Nitric oxide(NO),which generally originates from vehicle exhaust and industrial flue gases,is one of the most serious air pollutants.In this case,the electrochemical NO reduction reaction(NORR)not only removes the atm...Nitric oxide(NO),which generally originates from vehicle exhaust and industrial flue gases,is one of the most serious air pollutants.In this case,the electrochemical NO reduction reaction(NORR)not only removes the atmospheric pollutant NO but also produces valuable ammonia(NH_(3)).Hence,through the synthesis and modification of Fe_(3)C nanocrystal cata-lysts,the as-obtained optimal sample of Fe_(3)C/C-900 was adopted as the NORR catalyst at ambient conditions.As a result,the Fe_(3)C/C-900 catalyst showed an NH_(3)Faraday efficiency of 76.5%and an NH_(3)yield rate of 177.5μmol·h^(-1)·cm^(-2)at the working potentials of-0.8 and-1.2 V versus reversible hydrogen electrode(vs.RHE),respectively.And it delivered a stable NORR activity during the electrolysis.Moreover,we attribute the high NORR properties of Fe_(3)C/C-900 to two aspects:one is the enhanced intrinsic activity of Fe_(3)C nanocrystals,including the lowering of the energy barrier of rate-limiting step(*NOH→*N)and the inhibition of hydrogen evolution;on the other hand,the favorable dispersion of active components,the effective adsorption of gaseous NO,and the release of liquid NH_(3)products facilitated by the porous carbon substrate.展开更多
The label“posthumanism”identifies neither a doctrine,nor an intellectual or analytical approach with a defining set of protocols.Rather,we may take“posthumanism”as a term loosely applied to a range of contribution...The label“posthumanism”identifies neither a doctrine,nor an intellectual or analytical approach with a defining set of protocols.Rather,we may take“posthumanism”as a term loosely applied to a range of contributions and approaches,on the basis of a generally under-specified collection of sympathies and commitments.Approximately stated,these sympathies and commitments would entail the claim that—with due allowance for historical variation—the category of“the human”has long played a key role at the centre of Western thought;that this role has included serving to justify the promotion of human beings above other forms of being,and indeed within this,over its history,the violent oppression of the great majority of human beings themselves;and that,in league with the effects of various recent technological developments,it is therefore important to decentre,relativize,critique,and perhaps even move beyond“the human”.In this article,I will accordingly not look to define the term“posthumanism”:rather,I will present some of the background to and influences on the range of contributions and approaches that have come to be assembled under this label;delineate two principles which may be discerned within these contributions and approaches;and consider some of the critiques which these“posthumanist”interventions have attracted.Ultimately,I will argue that the label itself matters less than the impulses behind the contributions it has come to identify.展开更多
Local inhomogeneity in totally asymmetric simple exclusion processes （TASEPs） with different hopping rates was studied. Many biological and chemical phenomena can be described by these non-equilibrium processes. A s...Local inhomogeneity in totally asymmetric simple exclusion processes （TASEPs） with different hopping rates was studied. Many biological and chemical phenomena can be described by these non-equilibrium processes. A simple approximate theory and extensive Monte Carlo computer simulations were used to calculate the steady-state phase diagrams and bulk densities. It is found that the phase diagram for local inhomogeneity in TASEP with different hopping rates p is qualitatively similar to homogeneous models. Interestingly, there is a saturation point pair （a＊, fl＊） for the system, which is decided by parameters p and q. There are three stationary phases in the system, when parameter p is fixed （i.e., p=0.8）, with the increase of the parameter q, the region of LD/LD and HD/HD phase increases and the HD/LD is the only phase which the region shrinks. The analytical results are in good agreement with simulations.展开更多
Evaluation of the performance of existing support in underground tunnels is of great importance for production and interests.Based on field investigation,the shape and number of joints and fractures were investigated ...Evaluation of the performance of existing support in underground tunnels is of great importance for production and interests.Based on field investigation,the shape and number of joints and fractures were investigated in the mining area.Then,the stability of each structural blocks is analyzed by 3D wedge stability analysis software(Unwedge).Moreover,a new analysis method based on critical block theory is applied to analyze the stability of excavated laneways in continuous and discontinuous rock and monitor the stress changes in a fractured tunnel rock mass.The test results indicate that the 3D wedge stability analysis software for underground excavation can evaluate deep tunnel support.Besides,there is no direct relation between the size of the block and the instability of the tunnel.The support method,on large and thick key blocks,needs to be improved.In a broken tunnel section,U-shaped steel support can effectively promote the stress state of the surrounding rock.By monitoring the surrounding rock,it is proven that the vibrating string anchor stress monitoring system is an efficient and real-time method for tunnel stability evaluation.展开更多
