Poly (methyl methacrylate) (PMMA) brushes were synthesized from silicon wafers via surface initiated atom transfer radical polymerization (SI-ATRP). Energy disperse spectroscopy (EDS) and atomic force microsco...Poly (methyl methacrylate) (PMMA) brushes were synthesized from silicon wafers via surface initiated atom transfer radical polymerization (SI-ATRP). Energy disperse spectroscopy (EDS) and atomic force microscopy (AFM) confirmed that PMMA brushes were successfully prepared on the silicon wafers, and the surface became more hydrophobic according to the contact angle of 69~. It is found that CuCI/1, 1, 4, 7, 10, 10-hexamethyl triethylenetetramine (HMTETA) system is more suitable than CuBr/N, N, N′, N″, N′″-pentamethyl diethylenetriamine (PMDETA) system to control the free radical polymerization of MMA in solution. Nevertheless, better control on the thickness of PMMA brushes was achieved in CuBr/PMDETA than in CuC1/HMTETA due to higher activity and better reversibility of the former system.展开更多
Research on dual-fuel(DF)engines has become increasingly important as engine manufacturers seek to reduce carbon dioxide emissions.There are significant advantages of using diesel pilot-ignited natural gas engines as ...Research on dual-fuel(DF)engines has become increasingly important as engine manufacturers seek to reduce carbon dioxide emissions.There are significant advantages of using diesel pilot-ignited natural gas engines as DF engines.However,different combustion modes exist due to variations in the formation of the mixture.This research used a simulation model and numerical simulations to explore the combustion characteristics of high-pressure direct injection(HPDI),partially premixed compression ignition(PPCI),and double pilot injection premixed compression ignition(DPPCI)combustion modes under a low-medium load.The results revealed that the DPPCI combustion mode provides higher gross indicated thermal efficiency and more acceptable total hydrocarbon(THC)emission levels than the other modes.Due to its relatively good performance,an experimental study was conducted on the DPPCI mode engine to evaluate the impact of the diesel dual-injection strategy on the combustion process.In the DPPCI mode,a delay in the second pilot ignition injection time increased THC emissions(a maximum value of 4.27g/(kW·h)),decreased the emission of nitrogen oxides(a maximum value of 7.64 g/(kW·h)),increased and then subsequently decreased the gross indicated thermal efficiency values,which reached 50.4%under low-medium loads.展开更多
The cooling process of cooling water is veryimportant in power generation industry.The performanceof cooling towers has a great effect on security,stabilityand economy of power plants.The energy savingproblems of the ...The cooling process of cooling water is veryimportant in power generation industry.The performanceof cooling towers has a great effect on security,stabilityand economy of power plants.The energy savingproblems of the cooling tower have always beenneglected previously.With the aim of energy saving inthe power plants nowadays,improving the coolingefficiency of the cooling tower has important andpractical significance.展开更多
基金Project(21376271)supported by the National Natural Science Foundation of ChinaProject(2013)supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars,China+2 种基金Projects(CL12129,201310533008)supported by the Undergraduates Innovative Training Foundation of Central South University,ChinaProject(Z12060)supported by the Undergraduate Free Exploration Innovation Foundation of Central South University,ChinaProject(CSUZC2013008)supported by the Open-End Fund for the Valuable and Precision Instruments of Central South University,China
文摘Poly (methyl methacrylate) (PMMA) brushes were synthesized from silicon wafers via surface initiated atom transfer radical polymerization (SI-ATRP). Energy disperse spectroscopy (EDS) and atomic force microscopy (AFM) confirmed that PMMA brushes were successfully prepared on the silicon wafers, and the surface became more hydrophobic according to the contact angle of 69~. It is found that CuCI/1, 1, 4, 7, 10, 10-hexamethyl triethylenetetramine (HMTETA) system is more suitable than CuBr/N, N, N′, N″, N′″-pentamethyl diethylenetriamine (PMDETA) system to control the free radical polymerization of MMA in solution. Nevertheless, better control on the thickness of PMMA brushes was achieved in CuBr/PMDETA than in CuC1/HMTETA due to higher activity and better reversibility of the former system.
基金Project(2017YFE0102800)supported by the National Key R&D Program of ChinaProject(19JCYBJC21200)supported by the Tianjin Natural Science Foundation,China。
文摘Research on dual-fuel(DF)engines has become increasingly important as engine manufacturers seek to reduce carbon dioxide emissions.There are significant advantages of using diesel pilot-ignited natural gas engines as DF engines.However,different combustion modes exist due to variations in the formation of the mixture.This research used a simulation model and numerical simulations to explore the combustion characteristics of high-pressure direct injection(HPDI),partially premixed compression ignition(PPCI),and double pilot injection premixed compression ignition(DPPCI)combustion modes under a low-medium load.The results revealed that the DPPCI combustion mode provides higher gross indicated thermal efficiency and more acceptable total hydrocarbon(THC)emission levels than the other modes.Due to its relatively good performance,an experimental study was conducted on the DPPCI mode engine to evaluate the impact of the diesel dual-injection strategy on the combustion process.In the DPPCI mode,a delay in the second pilot ignition injection time increased THC emissions(a maximum value of 4.27g/(kW·h)),decreased the emission of nitrogen oxides(a maximum value of 7.64 g/(kW·h)),increased and then subsequently decreased the gross indicated thermal efficiency values,which reached 50.4%under low-medium loads.
文摘The cooling process of cooling water is veryimportant in power generation industry.The performanceof cooling towers has a great effect on security,stabilityand economy of power plants.The energy savingproblems of the cooling tower have always beenneglected previously.With the aim of energy saving inthe power plants nowadays,improving the coolingefficiency of the cooling tower has important andpractical significance.