Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relev...Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relevant analytical tests were applied to evaluate the phase and surface property variations of bastnaesite,and isothermal kinetic analysis of bastnaesite pyrolysis and Ce oxidation was performed.The results revealed that bastnaesite decomposed rapidly and accompanied by Ce oxidation,and the gas-solid products were identified as CO_(2),Ce_(7)O_(12),La_(2)O_(3),CeF_(3) and LaF_(3),with Ce oxidation restricted by bastnaesite pyrolysis.As roasting time prolonged,cracks and pores appeared on bastnaesite surface;the BET specific surface and pore diameter increased.In later roasting period,the pore diameter continued to increase but the specific surface decreased,assigned to particle fusion agglomeration and pore consolidation.Additionally,the surface C content reduced and Ce(Ⅳ)content increased gradually as roasting progressed.The reaction kinetics all followed Avrami-Erofeev equations,the reaction orders of bastnaesite pyrolysis and Ce oxidation decreased with decreasing reaction temperature.The calculated activation energies at lower temperatures were higher than those calculated at higher temperatures.This study analyzed the bastnaesite reaction mechanism to supply a reference for the application of suspension roasting technology in bastnaesite smelting.展开更多
A high-speed train travelling from the open air into a narrow tunnel will cause the“sonic boom”at tunnel exit.When the maglev train’s speed reaches 600 km/h,the train-tunnel aerodynamic effect is intensified,so a n...A high-speed train travelling from the open air into a narrow tunnel will cause the“sonic boom”at tunnel exit.When the maglev train’s speed reaches 600 km/h,the train-tunnel aerodynamic effect is intensified,so a new mitigation method is urgently expected to be explored.This study proposed a novel asymptotic linear method(ALM)for micro pressure wave(MPW)mitigation to achieve a constant gradient of initial c ompression waves(ICWs),via a study with various open ratios on hoods.The properties of ICWs and MPWs under various open ratios of hoods were analyzed.The results show that as the open ratio increases,the MPW amplitude at the tunnel exit initially decreases before rising.At the open ratio of 2.28%,the slope of the ICW curve is linearly coincident with a supposed straight line in the ALM,which further reduces the MPW amplitude by 26.9%at 20 m and 20.0%at 50 m from the exit,as compared to the unvented hood.Therefore,the proposed method effectively mitigates MPW and quickly determines the upper limit of alleviation for the MPW amplitude at a fixed train-tunnel operation condition.All achievements provide a ne w potential measure for the adaptive design of tunnel hoods.展开更多
The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO_(2) emission to achieve the goals of carbon peaking and carbon neutrality.The effects of temperatures on suspensi...The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO_(2) emission to achieve the goals of carbon peaking and carbon neutrality.The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR,Py-GC/MS and gas composition analyzer.The mixture reduction process is divided into four stages.In the temperature range of 200-450℃ for mixture,the release of CO_(2),acids,and ketones is dominated in gases products.The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900℃.At 700℃,the volume concentrations of CO,H_(2) and CH_(4) peak at 8.91%,8.90% and 4.91%,respectively.During the suspension magnetization roasting process,an optimal iron concentrate with an iron grade of 70.86%,a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700℃.Therefore,the magnetization reduction could react greatly in the temperature range of 600 to 700℃ owing to the suitable reducing gases.This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.展开更多
Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can b...Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can be well characterized based on various stochastic excitations.A three-dimensional refined spatial random vibration analysis model of high-speed maglev train-bridge coupled system is established in this paper,in which multi-source uncertainty excitation can be considered simultaneously,and the probability density evolution method(PDEM)is adopted to reveal the system-specific uncertainty dynamic characteristic.The motion equation of the maglev vehicle model is composed of multi-rigid bodies with a total 210-degrees of freedom for each vehicle,and a refined electromagnetic force-air gap model is used to account for the interaction and coupling effect between the moving train and track beam bridges,which are directly established by using finite element method.The model is proven to be applicable by comparing with Monte Carlo simulation.By applying the proposed stochastic framework to the high maglev line,the random dynamic responses of maglev vehicles running on the bridges are studied for running safety and stability assessment.Moreover,the effects of track irregularity wavelength range under different amplitude and running speeds on the coupled system are investigated.The results show that the augmentation of train speed will move backward the sensitive wavelength interval,and track irregularity amplitude influences the response remarkably in the sensitive interval.展开更多
