The two kinds of rigid polyurethane （PU） foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in...The two kinds of rigid polyurethane （PU） foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.展开更多
A study was conducted to identify the differences in the decompositions of leaf litter, lignin and carbohydrate between coniferous forest and broadleaf forest at 20℃ and 30℃ in Huangshan Mountain, Anhui Province, Ch...A study was conducted to identify the differences in the decompositions of leaf litter, lignin and carbohydrate between coniferous forest and broadleaf forest at 20℃ and 30℃ in Huangshan Mountain, Anhui Province, China. Results showed that at 20℃ mass loss of leaf litter driven by microbial decomposers was higher in broadleaf forest than that in coniferous forest, whereas the difference in mass loss of leaf litter was not significant at 30℃. The temperature increase did not affect the mass loss of leaf litter for coniferous forest treatment, but significantly reduced the decomposition rate for broadleaf forest treatment. The functional decomposers of microorganism in broadleaf forest produced a higher lignin decomposition rate at 20℃, compared to that in coniferous forest, but the difference in lignin decomposition was not found between two forest types at 30℃. Improved temperature increased the lignin decomposition for both broadleaf and coniferous forest. Additionally, the functional group of microorganism from broadleaf forest showed marginally higher carbohydrate loss than that from coniferous forest at both temperatures. Temperature increase reduced the carbohydrate decomposition for broadleaf forest, while only a little reduce was found for coniferous forest. Remarkable differences occurred in responses between most enzymes （Phenoloxidase, peroxidase, !5-glucosidase and endocellulase） and decomposition rate of leaf litter to forest type and temperature, although there exist strong relationships between measured enzyme activities and decomposition rate in most cases. The reason is that more than one enzyme contribute to the mass loss of leaf litter and organic chemical components. In conclusion, at a community scale the coniferous and broadleaf forests differed in their temperature-decomposition relationships.展开更多
Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR s...Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.展开更多
To convert the non biodegradable sodium lignin sulfonate into biodegradable substances, the sodium lignin sulfonate in the water was ozonized and the pH value, dissolved organic carbon(DOC), ultraviolet absorbency at...To convert the non biodegradable sodium lignin sulfonate into biodegradable substances, the sodium lignin sulfonate in the water was ozonized and the pH value, dissolved organic carbon(DOC), ultraviolet absorbency at λ =254 nm(UVA) and the biodegradability of the ozonation effluent were measured. The non biodegradable sodium lignin sulfonate can be partly converted into biodegradable substances by ozonation (about 38 76%). In the ozonation process, there is little DOC decrease, but much UVA decrease and obvious pH drop.展开更多
The bark of Pteroce/tis tatarinowii is a raw material for manufacturing XuanPaper. The effects of Ca^(2+) concentrations on the accumulation of mineral elements in the bark,leaf and root of Pteroceltis tatarinowii wer...The bark of Pteroce/tis tatarinowii is a raw material for manufacturing XuanPaper. The effects of Ca^(2+) concentrations on the accumulation of mineral elements in the bark,leaf and root of Pteroceltis tatarinowii were studied under controlled conditions. The types ofHoagland nutrient solution with three Ca^(2+) concentrations levels (200, 400 and 600 μg·g^(-1))and a control (without Ca^(2+)) were designed to culture Pteroceltis tatarinowii. After 6 months,contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and barkwere analyzed. The results indicated that Ca accumulations content in the root, leaf and bark hadpositively relation with Ca^(2+) concentrations (200, 400, 600 μg · g^(-1)), and the order of theCa content in the three components was root>leaf>bark. Ca content in the root treated with 600 μg·g^(-1) Ca^(2+) concentrations was 5.5 times as high as that of the control, and about 1.4 times ashigh as that of the root treated in 200 and 400 μg/g Ca^(2+) concentrations respectively. On thecontrary, K and Mg contents in the root, leaf and bark were negatively related to Ca^(2+)concentrations, especially in the bark, and their accumulation trend followed the order ofleaf>root>bark. K content in the bark treated with 600 μg ·g^(-1) Ca^(2+) concentrations was 39.3%of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 μg ·g^(-1)and 400 μg ·g^(-1) Ca^(2+) concentrations respectively; Mg content in the bark treated with 600μg ·g^(-1) Ca^(2+) concentrations was 23.4% of that of the control, and was 27.1% and 35.4% ofthat of the bark treated with 200 and 400 μg·g^(-1) Ca^(2+) concentrations respectively. Comparedwith the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca^(2+)concentrations and their contents were in the order: root>leaf>bark. Based on the results of thisstudy, the experiment has been useful for providing academic bases in improving the bark quality ofPteroceltis tatarinowii on non-limestone soil.展开更多
