A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The...A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystal is the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm 3, Z=1, D c=1.565 Mg/m 3, M r=1 063.59, μ=1.183 mm -1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.展开更多
A novel 3 D compound, [H 0.5 CoP 0.5 O 2.5 ], was hydrothermally synthesized and structurally characterized by singly crystal X ray diffraction, ICP, elemental analysis and IR spectra. The compound crystallizes in ort...A novel 3 D compound, [H 0.5 CoP 0.5 O 2.5 ], was hydrothermally synthesized and structurally characterized by singly crystal X ray diffraction, ICP, elemental analysis and IR spectra. The compound crystallizes in orthorhombic system, space group Pnnm with a =0.805 1(2) nm, b =0.838 09(13) nm, \{ c =\}0.595 0(2) nm, V =0.401(2) nm 3, Z=1, D =1.669 Mg/cm 3, R=0.049 1, wR =0.153 2.展开更多
文摘A 3-D inorganic-organic hybrid framework microporous material [Co 3(BDC) 3(EG) 4]·2DMF was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by a direct method and refined by full-matrix least-square method. The crystal is the triclinic system and belongs to space group P-1 with a=9.978(2) nm, b=11.223(2) nm, c=11.283(2) nm, α=102.26(3)°, β=113.52(3)°, γ=92.73(3)°, V=6.329(2) nm 3, Z=1, D c=1.565 Mg/m 3, M r=1 063.59, μ=1.183 mm -1, F(000)=541, GOF=1.024, R=0.044 2, wR=0.124 9.
文摘A novel 3 D compound, [H 0.5 CoP 0.5 O 2.5 ], was hydrothermally synthesized and structurally characterized by singly crystal X ray diffraction, ICP, elemental analysis and IR spectra. The compound crystallizes in orthorhombic system, space group Pnnm with a =0.805 1(2) nm, b =0.838 09(13) nm, \{ c =\}0.595 0(2) nm, V =0.401(2) nm 3, Z=1, D =1.669 Mg/cm 3, R=0.049 1, wR =0.153 2.