To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechani...To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.展开更多
In order to improve the process precision of an XY laser annealing table, a geometric error modeling, and an identification and compensation method were proposed. Based on multi-body system theory, a geometric error m...In order to improve the process precision of an XY laser annealing table, a geometric error modeling, and an identification and compensation method were proposed. Based on multi-body system theory, a geometric error model for the laser annealing table was established. It supports the identification of 7 geometric errors affecting the annealing accuracy. An original identification method was presented to recognize these geometric errors. Positioning errors of 5 lines in the workspace were measured by a laser interferometer, and the 7 geometric errors were identified by the proposed algorithm. Finally, a software-based error compensation method was adopted, and a compensation mechanism was developed in a postprocessor based on LabVIEW. The identified geometric errors can be compensated by converting ideal NC codes to actual NC codes. A validation experiment has been conducted on the laser annealing table, and the results indicate that positioning errors of two validation lines decreased from ±37 μm and ±33 μm to ±5 μm and ±4.5 μm, respectively. The geometric error modeling, identification and compensation method presented in this work can be straightforwardly extended to any configurations of 2-dimensional worktable.展开更多
The distribution of shear stress on the cross-section of plastic metal solid circular shaft under pure torsion yielding, the applicability of complete plastic model assumption and the shear stress formula were researc...The distribution of shear stress on the cross-section of plastic metal solid circular shaft under pure torsion yielding, the applicability of complete plastic model assumption and the shear stress formula were researched. Based on the shear stress formula of circular shaft under pure torsion in elastic stage, the formula of torque in elastic stage and the definition of yield, it is obtained that the yielding stage of plastic metal shaft under pure torsion is only a surface phenomenon of torque-torsion angle relationship, and the distribution of shear stress is essentially different from that of tensile stress when yielding under uniaxial tension. The pure torsion platform-torsion angle and the shape of torque-torsion angle curve cannot change the distribution of shear stress on the shaft cross-section. The distribution of shear stress is still linear with the maximum shear stress ts. The complete plasticity model assumption is not in accordance with the actual situation of shaft under torsion. The experimental strength data of nine plastic metals are consistent with the calculated results of the new limiting strain energy strength theory （LSEST）. The traditional yield stress formula for plastic shaft under torsion is reasonable. The shear stress formula based on the plane assumption in material mechanics is applicable for all loaded stages of torsion shaft.展开更多
Based on the slip-line field theory, a two-dimensional slip failure mechanism with mesh-like rigid block system was constructed to analyze the ultimate bearing capacity problems of rough foundation within the framewor...Based on the slip-line field theory, a two-dimensional slip failure mechanism with mesh-like rigid block system was constructed to analyze the ultimate bearing capacity problems of rough foundation within the framework of the upper bound limit analysis theorem. In the velocity discontinuities in transition area, the velocity changes in radial and tangent directions are allowed. The objective functions of the stability problems of geotechnical structures are obtained by equating the work rate of external force to internal dissipation along the velocity discontinuities, and then the objective functions are transformed as an upper-bound mathematic optimization model. The upper bound solutions for the objective functions are obtained by use of the nonlinear sequential quadratic programming and interior point method. From the numerical results and comparative analysis, it can be seen that the method presented in this work gives better calculation results than existing upper bound methods and can be used to establish the more accurate plastic collapse load for the ultimate bearing capacity of rough foundation.展开更多
From the continuum mechanics perspective, an attempt was made to clarify the role of Terzaghi's effective stress in the theoretical analysis of saturated soil subjected to seepage. The necessity of performing a co...From the continuum mechanics perspective, an attempt was made to clarify the role of Terzaghi's effective stress in the theoretical analysis of saturated soil subjected to seepage. The necessity of performing a coupled hydromechanical analysis to solve the seepage-deformation interaction problem was illustrated by examining the equations of static equilibrium among the effective stress, seepage force, pore-water pressure and total stress. The conceptual definition of stress variable that satisfies the principles of continuum mechanics is applied in the coupled hydromechanical analysis. It is shown that Terzaghi's effective stress is in fact not a stress variable under seepage conditions, and the seepage force acting on the soil skeleton cannot be viewed as a body force. This offers a clue to the underlying cause of a paradox between the real Pascal's hydrostatic state and the hydrostatic state predicted by a class of continuum hydromechanical theories.展开更多