The relationship between eco-hydrographic benefit of forest vegetation and climatic environmental factors is one of the focuses in the research on environmental protection and ecosystem countermeasures in Wetland. Th...The relationship between eco-hydrographic benefit of forest vegetation and climatic environmental factors is one of the focuses in the research on environmental protection and ecosystem countermeasures in Wetland. The runoff, sediment and soil moisture rate dynamics in Robinia pseudoacacia plantation and its clearcut area were investigated in the natural runoff experiment plots in Yellow River Delta Wet- land, Shandong Province, China. The correlation of height increment ofR. pseudoacacia with nine climate factors such as light, water, heat, etc. was analyzed by stepwise regression analysis. The results showed that the amounts of runoff and sediment in clearcut area of R. pseudoacacia were 53.9%-150.8% and 172.8%-387.1% higher than that in Robinia pseudoacacia plantation, respectively. The runoff peak value in R. pseudoacacia stand was obviously lower than that in clerarcut area, meantime, the occurrence of runoffpeak in R. pseudoacacia stand was 25 min later than in its clerarcut area. The soil moisture rates in R. pseudoacacia stand and its clearcut varied periodically with annual rainfall precipitation in both dry season and humid season. The annual mean soil moisture rate in R. pseudoacacia stand was 23.3%-25.6% higher than that in its clearcut area. Meanwhile, a regression model reflecting the correlation between the height increment of R. pseudoacacia and climatic factors was developed by stepwise regression procedure method. It showed that the light was the most important factor for the height increment ofR. pseudoacacia, followed by water and heat factors.展开更多
The bark of Pteroceltis tatarinowii is a raw material for manufacturing Xuan Paper. The effects of Ca2+ concentrations on the accumulation of mineral elements in the bark, leaf and root of Pteroceltis tatarinowii were...The bark of Pteroceltis tatarinowii is a raw material for manufacturing Xuan Paper. The effects of Ca2+ concentrations on the accumulation of mineral elements in the bark, leaf and root of Pteroceltis tatarinowii were studied under controlled condi-tions. The types of Hoagland nutrient solution with three Ca2+ concentrations levels (200, 400 and 600 靏g-1) and a control (without Ca2+) were designed to culture Pteroceltis tatarinowii. After 6 months, contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and bark were analyzed. The results indicated that Ca accumulations content in the root, leaf and bark had positively relation with Ca2+ concentrations (200, 400, 600 靏g-1), and the order of the Ca content in the three components was root】leaf】bark. Ca content in the root treated with 600 靏g-1 Ca2+ concentrations was 5.5 times as high as that of the control, and about 1.4 times as high as that of the root treated in 200 and 400 靏/g Ca2+ concentrations respectively. On the contrary, K and Mg contents in the root, leaf and bark were negatively related to Ca2+ concentrations, especially in the bark, and their accumulation trend followed the order of leaf】root】bark. K content in the bark treated with 600 靏g-1 Ca2+ con-centrations was 39.3% of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 靏g-1 and 400靏g-1 Ca2+ concentrations respectively; Mg content in the bark treated with 600 靏g-1 Ca2+ concentrations was 23.4% of that of the control, and was 27.1% and 35.4% of that of the bark treated with 200 and 400 靏g-1 Ca2+ concentrations respectively. Com-pared with the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca2+ concentrations and their contents were in the order: root】leaf】bark. Based on the results of this study, the experiment has been useful for providing academic bases in improving the bark quality of Pteroceltis tatarinowii on non-limestone soil.展开更多