In order to explore the precise dynamic response of the maglev train and verify the validity of proposed controller,a maglev guideway-electromagnet-air spring-cabin coupled model is developed in the first step.Based o...In order to explore the precise dynamic response of the maglev train and verify the validity of proposed controller,a maglev guideway-electromagnet-air spring-cabin coupled model is developed in the first step.Based on the coupled model,the stresses of the modules are analyzed,and it is pointed out that the inherent nonlinearity,the inner coupling,misalignments between the sensors and actuators,and external disturbances are the main issues that should be considered for the maglev engineering.Furthermore,a feedback linearization controller based on the mathematical model of a maglev module is derived,in which the nonlinearity,coupling and misalignments are taken into account.Then,to attenuate the effect of external disturbances,a disturbance observer is proposed and the dynamics of the estimation error is analyzed using the input-to-state stability theory.It shows that the error is negligible under a low-frequency disturbance.However,at the high-frequency range,the error is unacceptable and the disturbances can not be compensated in time,which lead to over designed fluctuations of levitation gap,even a clash between the upper surface of electromagnet and lower surface of guideway.To solve this problem,a novel nonlinear acceleration feedback is put forward to enhancing the attenuation ability of fast varying disturbances.Finally,numerical comparisons show that the proposed controller outperforms the traditional feedback linearization controller and maintains good robustness under disturbances.展开更多
Coal slimes are mainly composed of coal and clay particles.The interaction energies among these particles were calculated using extended DLVO(DERJAGUIN-LANDAU-VERWEY-OVERBEEK)theory and the aggregation mechanisms were...Coal slimes are mainly composed of coal and clay particles.The interaction energies among these particles were calculated using extended DLVO(DERJAGUIN-LANDAU-VERWEY-OVERBEEK)theory and the aggregation mechanisms were analyzed based on the settling experiments for coal-kaolinite and coal-montmorillonite suspensions,respectively,under different conditions of water hardness.The results indicate that for coal-kaolinite suspensions,as the water hardness reaches 10.0mol/L,the coal particles aggregate with each other easily,and then,the coal particles may aggregate with kaolinite particles.However,no aggregation occurs between kaolinite particles.A clay platelet network is formed in coal-montmorillonite suspensions by montmorillonite particles and coal particles are captured into the network.Coal and montmorillonite particles settle completely.展开更多
Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roa...Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roasting technology was proposed to recover and utilize the ore.The results showed that under the conditions of microwave pretreatment temperature of 1050℃ for 2 min,a magnetic concentrate with an iron grade of 58.72%at a recovery of 89.32%was obtained by microwave suspension magnetization roasting and magnetic separation.Moreover,compared with the no microwave pretreatment case,the iron grade and recovery increased by 3.17%and 1.58%,respectively.Microwave pretreatment increased the saturation magnetization of the roasted products from 24.974 to 39.236(A∙m^(2))/kg and the saturation susceptibility from 0.179×10^(−3) m^(3)/kg to 0.283×10^(−3) m^(3)/kg.Microcracks were formed between the iron and gangue minerals,and they gradually extended to the core of oolite with the increase in the pretreatment time.The reducing gas diffused from outside to inside along the microcracks,which promoted the selective transformation of the weak magnetic hematite into the strong magnetic magnetite.展开更多
The rheological behavior of fumed silica suspensions in polyethylene glycol(PEG) was studied at steady and oscillatory shear stress using AR 2000 stress controlled rheometer. The systems show reversible shear thickeni...The rheological behavior of fumed silica suspensions in polyethylene glycol(PEG) was studied at steady and oscillatory shear stress using AR 2000 stress controlled rheometer. The systems show reversible shear thickening behavior and the shear-thickening behavior can be explained by the clustering mechanism. The viscosity and the degree of shear-thickening of the systems strongly depend on the mass fraction of the silica, the molecular weigh of PEG and the frequency used in the rheological measurement. The silica volume fraction of the systems is 1.16% 3.62%, corresponding to the mass fraction of 4%9%. The shear-thickening taking place in the low volume fraction may contribute to the fractal nature of the silica. At oscillatory shear stress, when the shear stress is less than the critical stress, the storage modulus decreases significantly, meanwhile the loss modulus and the complex viscosity almost remain unchanged; when the shear stress is larger than the critical stress, the storage modulus, the loss modulus and the complex viscosity increase with the increase of shear stress. The loss modulus is larger than the storage modulus in the range of stress studied and both moduli depend on frequency.展开更多
Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigate...Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.展开更多
A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the movi...A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the moving platform along the guideway,the levitation subsystem uses six pairs of electromagnets to steadily suspend the moving platform over the guideway.The model of the levitation system,which is a typical nonlinear multi-input multi-output coupling system and has many inner nonlinear coupling characteristics,was deduced.For testifying the model,the levitation mechanism was firstly controlled by proportional-integral-differential(PID) control,and then a lot of input-output data were collected for model parameter identification.The least-square parameter identification method was used.The identification results prove that the model is feasible and suitable for the real system.展开更多
Several methods for evaluating the sublayer suspension beneath old pavement with falling weight deflectormeter(FWD), were summarized and the respective advantages and disadvantages were analyzed. Based on these method...Several methods for evaluating the sublayer suspension beneath old pavement with falling weight deflectormeter(FWD), were summarized and the respective advantages and disadvantages were analyzed. Based on these methods, the evaluation principles were improved and a new type of the neural network, functional-link neural network was proposed to evaluate the sublayer suspension with FWD test results. The concept of function link, learning method of functional-link neural network and the establishment process of neural network model were studied in detail. Based on the old pavement over-repairing engineering of Kaiping section, Guangdong Province in G325 National Highway, the application of functional-link neural network in evaluation of sublayer suspension beneath old pavement based on FWD test data on the spot was investigated. When learning rate is 0.1 and training cycles are 405, the functional-link network error is less than 0.000 1, while the optimum chosen 4-8-1 BP needs over 10 000 training cycles to reach the same accuracy with less precise evaluation results. Therefore, in contrast to common BP neural network,the functional-link neural network adopts single layer structure to learn and calculate, which simplifies the network, accelerates the convergence speed and improves the accuracy. Moreover the trained functional-link neural network can be (adopted) to directly evaluate the sublayer suspension based on FWD test data on the site. Engineering practice indicates that the functional-link neural model gains very excellent results and effectively guides the pavement over-repairing construction.展开更多
This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, d...This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, decreases the ride comfort, and restricts the cost of the whole system. Firstly, the interaction model of vehicle-bridge system is developed. Based on the interaction model, the relationship between the control voltage and vibration frequency is solved. Then, the variation of the effective direct component and fundamental harmonic are discussed. Furthermore, from the perspective of energy transmission between the levitation system and bridge, the principle underlying the self-excited vibration is explored, and the influence on the stability is discussed. Finally, in terms of the variation of the characteristic roots, the influence is analyzed further and some conclusions are obtained. This study provides a theoretical guidance for mastering the self-excited vibration problems.展开更多
基金Projects(2022YFC2905800,2021YFC2901000)supported by the National Key R&D Program of ChinaProject(52174242)supported by the National Science and Technology of ChinaProject(52130406)supported by the National Science and Technology Major Project of China。
文摘Roasting bastnaesite concentrates is a crucial process in extracting rare earths.This study explored an efficient suspension roasting technology and investigated the bastnaesite pyrolysis and cerium(Ce)oxidation.Relevant analytical tests were applied to evaluate the phase and surface property variations of bastnaesite,and isothermal kinetic analysis of bastnaesite pyrolysis and Ce oxidation was performed.The results revealed that bastnaesite decomposed rapidly and accompanied by Ce oxidation,and the gas-solid products were identified as CO_(2),Ce_(7)O_(12),La_(2)O_(3),CeF_(3) and LaF_(3),with Ce oxidation restricted by bastnaesite pyrolysis.As roasting time prolonged,cracks and pores appeared on bastnaesite surface;the BET specific surface and pore diameter increased.In later roasting period,the pore diameter continued to increase but the specific surface decreased,assigned to particle fusion agglomeration and pore consolidation.Additionally,the surface C content reduced and Ce(Ⅳ)content increased gradually as roasting progressed.The reaction kinetics all followed Avrami-Erofeev equations,the reaction orders of bastnaesite pyrolysis and Ce oxidation decreased with decreasing reaction temperature.The calculated activation energies at lower temperatures were higher than those calculated at higher temperatures.This study analyzed the bastnaesite reaction mechanism to supply a reference for the application of suspension roasting technology in bastnaesite smelting.