The concepts of rock strength intervals are presented in this work, furthermore, central values of intervals and their corresponding credibility are provided using two-case study based on blind data theory and fuzzy i...The concepts of rock strength intervals are presented in this work, furthermore, central values of intervals and their corresponding credibility are provided using two-case study based on blind data theory and fuzzy interval estimation. 60 granite specimens are first tested, the compressive strength interval and tensile strength interval are [ 103.68, 219.6 l ] and [7.53, 11,86] MPa, while the tested mean values of compressive strength and tensile strength are 152.86 and 10.14 MPa, the credibilities are less than 58.4% and around 70.4%, respectively, the credibility of shear strength is between 40% and 60%. Then 70 other rock specimens are designed and tested, the similar conclusions can be reached. The results show that the conventional definite values are the particular values within the intervals, and the credibility of them often fails to reach the high-precision engineering requirement. The results demonstrate the feasibility and application potential of this proposed algorithm for the engineering practice. The references for engineering value selection of rock strength under different credibility or according to frequency distribution of central values are provided to increase the reliability and precision of calculation.展开更多
Laboratory tests were performed on Toyoura sand specimens to investigate the relationship between degree of saturation Sr, B-value and P-wave velocity Vp. Different types of pore water （de-aired water or tap water） ...Laboratory tests were performed on Toyoura sand specimens to investigate the relationship between degree of saturation Sr, B-value and P-wave velocity Vp. Different types of pore water （de-aired water or tap water） and pore gas （air or CO2） as well as different magnitudes of back pressure were used to achieve different Sr （or B-value）. The measured relationship between B-value and Vp was not consistent with the theoretical prediction. The measurement shows that the Vp value in the specimen flushed with de-aired water is independent of B-value （or St） and is always around the one in fully saturated condition. However, the Vp value in the specimen flushed with tap water increases with B-value, but the shape of the relationship between Vp and B-value is quite different from the theoretical prediction. The possible explanation for the discrepancy between laboratory measurement and theoretical prediction lies in that the air exists in the water as air bubbles and therefore the pore fluid （air-water mixture） is heterogeneous instead of homogenous assumed in the theoretical prediction.展开更多
Due to the complex features of rock mass blastability assessment systems, an evaluation model of rock mass blastability was established on the basis of the unascertained measurement （UM） theory and the actual charac...Due to the complex features of rock mass blastability assessment systems, an evaluation model of rock mass blastability was established on the basis of the unascertained measurement （UM） theory and the actual characteristics of the project. Considering a comprehensive range of intact rock properties and discontinuous structures of rock mass, twelve main factors influencing the evaluation blastability of rock mass were taken into account in the UM model, and the blastability evaluation index system of rock mass was constructed. The unascertained evaluation indices corresponding to the selected factors for the actual situation were solved both qualitatively and quantitatively. Then, the UM function of each evaluation index was obtained based on the initial data for the analysis of the blastability of six rock mass at a highway improvement cutting site in North Wales. The index weights of the factors were calculated by entropy theory, and credible degree identification （CDI） criteria were established according to the UM theory. The results of rock mass blastability evaluation were obtained by the CDI criteria. The results show that the UM model assessment results agree well with the actual records, and are consistent with those of the fuzzy sets evaluation method. Meanwhile, the unascertained superiority degree of rock mass blastability of samples S1-$6 which can be calculated by scoring criteria are 3.428 5, 3.453 3, 4.058 7, 3.675 9, 3.516 7 and 3.289 7, respectively. Furthermore, the proposed method can take into account large amount of uncertain information in blastability evaluation, which can provide an effective, credible and feasible way for estimating the blastability of rock mass. Engineering practices show that it can complete the blastability assessment systematically and scientifically without any assumption by the proposed model, which can be applied to practical engineering.展开更多