Leaf litterfall,litter decomposition and nutrient return through litterfall of three dominant species,i.e.Quercus serrata,Schima wallichi and Lithocarpus dealbata were studied in different months throughout the year t...Leaf litterfall,litter decomposition and nutrient return through litterfall of three dominant species,i.e.Quercus serrata,Schima wallichi and Lithocarpus dealbata were studied in different months throughout the year to assess the input and release of nutrient in the forest soil of a sub-tropical mixed oak forest of Manipur,northeastern India.Oaks in northeastern region of India are economically important species for the production of Tasar silk.The monthly litterfall ranged from 25.6 g·m^-2（July） to 198.0 g·m^-2（February） and annual litterfall was 1093.8g·m^-2 in the forest site.At initial month（on November 3）,the concentrations of N and C were the highest in L.dealbata,followed by Q.serrata and lowest in S.wallichi,whereas lignin and cellulose concentrations at initial month were the highest in S.wallichi,followed by Q.serrata and L.dealbata.L.dealbata（k=0.54） exhibited a high rate of litter decomposition,coinciding with high concentrations of N and C and low cellulose in the litter at initial month.However,low rate of litter decomposition in S.wallichi（k=0.33） coincided with low value of N and C and highest value of lignin and cellulose at initial month.The remaining biomass in different months was positively correlated with the lignin,C,C/N ratio and cellulose,but it negatively correlated with nitrogen concentrations at initial month.The rate of litter decomposition was the highest in rainy summer months,owing to congenial environmental conditions and lowest rate of litter decomposition in cool and dry winter months.展开更多
The concentration, distribution, and occurrence of rare earth elements (REEs) in coals as well as stone coalsin different geological periods from Chongqing were studied. The results show that the REE content in coals ...The concentration, distribution, and occurrence of rare earth elements (REEs) in coals as well as stone coalsin different geological periods from Chongqing were studied. The results show that the REE content in coals fromChongqing is much higher than that of the ordinary Chinese coals, the Late Paleozoic coals from North China, UScoals, and the world coals. Although the concentration of light rare earth elements (LREE) is higher than that of heavyrare earth elements (HREE), the ratio of LREE to HREE is as low as 5.11. The REE content decreases with thecoal-formation periods from old to new. The REE content in the Sinian stone coal is the highest, but it is the lowest inEarly Jurassic coals. The similar REE contents in bituminous coals and anthracite show that the metamorphism has alittle influence on REE content in coal. In addition, silicate association dominates the occurrence mode of REEs incoals from Chongqing.展开更多
文摘The two kinds of rigid polyurethane （PU） foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight. The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams. The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples. The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently. Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples. The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.
基金This study was supported by National Natural Sci-ence Foundation of China (30470299)Key Project of National Sci-ence Foundation of China (30430570).
文摘A study was conducted to identify the differences in the decompositions of leaf litter, lignin and carbohydrate between coniferous forest and broadleaf forest at 20℃ and 30℃ in Huangshan Mountain, Anhui Province, China. Results showed that at 20℃ mass loss of leaf litter driven by microbial decomposers was higher in broadleaf forest than that in coniferous forest, whereas the difference in mass loss of leaf litter was not significant at 30℃. The temperature increase did not affect the mass loss of leaf litter for coniferous forest treatment, but significantly reduced the decomposition rate for broadleaf forest treatment. The functional decomposers of microorganism in broadleaf forest produced a higher lignin decomposition rate at 20℃, compared to that in coniferous forest, but the difference in lignin decomposition was not found between two forest types at 30℃. Improved temperature increased the lignin decomposition for both broadleaf and coniferous forest. Additionally, the functional group of microorganism from broadleaf forest showed marginally higher carbohydrate loss than that from coniferous forest at both temperatures. Temperature increase reduced the carbohydrate decomposition for broadleaf forest, while only a little reduce was found for coniferous forest. Remarkable differences occurred in responses between most enzymes （Phenoloxidase, peroxidase, !5-glucosidase and endocellulase） and decomposition rate of leaf litter to forest type and temperature, although there exist strong relationships between measured enzyme activities and decomposition rate in most cases. The reason is that more than one enzyme contribute to the mass loss of leaf litter and organic chemical components. In conclusion, at a community scale the coniferous and broadleaf forests differed in their temperature-decomposition relationships.