基金Project(24A0006)supported by the Key Project of Scientific Research Fund of Hunan Provincial Department of Education,ChinaProject(2024JJ5430)supported by the Natural Science Foundation of Hunan Province,ChinaProjects(2024JK2045,2023RC3061)supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘A high-speed train travelling from the open air into a narrow tunnel will cause the“sonic boom”at tunnel exit.When the maglev train’s speed reaches 600 km/h,the train-tunnel aerodynamic effect is intensified,so a new mitigation method is urgently expected to be explored.This study proposed a novel asymptotic linear method(ALM)for micro pressure wave(MPW)mitigation to achieve a constant gradient of initial c ompression waves(ICWs),via a study with various open ratios on hoods.The properties of ICWs and MPWs under various open ratios of hoods were analyzed.The results show that as the open ratio increases,the MPW amplitude at the tunnel exit initially decreases before rising.At the open ratio of 2.28%,the slope of the ICW curve is linearly coincident with a supposed straight line in the ALM,which further reduces the MPW amplitude by 26.9%at 20 m and 20.0%at 50 m from the exit,as compared to the unvented hood.Therefore,the proposed method effectively mitigates MPW and quickly determines the upper limit of alleviation for the MPW amplitude at a fixed train-tunnel operation condition.All achievements provide a ne w potential measure for the adaptive design of tunnel hoods.
基金Project(52022019)supported by the National Natural Science Foundation of China。
文摘The magnetization reduction of hematite using biomass waste can effectively utilize waste and reduce CO_(2) emission to achieve the goals of carbon peaking and carbon neutrality.The effects of temperatures on suspension magnetization roasting of hematite using biomass waste for evolved gases have been investigated using TG-FTIR,Py-GC/MS and gas composition analyzer.The mixture reduction process is divided into four stages.In the temperature range of 200-450℃ for mixture,the release of CO_(2),acids,and ketones is dominated in gases products.The yield and concentration of small molecules reducing gases increase when the temperature increases from 450 to 900℃.At 700℃,the volume concentrations of CO,H_(2) and CH_(4) peak at 8.91%,8.90% and 4.91%,respectively.During the suspension magnetization roasting process,an optimal iron concentrate with an iron grade of 70.86%,a recovery of 98.66% and a magnetic conversion of 45.70% is obtained at 700℃.Therefore,the magnetization reduction could react greatly in the temperature range of 600 to 700℃ owing to the suitable reducing gases.This study shows a detail gaseous evolution of roasting temperature and provides a new insight for studying the reduction process of hematite using biomass waste.
基金Project(2023YFB4302500)supported by the National Key R&D Program of ChinaProject(52078485)supported by the National Natural Science Foundation of ChinaProjects(2021-Major-16,2021-Special-08)supported by the Science and Technology Research and Development Program Project of China Railway Group Limited。
文摘Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can be well characterized based on various stochastic excitations.A three-dimensional refined spatial random vibration analysis model of high-speed maglev train-bridge coupled system is established in this paper,in which multi-source uncertainty excitation can be considered simultaneously,and the probability density evolution method(PDEM)is adopted to reveal the system-specific uncertainty dynamic characteristic.The motion equation of the maglev vehicle model is composed of multi-rigid bodies with a total 210-degrees of freedom for each vehicle,and a refined electromagnetic force-air gap model is used to account for the interaction and coupling effect between the moving train and track beam bridges,which are directly established by using finite element method.The model is proven to be applicable by comparing with Monte Carlo simulation.By applying the proposed stochastic framework to the high maglev line,the random dynamic responses of maglev vehicles running on the bridges are studied for running safety and stability assessment.Moreover,the effects of track irregularity wavelength range under different amplitude and running speeds on the coupled system are investigated.The results show that the augmentation of train speed will move backward the sensitive wavelength interval,and track irregularity amplitude influences the response remarkably in the sensitive interval.