To quantify the energy consumption in the process of production, transportation and processing of energy carriers, the life cycle of building energy used can be divided into two phases： on-site phase and embodied pha...To quantify the energy consumption in the process of production, transportation and processing of energy carriers, the life cycle of building energy used can be divided into two phases： on-site phase and embodied phase. As for the embodied phase, with the data in existing statistic yearbook, the consumption items of energy production and transportation were investigated. And based on the life cycle theory, an embodied coefficient of energy carriers was proposed to quantify the embodied energy consumption. Moreover, a calculation method for the embodied coefficient of energy carriers was deduced using Leontief inverse matrix based on the existing data sources. With relevant data of 2005-2007 in China, the embodied coefficients in 2005-2007 were obtained, in which the values for natural gas and thermal power are around 1.3 and 3. l, respectively; while they are 1.03-1.08 for other selected energy carriers. In addition, it is also found that the consumption in the production and processing accounts for more than 75%.展开更多
Based on the empirical electronic theory of solids and molecules （EET）, the actual model for unit cell of cementite （0-FeaC） was built and the valence electron structures （VES） of cementite with specified site a...Based on the empirical electronic theory of solids and molecules （EET）, the actual model for unit cell of cementite （0-FeaC） was built and the valence electron structures （VES） of cementite with specified site and a number of Fe atoms substituted by alloying atoms of M （ M=Cr, V, W, Mo, Mn ） were computed by statistical method. By defining P as the stability factor, the stability of alloyed cementite with different numbers and sites of Fe atoms substituted by M was calculated. Calculation results show that the density of lattice electrons, the symmetry of distribution of covalent electron pairs and bond energy have huge influence on the stability of alloyed cementite. It is more stable as M substitutes for FeE than for Fe1. The alloyed cementite is the most stable when Cr, Mo, W and V substitute for 2 atoms of Fe2 at the sites of Nos. 2 and 3 （or No. 6 and No. 7）. The stability of alloyed cementite decreases gradually as being substitutional doped by W, Cr, V, Mo and Mn.展开更多
基金supported by the Guangxi Natural Science Fund for Distinguished Young Scholars(2024GXNSFFA010008)Shenzhen Science and Technology Program(JCYJ20230807112503008).
文摘Nitric oxide(NO),which generally originates from vehicle exhaust and industrial flue gases,is one of the most serious air pollutants.In this case,the electrochemical NO reduction reaction(NORR)not only removes the atmospheric pollutant NO but also produces valuable ammonia(NH_(3)).Hence,through the synthesis and modification of Fe_(3)C nanocrystal cata-lysts,the as-obtained optimal sample of Fe_(3)C/C-900 was adopted as the NORR catalyst at ambient conditions.As a result,the Fe_(3)C/C-900 catalyst showed an NH_(3)Faraday efficiency of 76.5%and an NH_(3)yield rate of 177.5μmol·h^(-1)·cm^(-2)at the working potentials of-0.8 and-1.2 V versus reversible hydrogen electrode(vs.RHE),respectively.And it delivered a stable NORR activity during the electrolysis.Moreover,we attribute the high NORR properties of Fe_(3)C/C-900 to two aspects:one is the enhanced intrinsic activity of Fe_(3)C nanocrystals,including the lowering of the energy barrier of rate-limiting step(*NOH→*N)and the inhibition of hydrogen evolution;on the other hand,the favorable dispersion of active components,the effective adsorption of gaseous NO,and the release of liquid NH_(3)products facilitated by the porous carbon substrate.
文摘The label“posthumanism”identifies neither a doctrine,nor an intellectual or analytical approach with a defining set of protocols.Rather,we may take“posthumanism”as a term loosely applied to a range of contributions and approaches,on the basis of a generally under-specified collection of sympathies and commitments.Approximately stated,these sympathies and commitments would entail the claim that—with due allowance for historical variation—the category of“the human”has long played a key role at the centre of Western thought;that this role has included serving to justify the promotion of human beings above other forms of being,and indeed within this,over its history,the violent oppression of the great majority of human beings themselves;and that,in league with the effects of various recent technological developments,it is therefore important to decentre,relativize,critique,and perhaps even move beyond“the human”.In this article,I will accordingly not look to define the term“posthumanism”:rather,I will present some of the background to and influences on the range of contributions and approaches that have come to be assembled under this label;delineate two principles which may be discerned within these contributions and approaches;and consider some of the critiques which these“posthumanist”interventions have attracted.Ultimately,I will argue that the label itself matters less than the impulses behind the contributions it has come to identify.
