular loop contributes to the binding, too. Although the C-terminal in-tracellular domain has no association with the maintenance of the overall structure of the receptor and ligand binding capability, the signaling is decreased when this domain is truncated. For CXCR4 signaling, not only is the conserved motif DRY box needed, but also the characterized conformation of the whole molecule must be formed when activation is required. There are some overlaps between SDF-1β binding domains and coreceptor function domains in molecular structure of CXCR4. 展开更多
关键词 CXCR4 SDF-1β CHIMERAS STRUCTURE-FUNCTION
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The Two-dimensional Study of the Interaction between Liquid loshing and Elastic Structures 被引量:1
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作者 侯玲 朱仁庆 王全 《Journal of Marine Science and Application》 2010年第2期192-199,共8页
Sloshing phenomenon in the liquid cargo carriers has caught the attention of researchers as the interaction between the sloshing waves and structure is one of the key point and difficulty in the study of sloshing.In t... Sloshing phenomenon in the liquid cargo carriers has caught the attention of researchers as the interaction between the sloshing waves and structure is one of the key point and difficulty in the study of sloshing.In this paper,we captured the free surface with a volume of fluid(VOF) method and then calculated the motions and responses of the structure by adopting the Reynolds-averaged Navier-Stokes(RANS) equations for the whole fluid domain.With the use of user defined functions(UDF) in Fluent,the interaction between fluid and structure was then simulated.As a reasonable simplification,the authors studied the response of a single cantilever in a tank under sloshing loads;Further study should pay more attention to the mechanisms of interaction between sloshing waves and elastic structures. 展开更多
关键词 Liquid sloshing FLUENT DEFORMATION Numerical simulation
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