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炼焦煤成焦机理再认识:“衍构成焦机理”的提出 被引量:2
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作者 崔贝贝 王美君 +1 位作者 常丽萍 谢克昌 《煤炭学报》 EI CAS CSCD 北大核心 2024年第6期2826-2839,共14页
深度认识煤质特性、探究炼焦煤成焦机理是开发精细化配煤炼焦技术的关键。传统成焦机理仅宏观地解释了炼焦煤炭化过程中的塑性和黏结现象,缺乏对煤转变为焦炭所涉及的化学反应的深层次认识。基于此,从分子水平阐述了炼焦煤成焦特性的演... 深度认识煤质特性、探究炼焦煤成焦机理是开发精细化配煤炼焦技术的关键。传统成焦机理仅宏观地解释了炼焦煤炭化过程中的塑性和黏结现象,缺乏对煤转变为焦炭所涉及的化学反应的深层次认识。基于此,从分子水平阐述了炼焦煤成焦特性的演化机制并提出了“衍构成焦机理”,其核心观点是:煤的焦化本质是煤分子在温度作用下发生的一系列化学反应;成焦过程中的一切宏观特性都取决于煤基体的瞬态空间结构,即“结构决定性质”;炼焦过程中传热传质条件的动态变化将影响煤的热转化行为进而影响成焦特性和焦炭质量,即“环境影响行为”。基于煤分子结构特性及热解过程中共价键的断裂和重建规律,重点分析了炼焦煤的流动性、膨胀性及其演化机制,探究了煤分子空间结构重排与焦炭强度的内在联系。流动性源于煤中弱共价键的断裂,终于芳香碎片的交联缩聚。在流动过程中,煤热解碎片以分子链段的形式向孔穴相继跃迁并封闭孔隙,形成了包含塑性层和部分煤层及半焦层的低透气带,限制了挥发分的释放从而产生了膨胀压力;同时,碳基质结构发生重排,取向性增加,sp^(2)杂化和sp^(3)杂化形式的碳原子的空间排布方式决定了焦炭的强度。加热速率的合理调控将明显改善焦炭强度并实现焦化过程节能降耗。“衍构成焦机理”是对传统煤成焦机理的补充和延伸,以期为现代煤焦化工业精细化发展提供理论指导和技术支撑。 展开更多
关键词 成焦机理 分子结构转变 成焦特性 传热传质条件 焦炭质量
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Convective heat and mass transfer in MHD mixed convection flow of Jeffrey nanofluid over a radially stretching surface with thermal radiation 被引量:6
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作者 M.BILAL ASHRAF T.HAYAT +1 位作者 A.ALSAEDI S.A.SHEHZAD 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第3期1114-1123,共10页
Mixed convection flow of magnetohydrodynamic(MHD) Jeffrey nanofluid over a radially stretching surface with radiative surface is studied. Radial sheet is considered to be convectively heated. Convective boundary condi... Mixed convection flow of magnetohydrodynamic(MHD) Jeffrey nanofluid over a radially stretching surface with radiative surface is studied. Radial sheet is considered to be convectively heated. Convective boundary conditions through heat and mass are employed. The governing boundary layer equations are transformed into ordinary differential equations. Convergent series solutions of the resulting problems are derived. Emphasis has been focused on studying the effects of mixed convection, thermal radiation, magnetic field and nanoparticles on the velocity, temperature and concentration fields. Numerical values of the physical parameters involved in the problem are computed for the local Nusselt and Sherwood numbers are computed. 展开更多
关键词 Jeffrey nanofluid mixed convection flow radially stretching surface convective boundary conditions magnetic field
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Convective heat and mass transfer effects in three-dimensional flow of Maxwell fluid over a stretching surface with heat source 被引量:1
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作者 T.Hayat M.Bilal Ashraf +1 位作者 A.Alsaedi S.A.Shehzad 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第2期717-726,共10页
Heat and mass transfer effects in three-dimensional flow of Maxwell fluid over a stretching surface were addressed.Analysis was performed in the presence of internal heat generation/absorption. Concentration and therm... Heat and mass transfer effects in three-dimensional flow of Maxwell fluid over a stretching surface were addressed.Analysis was performed in the presence of internal heat generation/absorption. Concentration and thermal buoyancy effects were accounted. Convective boundary conditions for heat and mass transfer analysis were explored. Series solutions of the resulting problem were developed. Effects of mixed convection, internal heat generation/absorption parameter and Biot numbers on the dimensionless velocity, temperature and concentration distributions were illustrated graphically. Numerical values of local Nusselt and Sherwood numbers were obtained and analyzed for all the physical parameters. It is found that both thermal and concentration boundary layer thicknesses are decreasing functions of stretching ratio. Variations of mixed convection parameter and concentration buoyancy parameter on the velocity profiles and associated boundary layer thicknesses are enhanced. Velocity profiles and temperature increase in the case of internal heat generation while they reduce for heat absorption. Heat transfer Biot number increases the thermal boundary layer thickness and temperature. Also concentration and its associated boundary layer are enhanced with an increase in mass transfer Biot number. The local Nusselt and Sherwood numbers have quite similar behaviors for increasing values of mixed convection parameter, concentration buoyancy parameter and Deborah number. 展开更多
关键词 Maxwell fluid mixed convection convective conditions three-dimensional flow internal heat generation/absorption
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