Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils...Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils,vegetables and paddy rice were investigated,and potential non-carcinogenic and carcinogenic health risks exposure to Cd were estimated at six villages around the Dabaoshan Mine,South China.A total of 87 soil samples were found to exceed the China's maximum permission level(MPL)for Cd,while the highest value of 4.42 mg/kg was found near irrigation ditch associated with Hengshi River in Xinyi(XY)Village.Cd contents in vegetables and rice exceeded the maximum permissible concentration by more than five times in every village.Cadmium accumulation in plants is in the order of celery>lactuca sativa L>Chinese cabbage>Romaine lettuce>asparagus lettuce>mustard>cabbage mustard>cabbage.The mean hazard quotient(HQ)of all villages is in the range of [5.29,25.75],and the mean values of cancer risk for investigated areas are more than 10 times greater than the USEPA(2009)threshold limit value of 10-4.Moreover,human non-carcinogenic and carcinogenic risks are mainly attributable to paddy rice intake,followed by vegetables intake,soil ingestion,inhalation,and dermal contact.The results indicate that Cd has a huge potential risk on human health for the local residents.展开更多
Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and ...Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and competitive ions （Cu2＋）. The adsorption of Pb2＋ onto the soil was investigated on batch equilibrium adsorption experiments. Results show that the Pb2＋ adsorption on the soil is relatively rapid in the first 30 min and reaches equilibrium at 2 h, and the kinetics of the adsorption process on the soil is well characterized by the pseudo-second order reaction rate. Langmuir, Freundlich and Temkin isothermal models are fit for the adsorption of Pb2＋ onto the soil, and the maximum amount of Pb2＋ adsorption （Qm） is 7.47 mg/g. The amount of Pb2＋ adsorption increases with increasing the pH at the range of 1.2-4.5 and reaches a plateau at the range of 4.5-12. The presence of humic acid in soil decreases the adsorption of Pb2＋ onto the soil at solution pH of 8 since the negatively charged humic acid with Pb2＋ is difficult to be adsorbed on the negatively charged soil surface. The adsorption of Pb2＋ onto the soil also decreases in the presence of Cu2＋ due to file competition adsorption between Pb2＋ and Cu2＋.展开更多
The properties and feasibility of L-band differential InSAR for detecting and monitoring mining-induced subsidence were systematically analyzed and demonstrated. The largest monitored subsidence gradient of 7.9×1...The properties and feasibility of L-band differential InSAR for detecting and monitoring mining-induced subsidence were systematically analyzed and demonstrated. The largest monitored subsidence gradient of 7.9×10-3 and magnitude of 91 cm were firstly derived by theoretical derivation. Then, the stronger phase maintaining capacity and weaker sensitivity to minor land subsidence compared with C-band DInSAR were illustrated by phase simulation of the actual mine subsidence. Finally, the data processing procedure of two-pass DInSAR was further refined to accurately observe subsidence of a coalfield of Jining in Northern China using 7 ALOS PALSAR images. The largest monitored subsidence magnitude of 39.22 cm and other properties were better investigated by testing results interpretation and subsidence analysis, and the absolute difference varying from 0.5 mm to 17.9 mm was obtained by comparison with leveling-measured subsidence. All of results show that L-band DInSAR technique can investigate the location, amount, area and other detailed subsidence information with relatively higher accuracy.展开更多
The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated b...The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated by a modified Tessier sequential extraction technique.The results show that the chemical fraction of Pb in soil is mainly the Res fraction and followed by FMO fraction,and the WS,WO,FMO,and SO fractions in topsoils(0-10 cm) are higher than those in subsoils(30-40 cm).The sum of contents of WS and Ex fractions(SWE) in topsoils is significantly positively related with that in subsoils,indicating the strong mobility of Pb in WS and Ex fractions in soils,and the SWE in soils is higher than the German trigger value for the transfer path soil-plant,indicating the high bioavailability of Pb in soils of this area.Fortunately,SWE and the ratio of WS and Ex fractions(RWE) to the sum of all fractions generally decrease with the soil depth in soil profile and the RWE in soil profile is lower than 0.5%,indicating the low pollution risk for Pb in groundwater.In addition,soil particles,pH and Fe2O3 play an important role in the impact of mobility and chemical fractions of Pb in soils.展开更多
