The mathematical topological rule was applied to plot the predominance area diagram.Based on the analysis of the mutually conjugated,only two diagrams were the best topological embryonic graphs to build the predominan...The mathematical topological rule was applied to plot the predominance area diagram.Based on the analysis of the mutually conjugated,only two diagrams were the best topological embryonic graphs to build the predominance area diagram of Me-S-O system.Combined with topological rules and thermodynamic calculation,four relation-diagrams were denoted asαandβstable and unstable plane-topological diagrams,which were plotted for the Pb-S-O system and Zn-S-O system.The results show thatβstable plane-topological diagram of Pb-S-O system andαstable one of Zn-S-O system are in accordance with the traditional predominance area diagram,which indicates that it is feasible to plot the predominance area diagram based on mathematical topological rules.Meanwhile,αunstable plane-topological diagram of Pb-S-O system can elucidate the phenomenon that metallic lead exists in higher oxygen and sulfur pressure area in modern bath smelting furnace.The mathematical topological rules broaden the application scope of the predominance area diagram and enrich the practice of its plotting.展开更多
基金Project(2011AA061003) supported by the High-Tech Research and Development Program of China
文摘The mathematical topological rule was applied to plot the predominance area diagram.Based on the analysis of the mutually conjugated,only two diagrams were the best topological embryonic graphs to build the predominance area diagram of Me-S-O system.Combined with topological rules and thermodynamic calculation,four relation-diagrams were denoted asαandβstable and unstable plane-topological diagrams,which were plotted for the Pb-S-O system and Zn-S-O system.The results show thatβstable plane-topological diagram of Pb-S-O system andαstable one of Zn-S-O system are in accordance with the traditional predominance area diagram,which indicates that it is feasible to plot the predominance area diagram based on mathematical topological rules.Meanwhile,αunstable plane-topological diagram of Pb-S-O system can elucidate the phenomenon that metallic lead exists in higher oxygen and sulfur pressure area in modern bath smelting furnace.The mathematical topological rules broaden the application scope of the predominance area diagram and enrich the practice of its plotting.