基金This study was sponsored by the Research Funding for Key Laboratory of Cellulose and Ligno cellulosics Chemistry, Guangzhou Institute of Chemistry, Chinese Academy of Sciences (No. LCLC-2004-158)the National Natural Science Foundation of Fujian(No. Z0513015)
文摘Rice husk high boiling solvent lignin （RHL） was prepared by high boiling solvent method, and its characteristics was analyzed by using chemical composition analysis, infrared spectroscopy, and ^1H-NMR and ^13C-NMR spectroscopy. The optimum prepared condition was that the rice husk with 70%-90% aqueous solution of 1, 4-butanediol was mixed with autoclave, under a certain weight ratio of solid raw material and solvent, heated to 200-220℃ for 1.0-3.0 h, then water-insoluble RHL was separated from the liquor reaction mixture by water precipitation. Results suggested that the lower digestion temperature and concentration of 1,4-butanediol were both unfavorable for extracting lignin. Chemical weight-average molecular weight of RHL was 1939 g·mol^-1, and the residual polysaccharide content was 5.12%. The ^1H-NMR spectra of RHL showed the relative intensity ratio, aliphatic over aromatic methoxyl groups, situated at 3.5-3.8 and 3.8-4.0 ppm, respectively. The results from ^13C-NMR spectra showed that β-O-4 bond and β-5 carbon-carbon linkage were the major linkages between RHL units. The C9-formula of RHL was calculated by the experiment data.
文摘To convert the non biodegradable sodium lignin sulfonate into biodegradable substances, the sodium lignin sulfonate in the water was ozonized and the pH value, dissolved organic carbon(DOC), ultraviolet absorbency at λ =254 nm(UVA) and the biodegradability of the ozonation effluent were measured. The non biodegradable sodium lignin sulfonate can be partly converted into biodegradable substances by ozonation (about 38 76%). In the ozonation process, there is little DOC decrease, but much UVA decrease and obvious pH drop.
基金This paper is supported by National Natural Science Foundation of China (No. 39970608).
文摘The bark of Pteroce/tis tatarinowii is a raw material for manufacturing XuanPaper. The effects of Ca^(2+) concentrations on the accumulation of mineral elements in the bark,leaf and root of Pteroceltis tatarinowii were studied under controlled conditions. The types ofHoagland nutrient solution with three Ca^(2+) concentrations levels (200, 400 and 600 μg·g^(-1))and a control (without Ca^(2+)) were designed to culture Pteroceltis tatarinowii. After 6 months,contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and barkwere analyzed. The results indicated that Ca accumulations content in the root, leaf and bark hadpositively relation with Ca^(2+) concentrations (200, 400, 600 μg · g^(-1)), and the order of theCa content in the three components was root>leaf>bark. Ca content in the root treated with 600 μg·g^(-1) Ca^(2+) concentrations was 5.5 times as high as that of the control, and about 1.4 times ashigh as that of the root treated in 200 and 400 μg/g Ca^(2+) concentrations respectively. On thecontrary, K and Mg contents in the root, leaf and bark were negatively related to Ca^(2+)concentrations, especially in the bark, and their accumulation trend followed the order ofleaf>root>bark. K content in the bark treated with 600 μg ·g^(-1) Ca^(2+) concentrations was 39.3%of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 μg ·g^(-1)and 400 μg ·g^(-1) Ca^(2+) concentrations respectively; Mg content in the bark treated with 600μg ·g^(-1) Ca^(2+) concentrations was 23.4% of that of the control, and was 27.1% and 35.4% ofthat of the bark treated with 200 and 400 μg·g^(-1) Ca^(2+) concentrations respectively. Comparedwith the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca^(2+)concentrations and their contents were in the order: root>leaf>bark. Based on the results of thisstudy, the experiment has been useful for providing academic bases in improving the bark quality ofPteroceltis tatarinowii on non-limestone soil.
基金the National "11th Five Year" Plan of Science and technology (2006BAD26B06,2006BAD03A1205) Ecological Restore Project of Water Resources Ministry of China (2006-2008)
文摘The relationship between eco-hydrographic benefit of forest vegetation and climatic environmental factors is one of the focuses in the research on environmental protection and ecosystem countermeasures in Wetland. The runoff, sediment and soil moisture rate dynamics in Robinia pseudoacacia plantation and its clearcut area were investigated in the natural runoff experiment plots in Yellow River Delta Wet- land, Shandong Province, China. The correlation of height increment ofR. pseudoacacia with nine climate factors such as light, water, heat, etc. was analyzed by stepwise regression analysis. The results showed that the amounts of runoff and sediment in clearcut area of R. pseudoacacia were 53.9%-150.8% and 172.8%-387.1% higher than that in Robinia pseudoacacia plantation, respectively. The runoff peak value in R. pseudoacacia stand was obviously lower than that in clerarcut area, meantime, the occurrence of runoffpeak in R. pseudoacacia stand was 25 min later than in its clerarcut area. The soil moisture rates in R. pseudoacacia stand and its clearcut varied periodically with annual rainfall precipitation in both dry season and humid season. The annual mean soil moisture rate in R. pseudoacacia stand was 23.3%-25.6% higher than that in its clearcut area. Meanwhile, a regression model reflecting the correlation between the height increment of R. pseudoacacia and climatic factors was developed by stepwise regression procedure method. It showed that the light was the most important factor for the height increment ofR. pseudoacacia, followed by water and heat factors.