Nitrate pollution in groundwater is a serious water quality problem that increases the risk of developing various cancers.Groundwater is the most important water resource and supports a population of 5 million in Anya...Nitrate pollution in groundwater is a serious water quality problem that increases the risk of developing various cancers.Groundwater is the most important water resource and supports a population of 5 million in Anyang area of the southern part of the North China Plain. Determining the source of nitrate pollution is the challenge in hydrology area due to the complex processes of migration and transformation. A new method is presented to determine the source of nitrogen pollution by combining the composition characteristics of stable carbon isotope in dissolved organic carbon in groundwater. The source of groundwater nitrate is dominated by agricultural fertilizers, as well as manure and wastewater. Mineralization, nitrification and mixing processes occur in the groundwater recharge area, whereas the confined groundwater area is dominated by denitrification processes.展开更多
Energy performance assessment on central air-conditioning system is essential to optimize operating, reduce operating costs, improve indoor environmental quality, and determine whether the retrofitting of the equipmen...Energy performance assessment on central air-conditioning system is essential to optimize operating, reduce operating costs, improve indoor environmental quality, and determine whether the retrofitting of the equipment is necessary. But it is difficult to evaluate it reasonably and comprehensively due to its complexity. A "holistic" approach was discussed to evaluate the energy performance of central air-conditioning system for an extra-large commercial building in a subtropical city. All procedures were described in detail, including field investigation method, field measurement instruments, data processing and data analyzing. The main factors affecting energy consumption of air-conditioning system were analyzed and the annual cooling-energy use intensity of this building was calculated and also compared with other shopping malls and other types of buildings in Guangzhou. And COP(coefficient of performance) of chiller, water transfer factor of chilled water system and cooling water system were taken into consideration. At last, the thermal comfort and indoor air quality issues were addressed. The results show that the chilled water pumps are over-sized and the indoor environmental quality should be improved. The purpose of this work is to provide reference for energy performance assessment method for air-conditioning system.展开更多
The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, ne...The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, near sources and intensive tectonic activity. This work was focused on the sedimentary feature of the glutenite segment to conduct the seismic sedimentology research. The near-shore subaqueous fans and its relative gravity channel and slump turbidite fan depositions were identified according to observation and description of cores combining with the numerous data of seismic and logging. Then, the depositional model was built depending on the analysis of palaeogeomorphology. The seismic attributes which are related to the hydrocarbon but relative independent were chosen to conduct the analysis, the reservoir area of the glutenite segment was found performing a distribution where the amplitude value is relatively higher, and finally the RMS amplitude attribute was chosen to conduct the attribute predicting. At the same time, the horizontal distribution of the sedimentary facies was analyzed qualitatively. At last, the sparse spike inversion method was used to conduct the acoustic impedance inversion, and the inversion result can distinguish glutenite reservoir which is greater than 5 m. This method quantitatively characterizes the distribution area of the favorable reservoir sand.展开更多
基金Project(51204074)supported by the National Natural Science Foundation of ChinaProjects(2010009017,201209048,ZX021-201106-031)supported by the National Environmental Protection Public Welfare Industry Targeted Research Fund,China
文摘Soil cadmium(Cd)contamination resulted from mining and smelting is a major environmental concern,and health risk associated with Cd exposure to multi-media through muti-pathway is increasing.Cd concentrations in soils,vegetables and paddy rice were investigated,and potential non-carcinogenic and carcinogenic health risks exposure to Cd were estimated at six villages around the Dabaoshan Mine,South China.A total of 87 soil samples were found to exceed the China's maximum permission level(MPL)for Cd,while the highest value of 4.42 mg/kg was found near irrigation ditch associated with Hengshi River in Xinyi(XY)Village.Cd contents in vegetables and rice exceeded the maximum permissible concentration by more than five times in every village.Cadmium accumulation in plants is in the order of celery>lactuca sativa L>Chinese cabbage>Romaine lettuce>asparagus lettuce>mustard>cabbage mustard>cabbage.The mean hazard quotient(HQ)of all villages is in the range of [5.29,25.75],and the mean values of cancer risk for investigated areas are more than 10 times greater than the USEPA(2009)threshold limit value of 10-4.Moreover,human non-carcinogenic and carcinogenic risks are mainly attributable to paddy rice intake,followed by vegetables intake,soil ingestion,inhalation,and dermal contact.The results indicate that Cd has a huge potential risk on human health for the local residents.