基金Project(2011FZ050) supported by Applied Basic Research Program of Yunnan Provincial Science and Technology Department,ChinaProject(2011J084) supported by Master Program of Yunnan Province Education Department,China
文摘Local inhomogeneity in totally asymmetric simple exclusion processes （TASEPs） with different hopping rates was studied. Many biological and chemical phenomena can be described by these non-equilibrium processes. A simple approximate theory and extensive Monte Carlo computer simulations were used to calculate the steady-state phase diagrams and bulk densities. It is found that the phase diagram for local inhomogeneity in TASEP with different hopping rates p is qualitatively similar to homogeneous models. Interestingly, there is a saturation point pair （a＊, fl＊） for the system, which is decided by parameters p and q. There are three stationary phases in the system, when parameter p is fixed （i.e., p=0.8）, with the increase of the parameter q, the region of LD/LD and HD/HD phase increases and the HD/LD is the only phase which the region shrinks. The analytical results are in good agreement with simulations.
基金Projects(51964007,51774101)supported by the National Natural Science Foundation of ChinaProject(2016-4011)supported by the High-level Innovative Talents Training Project in Guizhou Province,ChinaProject(2019-5619)supported by the Guizhou Mining Power Disaster Early Warning and Control Technology Innovation Team,China。
文摘Evaluation of the performance of existing support in underground tunnels is of great importance for production and interests.Based on field investigation,the shape and number of joints and fractures were investigated in the mining area.Then,the stability of each structural blocks is analyzed by 3D wedge stability analysis software(Unwedge).Moreover,a new analysis method based on critical block theory is applied to analyze the stability of excavated laneways in continuous and discontinuous rock and monitor the stress changes in a fractured tunnel rock mass.The test results indicate that the 3D wedge stability analysis software for underground excavation can evaluate deep tunnel support.Besides,there is no direct relation between the size of the block and the instability of the tunnel.The support method,on large and thick key blocks,needs to be improved.In a broken tunnel section,U-shaped steel support can effectively promote the stress state of the surrounding rock.By monitoring the surrounding rock,it is proven that the vibrating string anchor stress monitoring system is an efficient and real-time method for tunnel stability evaluation.
基金Foundation item： Project（PLN1129）supported by Opening Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation （Southwest Petroleum University）, China
文摘To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.
基金Projects(2012ZX04010-011,2009ZX02037-02) supported by the Key National Science and Technology Project of China
文摘In order to improve the process precision of an XY laser annealing table, a geometric error modeling, and an identification and compensation method were proposed. Based on multi-body system theory, a geometric error model for the laser annealing table was established. It supports the identification of 7 geometric errors affecting the annealing accuracy. An original identification method was presented to recognize these geometric errors. Positioning errors of 5 lines in the workspace were measured by a laser interferometer, and the 7 geometric errors were identified by the proposed algorithm. Finally, a software-based error compensation method was adopted, and a compensation mechanism was developed in a postprocessor based on LabVIEW. The identified geometric errors can be compensated by converting ideal NC codes to actual NC codes. A validation experiment has been conducted on the laser annealing table, and the results indicate that positioning errors of two validation lines decreased from ±37 μm and ±33 μm to ±5 μm and ±4.5 μm, respectively. The geometric error modeling, identification and compensation method presented in this work can be straightforwardly extended to any configurations of 2-dimensional worktable.
文摘The distribution of shear stress on the cross-section of plastic metal solid circular shaft under pure torsion yielding, the applicability of complete plastic model assumption and the shear stress formula were researched. Based on the shear stress formula of circular shaft under pure torsion in elastic stage, the formula of torque in elastic stage and the definition of yield, it is obtained that the yielding stage of plastic metal shaft under pure torsion is only a surface phenomenon of torque-torsion angle relationship, and the distribution of shear stress is essentially different from that of tensile stress when yielding under uniaxial tension. The pure torsion platform-torsion angle and the shape of torque-torsion angle curve cannot change the distribution of shear stress on the shaft cross-section. The distribution of shear stress is still linear with the maximum shear stress ts. The complete plasticity model assumption is not in accordance with the actual situation of shaft under torsion. The experimental strength data of nine plastic metals are consistent with the calculated results of the new limiting strain energy strength theory （LSEST）. The traditional yield stress formula for plastic shaft under torsion is reasonable. The shear stress formula based on the plane assumption in material mechanics is applicable for all loaded stages of torsion shaft.
