There are some inherent defects for the polyolefin based lithium battery separator,such as,poor thermal stability,poor electrolyte wettability and low porosity,which limit the development of lithium battery.An importa...There are some inherent defects for the polyolefin based lithium battery separator,such as,poor thermal stability,poor electrolyte wettability and low porosity,which limit the development of lithium battery.An important way to improve the performance of lithium battery is to improve the separator.Here,three novel separators combined with metal-organic framework materials(MOFs)and carbon materials were prepared by using the in situ growth method and the adsorption combination method simultaneously.The result showed that compared with the polypropylene separator,the porosity and electrolyte wettability were significantly improved in view of these novel polypropylene separators combined with MOFs and carbon materials.Meanwhile,the electrochemical performance of lithium battery equipped with the polypropylene separator combined with MOFs materials and carbon materials was also improved.The result showed that lithium batteries equipped with polypropylene separator combined with MOFs and carbon materials had higher capacity in the first charge and discharge cycle and better electrochemical kinetic reaction processes.展开更多
Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently.The development and utilization of renewable,sustainable,and clean energy sources,...Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently.The development and utilization of renewable,sustainable,and clean energy sources,such as wind and solar,are crucial.However,the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent.Aqueous zinc-ion batteries(AZIBs)have received widespread attention due to their unique advantages,such as high energy density,cost-effectiveness,environmental friendliness,and safety.However,AZIBs face significant challenges,mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries,leading to battery failure.Therefore,reducing the formation of zinc dendrites is crucial for improving the performance of AZIBs.This review systematically and comprehensively comprehends the current strategies and advances in inhibiting the formation of zinc dendrites.By comprehensively analyzing the latest developments in zinc anode,electrolyte,separator design and modification,as well as other novel mechanisms,it provides researchers with a thorough understanding to guide future research and advance the development of AZIBs.展开更多
In order to characterize the voltage behavior of a lithium-ion battery for on-board electric vehicle battery management and control applications,a battery model with a moderate complexity was established.The battery o...In order to characterize the voltage behavior of a lithium-ion battery for on-board electric vehicle battery management and control applications,a battery model with a moderate complexity was established.The battery open circuit voltage (OCV) as a function of state of charge (SOC) was depicted by the Nernst equation.An equivalent circuit network was adopted to describe the polarization effect of the lithium-ion battery.A linear identifiable formulation of the battery model was derived by discretizing the frequent-domain description of the battery model.The recursive least square algorithm with forgetting was applied to implement the on-line parameter calibration.The validation results show that the on-line calibrated model can accurately predict the dynamic voltage behavior of the lithium-ion battery.The maximum and mean relative errors are 1.666% and 0.01%,respectively,in a hybrid pulse test,while 1.933% and 0.062%,respectively,in a transient power test.The on-line parameter calibration method thereby can ensure that the model possesses an acceptable robustness to varied battery loading profiles.展开更多
A novel 50 kW fast charger was proposed for electric vehicles. The proposed fast charger is divided into two main sections an AC-DC converter performing a PFC function and a DC-DC converter performing a charging funct...A novel 50 kW fast charger was proposed for electric vehicles. The proposed fast charger is divided into two main sections an AC-DC converter performing a PFC function and a DC-DC converter performing a charging function. A transformer including leakage inductances was used in the AC-DC converter in order to obtain isolation and inductance. A series-connection topology was used in the DC-DC converter between the DC-bus and outlet. This topology enables high power conversion efficiency up to 95% for the DC-DC converter. In order to reduce the impact of the 50 kW charging on the AC grid, the proposed fast charger system includes a buffering battery unit between the two main power conversion units. This leads to reductions in the power installation costs of power companies and to improvements in the power quality were verified through simulations and experimental results. on the AC grid. The performances of the proposed fast charger system展开更多
Motion equations of AUV(autonomous underwater vehicle) load separation with the constraint of anchor chain is derived.Based on proper engineering assumptions for anchor chain,system viewpoint is used to found the moti...Motion equations of AUV(autonomous underwater vehicle) load separation with the constraint of anchor chain is derived.Based on proper engineering assumptions for anchor chain,system viewpoint is used to found the motion equations,and the D'Alembert principle is used to eliminate the constraint force of anchor chain.Based on the equations,the motion simulation is carried out to a certain AUV,which reflects the actual condition,and is used for the reference of resrarching AUV load separation motion with the constraint of anchor chain.展开更多
The sluggish kinetics of the sulfur redox reaction(SRR)and the shuttling effect of lithium polysulfides(LiPSs)both restrict the practical application of lithium-sulfur(Li-S)batteries.Heterostructures,with their pronou...The sluggish kinetics of the sulfur redox reaction(SRR)and the shuttling effect of lithium polysulfides(LiPSs)both restrict the practical application of lithium-sulfur(Li-S)batteries.Heterostructures,with their pronounced electroactivity and structural stability,showcase their potential as electrodes/functional separators for lithium-sulfur batteries.Herein,we proposed a bifunctional catalyst exhibiting strong adsorption and rapid catalytic conversion of LiPSs through in situ UV photocatalytic synthesis of Ti_(3)C_(2)@TiO_(2)heterostructure.The TiO_(2)nanoparticles act as the anchoring center for LiPSs,while the electrically conductive Ti_(3)C_(2)ensures the rapid diffusion of these LiPSs from TiO_(2)to the catalytically active Ti_(3)C_(2)layer across heterogeneous interfaces.The Li-S batteries with Ti_(3)C_(2)@TiO_(2)-40 min-PP separator delivered a high initial capacity of 1283 mA∙h/g,which decreased slightly to 691 mA∙h/g after 200 cycles at 1C.This work advances the understanding of the synergistic effect of polysulfide adsorbents and conductive agents in inhibiting shuttle effects,and offers a method for designing polysulfide barriers in lithium-sulfur batteries.展开更多
基金2023 undergraduate Innovation and Entrepreneurship Project of Yichun University(S202310417015)。
文摘There are some inherent defects for the polyolefin based lithium battery separator,such as,poor thermal stability,poor electrolyte wettability and low porosity,which limit the development of lithium battery.An important way to improve the performance of lithium battery is to improve the separator.Here,three novel separators combined with metal-organic framework materials(MOFs)and carbon materials were prepared by using the in situ growth method and the adsorption combination method simultaneously.The result showed that compared with the polypropylene separator,the porosity and electrolyte wettability were significantly improved in view of these novel polypropylene separators combined with MOFs and carbon materials.Meanwhile,the electrochemical performance of lithium battery equipped with the polypropylene separator combined with MOFs materials and carbon materials was also improved.The result showed that lithium batteries equipped with polypropylene separator combined with MOFs and carbon materials had higher capacity in the first charge and discharge cycle and better electrochemical kinetic reaction processes.