基金Project(SK201109) supported by the Basic Scientific Study Funding from Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological SciencesProject(2010CB428806-2) supported by the National Basic Research Program of China
文摘Pb2＋ adsorption onto a soil by irrigation of sewage in the Pearl River Delta of South China was examined as a function of the reaction time, solution pH, initial lead concentration, organic matter （humic acid） and competitive ions （Cu2＋）. The adsorption of Pb2＋ onto the soil was investigated on batch equilibrium adsorption experiments. Results show that the Pb2＋ adsorption on the soil is relatively rapid in the first 30 min and reaches equilibrium at 2 h, and the kinetics of the adsorption process on the soil is well characterized by the pseudo-second order reaction rate. Langmuir, Freundlich and Temkin isothermal models are fit for the adsorption of Pb2＋ onto the soil, and the maximum amount of Pb2＋ adsorption （Qm） is 7.47 mg/g. The amount of Pb2＋ adsorption increases with increasing the pH at the range of 1.2-4.5 and reaches a plateau at the range of 4.5-12. The presence of humic acid in soil decreases the adsorption of Pb2＋ onto the soil at solution pH of 8 since the negatively charged humic acid with Pb2＋ is difficult to be adsorbed on the negatively charged soil surface. The adsorption of Pb2＋ onto the soil also decreases in the presence of Cu2＋ due to file competition adsorption between Pb2＋ and Cu2＋.
基金Projects(41274007,40874001)supported by the National Natural Science Foundations of ChinaProjects(ZR2012DM001,ZR2010DQ020)supported by Shandong Province Natural Science Foundation,China+2 种基金Project(2011B04)supported by the Key Laboratory of Surveying and Mapping Technology on Island and Reef,National Administration of Surveying,Mapping and Geoinformation,ChinaProject(2011KYTD103)supported by SDUST Research Fund,ChinaProject(BS2013F013)supported by Shangdong Province Outstanding Youth Scientist Foundation,China
文摘The properties and feasibility of L-band differential InSAR for detecting and monitoring mining-induced subsidence were systematically analyzed and demonstrated. The largest monitored subsidence gradient of 7.9×10-3 and magnitude of 91 cm were firstly derived by theoretical derivation. Then, the stronger phase maintaining capacity and weaker sensitivity to minor land subsidence compared with C-band DInSAR were illustrated by phase simulation of the actual mine subsidence. Finally, the data processing procedure of two-pass DInSAR was further refined to accurately observe subsidence of a coalfield of Jining in Northern China using 7 ALOS PALSAR images. The largest monitored subsidence magnitude of 39.22 cm and other properties were better investigated by testing results interpretation and subsidence analysis, and the absolute difference varying from 0.5 mm to 17.9 mm was obtained by comparison with leveling-measured subsidence. All of results show that L-band DInSAR technique can investigate the location, amount, area and other detailed subsidence information with relatively higher accuracy.