基金Projects(51078359, 51208522) supported by the National Natural Science Foundation of ChinaProjects(20110491269, 2012T50708) supported by China Postdoctoral Science FoundationProject supported by Postdoctoral Science Foundation of Central South University, China
文摘Based on the slip-line field theory, a two-dimensional slip failure mechanism with mesh-like rigid block system was constructed to analyze the ultimate bearing capacity problems of rough foundation within the framework of the upper bound limit analysis theorem. In the velocity discontinuities in transition area, the velocity changes in radial and tangent directions are allowed. The objective functions of the stability problems of geotechnical structures are obtained by equating the work rate of external force to internal dissipation along the velocity discontinuities, and then the objective functions are transformed as an upper-bound mathematic optimization model. The upper bound solutions for the objective functions are obtained by use of the nonlinear sequential quadratic programming and interior point method. From the numerical results and comparative analysis, it can be seen that the method presented in this work gives better calculation results than existing upper bound methods and can be used to establish the more accurate plastic collapse load for the ultimate bearing capacity of rough foundation.
基金Project(51278171)supported by the National Natural Science Foundation of ChinaProject(B13024)supported by the"111"Project,China+1 种基金Projects(2014B04914,2011B02814,2010B28114)supported by the Fundamental Research Funds for the Central Universities of ChinaProject(617608)supported by the Research Grants Council of the Hong Kong Special Administrative Region of China
文摘From the continuum mechanics perspective, an attempt was made to clarify the role of Terzaghi's effective stress in the theoretical analysis of saturated soil subjected to seepage. The necessity of performing a coupled hydromechanical analysis to solve the seepage-deformation interaction problem was illustrated by examining the equations of static equilibrium among the effective stress, seepage force, pore-water pressure and total stress. The conceptual definition of stress variable that satisfies the principles of continuum mechanics is applied in the coupled hydromechanical analysis. It is shown that Terzaghi's effective stress is in fact not a stress variable under seepage conditions, and the seepage force acting on the soil skeleton cannot be viewed as a body force. This offers a clue to the underlying cause of a paradox between the real Pascal's hydrostatic state and the hydrostatic state predicted by a class of continuum hydromechanical theories.
基金Project(2011DA105287-MS201605)supported by the State Key Laboratory of Coal Mine Disaster Dynamics and Control,ChinaProject(51374242)supported by the National Natural Science Foundation of ChinaProject(106112016CDJXY240004)supported by the Fundamental Research Funds for the Central Universities,China
文摘The concepts of rock strength intervals are presented in this work, furthermore, central values of intervals and their corresponding credibility are provided using two-case study based on blind data theory and fuzzy interval estimation. 60 granite specimens are first tested, the compressive strength interval and tensile strength interval are [ 103.68, 219.6 l ] and [7.53, 11,86] MPa, while the tested mean values of compressive strength and tensile strength are 152.86 and 10.14 MPa, the credibilities are less than 58.4% and around 70.4%, respectively, the credibility of shear strength is between 40% and 60%. Then 70 other rock specimens are designed and tested, the similar conclusions can be reached. The results show that the conventional definite values are the particular values within the intervals, and the credibility of them often fails to reach the high-precision engineering requirement. The results demonstrate the feasibility and application potential of this proposed algorithm for the engineering practice. The references for engineering value selection of rock strength under different credibility or according to frequency distribution of central values are provided to increase the reliability and precision of calculation.
