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金沙江乌东德水电站设计重大技术问题研究 被引量:16
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作者 钮新强 石伯勋 翁永红 《人民长江》 北大核心 2014年第20期1-7,11,共8页
金沙江乌东德水电站装机容量为10 200 MW,是世界上少有的巨型水电站及特高拱坝。2003年开始预可行性研究,历经11年艰苦高强度的勘察设计研究,完成了工程开发方案及坝址选择,结合成昆铁路扩能改造,论证确定了由原950 m适当提高至975 m的... 金沙江乌东德水电站装机容量为10 200 MW,是世界上少有的巨型水电站及特高拱坝。2003年开始预可行性研究,历经11年艰苦高强度的勘察设计研究,完成了工程开发方案及坝址选择,结合成昆铁路扩能改造,论证确定了由原950 m适当提高至975 m的正常蓄水位方案。根据坝址峡谷区地形地质条件,比较确定了最大坝高270 m混凝土双曲拱坝、两岸各布置6台850 MW水轮发电机组地下电站、左岸边布置3条泄洪洞的枢纽总体布置格局,完成了枢纽建筑物设计,并解决了枢纽工程设计中的多个重大技术难题。 展开更多
关键词 混凝土双曲拱坝 正常蓄水位选择 枢纽建筑物 1 000 MW水力发电机组 乌东德水电站
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Rock-forming mechanism of Fenghuangshan rockbody in Tongling area
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作者 邵拥军 彭省临 +3 位作者 吴淦国 刘亮明 赖健清 张达 《Journal of Central South University of Technology》 2003年第3期216-221,共6页
Based on the detailed geological investigation and record of galleries and drill holes, a new idea has been advanced that granodiorite is earlier than quartz monzodiorite porphyry. Both of them are products of two dif... Based on the detailed geological investigation and record of galleries and drill holes, a new idea has been advanced that granodiorite is earlier than quartz monzodiorite porphyry. Both of them are products of two different magmatic intrusive activities. The analysis results of trace elements show that the Sr content is beyond any other crustal rock and the Th content is beyond that of Ta. The whole-rock analysis indicates that rockbody is rich in CaO and poor in K2O. In the composition of Pb istope of rockbody, the ratio of 207 Pb to 204Pb is less than 15. 60. All these show that the magma mainly comes from the upper mantle. Ti,Zr,Cr,Nb trace elements and the relation between the Gardini index(τ) and the Rittmann index(σ) indicate that the rockbodies are formed in the orogenic belt and island arc tectonic setting. The summation (2REE) and the characteristic value(m( La)/m( Yb)) of the rare earth elements show that the original rock is alkalic basalt. The analysis of the characteristic values of REE and the quantitative modeling calculation indicate that the rock-forming process is dominated by mixed crystallization. According to the analysis on the rock-forming order, magmatic source, tectonic setting and rock-forming process, combined with the achievements of regional rock-controlling structures and division of sublayer of crust, it is believed that Fenghuangshan rock body derives from the deep-seated alkalic basalt magma. The rock-forming process has undertaken sialic and calcareous assimilation and contamination of two different degrees. The rock-forming model belongs to the typical assimilation and fractional cryatalization mechanism. 展开更多
关键词 complex rockbody upper mantle erogenic belt island arc alkalic basalt assimilation and fractional crytalization mechanism
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CS_2在Ag-S键中的插入反应(Ⅲ)——[PyAg(SC_6H_2Bu_3~t-2,4,6)]_n及其CS_2插入产物[(PPh_3)_2Ag(S_2CSC_6H_2Bu_3~t-2,4,6)]·CHCl_3的合成和晶体结构
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作者 汤卡罗 吴德冬 +1 位作者 金祥林 唐有棋 《北京大学学报(自然科学版)》 CAS CSCD 北大核心 1992年第4期446-454,共9页
2,4,6-三特丁基硫酚银化合物在吡啶中重结晶,获得一维双链带状高聚物[PyAg(SC_6H_2Bu_3~t-2,4,6)]~n(晶体Ⅰ)。该硫酚银化合物在三苯基膦存在下与CS_2反应,得到单核银的CS_2插入产物[(PPh_3)_2Ag(S_2CSC_6H_2Bu_3~t-2,4,6)]·CHCl_3... 2,4,6-三特丁基硫酚银化合物在吡啶中重结晶,获得一维双链带状高聚物[PyAg(SC_6H_2Bu_3~t-2,4,6)]~n(晶体Ⅰ)。该硫酚银化合物在三苯基膦存在下与CS_2反应,得到单核银的CS_2插入产物[(PPh_3)_2Ag(S_2CSC_6H_2Bu_3~t-2,4,6)]·CHCl_3(晶体Ⅱ)。用X射线单晶衍射法测定了它们的晶体结构。 展开更多
关键词 CS2 插入反应 银一硫键 硫氏碳
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