基金Project(41103059) supported by the National Natural Science Foundation of ChinaProject(2010CB428806-2) supported by the National Basic Research Program of China
文摘The chemical fractions,i.e.,water soluble(WS),exchangeable(Ex),carbonate(Car),weakly organic(WO),Fe-Mn oxide(FMO),strongly organic(SO),residual(Res) fraction,of Pb in irrigated soils in South China were investigated by a modified Tessier sequential extraction technique.The results show that the chemical fraction of Pb in soil is mainly the Res fraction and followed by FMO fraction,and the WS,WO,FMO,and SO fractions in topsoils(0-10 cm) are higher than those in subsoils(30-40 cm).The sum of contents of WS and Ex fractions(SWE) in topsoils is significantly positively related with that in subsoils,indicating the strong mobility of Pb in WS and Ex fractions in soils,and the SWE in soils is higher than the German trigger value for the transfer path soil-plant,indicating the high bioavailability of Pb in soils of this area.Fortunately,SWE and the ratio of WS and Ex fractions(RWE) to the sum of all fractions generally decrease with the soil depth in soil profile and the RWE in soil profile is lower than 0.5%,indicating the low pollution risk for Pb in groundwater.In addition,soil particles,pH and Fe2O3 play an important role in the impact of mobility and chemical fractions of Pb in soils.
基金Projects(41072179,41002083)supported by the National Natural Science Foundation of China
文摘Nitrate pollution in groundwater is a serious water quality problem that increases the risk of developing various cancers.Groundwater is the most important water resource and supports a population of 5 million in Anyang area of the southern part of the North China Plain. Determining the source of nitrate pollution is the challenge in hydrology area due to the complex processes of migration and transformation. A new method is presented to determine the source of nitrogen pollution by combining the composition characteristics of stable carbon isotope in dissolved organic carbon in groundwater. The source of groundwater nitrate is dominated by agricultural fertilizers, as well as manure and wastewater. Mineralization, nitrification and mixing processes occur in the groundwater recharge area, whereas the confined groundwater area is dominated by denitrification processes.
基金Project(2011B061200043)supported by the Guangdong Provincial Department of Science and Technology,China
文摘Energy performance assessment on central air-conditioning system is essential to optimize operating, reduce operating costs, improve indoor environmental quality, and determine whether the retrofitting of the equipment is necessary. But it is difficult to evaluate it reasonably and comprehensively due to its complexity. A "holistic" approach was discussed to evaluate the energy performance of central air-conditioning system for an extra-large commercial building in a subtropical city. All procedures were described in detail, including field investigation method, field measurement instruments, data processing and data analyzing. The main factors affecting energy consumption of air-conditioning system were analyzed and the annual cooling-energy use intensity of this building was calculated and also compared with other shopping malls and other types of buildings in Guangzhou. And COP(coefficient of performance) of chiller, water transfer factor of chilled water system and cooling water system were taken into consideration. At last, the thermal comfort and indoor air quality issues were addressed. The results show that the chilled water pumps are over-sized and the indoor environmental quality should be improved. The purpose of this work is to provide reference for energy performance assessment method for air-conditioning system.
基金Project(41172109)supported by the National Natural Science Foundation of ChinaProject(20110003110014)supported by the ResearchFoundation for the Doctoral Program of Higher Education,China
文摘The sand-conglomerate fans are the major depositional systems in the lower third member of Shahejie Formation in Shengtuo area, which formed in the deep lacustrine environment characterized by steep slope gradient, near sources and intensive tectonic activity. This work was focused on the sedimentary feature of the glutenite segment to conduct the seismic sedimentology research. The near-shore subaqueous fans and its relative gravity channel and slump turbidite fan depositions were identified according to observation and description of cores combining with the numerous data of seismic and logging. Then, the depositional model was built depending on the analysis of palaeogeomorphology. The seismic attributes which are related to the hydrocarbon but relative independent were chosen to conduct the analysis, the reservoir area of the glutenite segment was found performing a distribution where the amplitude value is relatively higher, and finally the RMS amplitude attribute was chosen to conduct the attribute predicting. At the same time, the horizontal distribution of the sedimentary facies was analyzed qualitatively. At last, the sparse spike inversion method was used to conduct the acoustic impedance inversion, and the inversion result can distinguish glutenite reservoir which is greater than 5 m. This method quantitatively characterizes the distribution area of the favorable reservoir sand.