基金Project(60404003)supported by the National Natural Science Foundation of China
文摘In order to explore the precise dynamic response of the maglev train and verify the validity of proposed controller,a maglev guideway-electromagnet-air spring-cabin coupled model is developed in the first step.Based on the coupled model,the stresses of the modules are analyzed,and it is pointed out that the inherent nonlinearity,the inner coupling,misalignments between the sensors and actuators,and external disturbances are the main issues that should be considered for the maglev engineering.Furthermore,a feedback linearization controller based on the mathematical model of a maglev module is derived,in which the nonlinearity,coupling and misalignments are taken into account.Then,to attenuate the effect of external disturbances,a disturbance observer is proposed and the dynamics of the estimation error is analyzed using the input-to-state stability theory.It shows that the error is negligible under a low-frequency disturbance.However,at the high-frequency range,the error is unacceptable and the disturbances can not be compensated in time,which lead to over designed fluctuations of levitation gap,even a clash between the upper surface of electromagnet and lower surface of guideway.To solve this problem,a novel nonlinear acceleration feedback is put forward to enhancing the attenuation ability of fast varying disturbances.Finally,numerical comparisons show that the proposed controller outperforms the traditional feedback linearization controller and maintains good robustness under disturbances.
基金Project(50425168)supported by the National Natural Science Foundation of ChinaProject (0100471413)supported by China Postdoctoral Science FoundationProject (201104547)supported by Pisdoctorcal Science Foundation of Jiangsu Province,China
文摘Coal slimes are mainly composed of coal and clay particles.The interaction energies among these particles were calculated using extended DLVO(DERJAGUIN-LANDAU-VERWEY-OVERBEEK)theory and the aggregation mechanisms were analyzed based on the settling experiments for coal-kaolinite and coal-montmorillonite suspensions,respectively,under different conditions of water hardness.The results indicate that for coal-kaolinite suspensions,as the water hardness reaches 10.0mol/L,the coal particles aggregate with each other easily,and then,the coal particles may aggregate with kaolinite particles.However,no aggregation occurs between kaolinite particles.A clay platelet network is formed in coal-montmorillonite suspensions by montmorillonite particles and coal particles are captured into the network.Coal and montmorillonite particles settle completely.
基金Projects(51874071,51734005,52104257)supported by the National Natural Science Foundation of ChinaProject(161045)supported by the Fok Ying Tung Education Foundation for Yong Teachers in the Higher Education Institutions of China。
文摘Oolitic hematite is an iron ore resource with rich reserves,complex composition,low grade,fine disseminated particle sizes,and a unique oolitic structure.In this study,a microwave-assisted suspension magnetization roasting technology was proposed to recover and utilize the ore.The results showed that under the conditions of microwave pretreatment temperature of 1050℃ for 2 min,a magnetic concentrate with an iron grade of 58.72%at a recovery of 89.32%was obtained by microwave suspension magnetization roasting and magnetic separation.Moreover,compared with the no microwave pretreatment case,the iron grade and recovery increased by 3.17%and 1.58%,respectively.Microwave pretreatment increased the saturation magnetization of the roasted products from 24.974 to 39.236(A∙m^(2))/kg and the saturation susceptibility from 0.179×10^(−3) m^(3)/kg to 0.283×10^(−3) m^(3)/kg.Microcracks were formed between the iron and gangue minerals,and they gradually extended to the core of oolite with the increase in the pretreatment time.The reducing gas diffused from outside to inside along the microcracks,which promoted the selective transformation of the weak magnetic hematite into the strong magnetic magnetite.