文摘Continued growth in energy demand and increased environmental pollution constitute major challenges that need to be addressed urgently.The development and utilization of renewable,sustainable,and clean energy sources,such as wind and solar,are crucial.However,the instability of these intermittent energy sources makes the need for energy storage systems increasingly urgent.Aqueous zinc-ion batteries(AZIBs)have received widespread attention due to their unique advantages,such as high energy density,cost-effectiveness,environmental friendliness,and safety.However,AZIBs face significant challenges,mainly the formation of zinc dendrites that seriously affect the stability and lifetime of the batteries,leading to battery failure.Therefore,reducing the formation of zinc dendrites is crucial for improving the performance of AZIBs.This review systematically and comprehensively comprehends the current strategies and advances in inhibiting the formation of zinc dendrites.By comprehensively analyzing the latest developments in zinc anode,electrolyte,separator design and modification,as well as other novel mechanisms,it provides researchers with a thorough understanding to guide future research and advance the development of AZIBs.
基金Project(50905015) supported by the National Natural Science Foundation of China
文摘In order to characterize the voltage behavior of a lithium-ion battery for on-board electric vehicle battery management and control applications,a battery model with a moderate complexity was established.The battery open circuit voltage (OCV) as a function of state of charge (SOC) was depicted by the Nernst equation.An equivalent circuit network was adopted to describe the polarization effect of the lithium-ion battery.A linear identifiable formulation of the battery model was derived by discretizing the frequent-domain description of the battery model.The recursive least square algorithm with forgetting was applied to implement the on-line parameter calibration.The validation results show that the on-line calibrated model can accurately predict the dynamic voltage behavior of the lithium-ion battery.The maximum and mean relative errors are 1.666% and 0.01%,respectively,in a hybrid pulse test,while 1.933% and 0.062%,respectively,in a transient power test.The on-line parameter calibration method thereby can ensure that the model possesses an acceptable robustness to varied battery loading profiles.
基金Project supported by Changwon National University in 2011-2012
文摘A novel 50 kW fast charger was proposed for electric vehicles. The proposed fast charger is divided into two main sections an AC-DC converter performing a PFC function and a DC-DC converter performing a charging function. A transformer including leakage inductances was used in the AC-DC converter in order to obtain isolation and inductance. A series-connection topology was used in the DC-DC converter between the DC-bus and outlet. This topology enables high power conversion efficiency up to 95% for the DC-DC converter. In order to reduce the impact of the 50 kW charging on the AC grid, the proposed fast charger system includes a buffering battery unit between the two main power conversion units. This leads to reductions in the power installation costs of power companies and to improvements in the power quality were verified through simulations and experimental results. on the AC grid. The performances of the proposed fast charger system
文摘Motion equations of AUV(autonomous underwater vehicle) load separation with the constraint of anchor chain is derived.Based on proper engineering assumptions for anchor chain,system viewpoint is used to found the motion equations,and the D'Alembert principle is used to eliminate the constraint force of anchor chain.Based on the equations,the motion simulation is carried out to a certain AUV,which reflects the actual condition,and is used for the reference of resrarching AUV load separation motion with the constraint of anchor chain.
基金Project(2023JJ10062)supported by the Hunan Province Funds for Distinguished Young Scientists,ChinaProject(2023RC3051)supported by the Science and Technology Innovation Program of Hunan Province of ChinaProject(kh2401026)supported by the Science and Technology Program of Changsha of China。
文摘The sluggish kinetics of the sulfur redox reaction(SRR)and the shuttling effect of lithium polysulfides(LiPSs)both restrict the practical application of lithium-sulfur(Li-S)batteries.Heterostructures,with their pronounced electroactivity and structural stability,showcase their potential as electrodes/functional separators for lithium-sulfur batteries.Herein,we proposed a bifunctional catalyst exhibiting strong adsorption and rapid catalytic conversion of LiPSs through in situ UV photocatalytic synthesis of Ti_(3)C_(2)@TiO_(2)heterostructure.The TiO_(2)nanoparticles act as the anchoring center for LiPSs,while the electrically conductive Ti_(3)C_(2)ensures the rapid diffusion of these LiPSs from TiO_(2)to the catalytically active Ti_(3)C_(2)layer across heterogeneous interfaces.The Li-S batteries with Ti_(3)C_(2)@TiO_(2)-40 min-PP separator delivered a high initial capacity of 1283 mA∙h/g,which decreased slightly to 691 mA∙h/g after 200 cycles at 1C.This work advances the understanding of the synergistic effect of polysulfide adsorbents and conductive agents in inhibiting shuttle effects,and offers a method for designing polysulfide barriers in lithium-sulfur batteries.