基金This paper is supported by National Natural Science Foundation of China (No. 39970608).
文摘The bark of Pteroceltis tatarinowii is a raw material for manufacturing Xuan Paper. The effects of Ca2+ concentrations on the accumulation of mineral elements in the bark, leaf and root of Pteroceltis tatarinowii were studied under controlled condi-tions. The types of Hoagland nutrient solution with three Ca2+ concentrations levels (200, 400 and 600 靏g-1) and a control (without Ca2+) were designed to culture Pteroceltis tatarinowii. After 6 months, contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and bark were analyzed. The results indicated that Ca accumulations content in the root, leaf and bark had positively relation with Ca2+ concentrations (200, 400, 600 靏g-1), and the order of the Ca content in the three components was root】leaf】bark. Ca content in the root treated with 600 靏g-1 Ca2+ concentrations was 5.5 times as high as that of the control, and about 1.4 times as high as that of the root treated in 200 and 400 靏/g Ca2+ concentrations respectively. On the contrary, K and Mg contents in the root, leaf and bark were negatively related to Ca2+ concentrations, especially in the bark, and their accumulation trend followed the order of leaf】root】bark. K content in the bark treated with 600 靏g-1 Ca2+ con-centrations was 39.3% of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 靏g-1 and 400靏g-1 Ca2+ concentrations respectively; Mg content in the bark treated with 600 靏g-1 Ca2+ concentrations was 23.4% of that of the control, and was 27.1% and 35.4% of that of the bark treated with 200 and 400 靏g-1 Ca2+ concentrations respectively. Com-pared with the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca2+ concentrations and their contents were in the order: root】leaf】bark. Based on the results of this study, the experiment has been useful for providing academic bases in improving the bark quality of Pteroceltis tatarinowii on non-limestone soil.
基金supported by UGC-Special Assistance Programme by providing the financial assistance to one ofthe authors (NB Devi)
文摘Leaf litterfall,litter decomposition and nutrient return through litterfall of three dominant species,i.e.Quercus serrata,Schima wallichi and Lithocarpus dealbata were studied in different months throughout the year to assess the input and release of nutrient in the forest soil of a sub-tropical mixed oak forest of Manipur,northeastern India.Oaks in northeastern region of India are economically important species for the production of Tasar silk.The monthly litterfall ranged from 25.6 g·m^-2（July） to 198.0 g·m^-2（February） and annual litterfall was 1093.8g·m^-2 in the forest site.At initial month（on November 3）,the concentrations of N and C were the highest in L.dealbata,followed by Q.serrata and lowest in S.wallichi,whereas lignin and cellulose concentrations at initial month were the highest in S.wallichi,followed by Q.serrata and L.dealbata.L.dealbata（k=0.54） exhibited a high rate of litter decomposition,coinciding with high concentrations of N and C and low cellulose in the litter at initial month.However,low rate of litter decomposition in S.wallichi（k=0.33） coincided with low value of N and C and highest value of lignin and cellulose at initial month.The remaining biomass in different months was positively correlated with the lignin,C,C/N ratio and cellulose,but it negatively correlated with nitrogen concentrations at initial month.The rate of litter decomposition was the highest in rainy summer months,owing to congenial environmental conditions and lowest rate of litter decomposition in cool and dry winter months.
文摘The concentration, distribution, and occurrence of rare earth elements (REEs) in coals as well as stone coalsin different geological periods from Chongqing were studied. The results show that the REE content in coals fromChongqing is much higher than that of the ordinary Chinese coals, the Late Paleozoic coals from North China, UScoals, and the world coals. Although the concentration of light rare earth elements (LREE) is higher than that of heavyrare earth elements (HREE), the ratio of LREE to HREE is as low as 5.11. The REE content decreases with thecoal-formation periods from old to new. The REE content in the Sinian stone coal is the highest, but it is the lowest inEarly Jurassic coals. The similar REE contents in bituminous coals and anthracite show that the metamorphism has alittle influence on REE content in coal. In addition, silicate association dominates the occurrence mode of REEs incoals from Chongqing.