文摘The rheological behavior of fumed silica suspensions in polyethylene glycol(PEG) was studied at steady and oscillatory shear stress using AR 2000 stress controlled rheometer. The systems show reversible shear thickening behavior and the shear-thickening behavior can be explained by the clustering mechanism. The viscosity and the degree of shear-thickening of the systems strongly depend on the mass fraction of the silica, the molecular weigh of PEG and the frequency used in the rheological measurement. The silica volume fraction of the systems is 1.16% 3.62%, corresponding to the mass fraction of 4%9%. The shear-thickening taking place in the low volume fraction may contribute to the fractal nature of the silica. At oscillatory shear stress, when the shear stress is less than the critical stress, the storage modulus decreases significantly, meanwhile the loss modulus and the complex viscosity almost remain unchanged; when the shear stress is larger than the critical stress, the storage modulus, the loss modulus and the complex viscosity increase with the increase of shear stress. The loss modulus is larger than the storage modulus in the range of stress studied and both moduli depend on frequency.
基金Projects(51874071,52022019,51734005)supported by the National Natural Science Foundation of ChinaProject(161045)supported by the Fok Ying Tung Education Foundation for Yong Teachers in the Higher Education Institutions of China。
文摘Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.
基金Projects(50735007,51005253) supported by the National Natural Science Foundation of ChinaProject(2007AA04Z344) supported by the National High-Tech Research and Development Program of China
文摘A novel maglev transportation system was proposed for large travel range ultra precision motion.The system consists of a levitation subsystem and a propulsion subsystem.During the propulsion subsystem driving the moving platform along the guideway,the levitation subsystem uses six pairs of electromagnets to steadily suspend the moving platform over the guideway.The model of the levitation system,which is a typical nonlinear multi-input multi-output coupling system and has many inner nonlinear coupling characteristics,was deduced.For testifying the model,the levitation mechanism was firstly controlled by proportional-integral-differential(PID) control,and then a lot of input-output data were collected for model parameter identification.The least-square parameter identification method was used.The identification results prove that the model is feasible and suitable for the real system.
文摘Several methods for evaluating the sublayer suspension beneath old pavement with falling weight deflectormeter(FWD), were summarized and the respective advantages and disadvantages were analyzed. Based on these methods, the evaluation principles were improved and a new type of the neural network, functional-link neural network was proposed to evaluate the sublayer suspension with FWD test results. The concept of function link, learning method of functional-link neural network and the establishment process of neural network model were studied in detail. Based on the old pavement over-repairing engineering of Kaiping section, Guangdong Province in G325 National Highway, the application of functional-link neural network in evaluation of sublayer suspension beneath old pavement based on FWD test data on the spot was investigated. When learning rate is 0.1 and training cycles are 405, the functional-link network error is less than 0.000 1, while the optimum chosen 4-8-1 BP needs over 10 000 training cycles to reach the same accuracy with less precise evaluation results. Therefore, in contrast to common BP neural network,the functional-link neural network adopts single layer structure to learn and calculate, which simplifies the network, accelerates the convergence speed and improves the accuracy. Moreover the trained functional-link neural network can be (adopted) to directly evaluate the sublayer suspension based on FWD test data on the site. Engineering practice indicates that the functional-link neural model gains very excellent results and effectively guides the pavement over-repairing construction.
基金Projects(11302252,11202230)supported by the National Natural Science Foundation of China
文摘This work addresses the saturation influence of control voltage on the occurring of self-excited vibration of maglev vehicle-bridge interaction system, which greatly degrades the stability of the levitation control, decreases the ride comfort, and restricts the cost of the whole system. Firstly, the interaction model of vehicle-bridge system is developed. Based on the interaction model, the relationship between the control voltage and vibration frequency is solved. Then, the variation of the effective direct component and fundamental harmonic are discussed. Furthermore, from the perspective of energy transmission between the levitation system and bridge, the principle underlying the self-excited vibration is explored, and the influence on the stability is discussed. Finally, in terms of the variation of the characteristic roots, the influence is analyzed further and some conclusions are obtained. This study provides a theoretical guidance for mastering the self-excited vibration problems.