基金Foundation item： Project（2012CB719803） supported by the National Basic Research Program of China Project（201011159098） supported by the Seed Funding for Basic Research Scheme from The University of Hong Kong, China
文摘Laboratory tests were performed on Toyoura sand specimens to investigate the relationship between degree of saturation Sr, B-value and P-wave velocity Vp. Different types of pore water （de-aired water or tap water） and pore gas （air or CO2） as well as different magnitudes of back pressure were used to achieve different Sr （or B-value）. The measured relationship between B-value and Vp was not consistent with the theoretical prediction. The measurement shows that the Vp value in the specimen flushed with de-aired water is independent of B-value （or St） and is always around the one in fully saturated condition. However, the Vp value in the specimen flushed with tap water increases with B-value, but the shape of the relationship between Vp and B-value is quite different from the theoretical prediction. The possible explanation for the discrepancy between laboratory measurement and theoretical prediction lies in that the air exists in the water as air bubbles and therefore the pore fluid （air-water mixture） is heterogeneous instead of homogenous assumed in the theoretical prediction.
基金Project(50934006) supported by the National Natural Science Foundation of ChinaProject(2010CB732004) supported by the National Basic Research Program of China+1 种基金Project(2009ssxt230) supported by the Central South University Innovation Fund,ChinaProject(CX2011B119) supported by the Graduated Students’Research and Innovation Fund of Hunan Province,China
文摘Due to the complex features of rock mass blastability assessment systems, an evaluation model of rock mass blastability was established on the basis of the unascertained measurement （UM） theory and the actual characteristics of the project. Considering a comprehensive range of intact rock properties and discontinuous structures of rock mass, twelve main factors influencing the evaluation blastability of rock mass were taken into account in the UM model, and the blastability evaluation index system of rock mass was constructed. The unascertained evaluation indices corresponding to the selected factors for the actual situation were solved both qualitatively and quantitatively. Then, the UM function of each evaluation index was obtained based on the initial data for the analysis of the blastability of six rock mass at a highway improvement cutting site in North Wales. The index weights of the factors were calculated by entropy theory, and credible degree identification （CDI） criteria were established according to the UM theory. The results of rock mass blastability evaluation were obtained by the CDI criteria. The results show that the UM model assessment results agree well with the actual records, and are consistent with those of the fuzzy sets evaluation method. Meanwhile, the unascertained superiority degree of rock mass blastability of samples S1-$6 which can be calculated by scoring criteria are 3.428 5, 3.453 3, 4.058 7, 3.675 9, 3.516 7 and 3.289 7, respectively. Furthermore, the proposed method can take into account large amount of uncertain information in blastability evaluation, which can provide an effective, credible and feasible way for estimating the blastability of rock mass. Engineering practices show that it can complete the blastability assessment systematically and scientifically without any assumption by the proposed model, which can be applied to practical engineering.
基金Project(CDJZR10210009) supported by Central College General Fund for Natural Science of Chongqing City,China
文摘To quantify the energy consumption in the process of production, transportation and processing of energy carriers, the life cycle of building energy used can be divided into two phases： on-site phase and embodied phase. As for the embodied phase, with the data in existing statistic yearbook, the consumption items of energy production and transportation were investigated. And based on the life cycle theory, an embodied coefficient of energy carriers was proposed to quantify the embodied energy consumption. Moreover, a calculation method for the embodied coefficient of energy carriers was deduced using Leontief inverse matrix based on the existing data sources. With relevant data of 2005-2007 in China, the embodied coefficients in 2005-2007 were obtained, in which the values for natural gas and thermal power are around 1.3 and 3. l, respectively; while they are 1.03-1.08 for other selected energy carriers. In addition, it is also found that the consumption in the production and processing accounts for more than 75%.
基金Project(2014CFB801)supported by Natural Science Foundation of Hubei Province of ChinaProject(11304236)supported by the National Natural Science Foundation of China
文摘Based on the empirical electronic theory of solids and molecules （EET）, the actual model for unit cell of cementite （0-FeaC） was built and the valence electron structures （VES） of cementite with specified site and a number of Fe atoms substituted by alloying atoms of M （ M=Cr, V, W, Mo, Mn ） were computed by statistical method. By defining P as the stability factor, the stability of alloyed cementite with different numbers and sites of Fe atoms substituted by M was calculated. Calculation results show that the density of lattice electrons, the symmetry of distribution of covalent electron pairs and bond energy have huge influence on the stability of alloyed cementite. It is more stable as M substitutes for FeE than for Fe1. The alloyed cementite is the most stable when Cr, Mo, W and V substitute for 2 atoms of Fe2 at the sites of Nos. 2 and 3 （or No. 6 and No. 7）. The stability of alloyed cementite decreases gradually as being substitutional doped by W, Cr, V, Mo and Mn.
