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Polycrystalline ZSM-5 Aggregates Induced by Seed and Catalytic Performance in Methanol to Hydrocarbon
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作者 WANG Xuchang JIAO Chuyu +5 位作者 JI Zhuo JIAO Qirui QIN Bo DU Yanze ZHENG Jiajun LI Ruifeng 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2024年第8期945-954,I0010-I0013,共14页
Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use ... Synthesis of ZSM-5 zeolite typically utilizes small molecule polyamines or quaternary ammonium salts as organic structure guiding agent(OSDA).By contrast,the OSDA-free hydrothermal synthesis system eliminates the use of organic templates and the subsequent calcination procedure.This not only reduces the cost of synthesis,but also prevents environmental pollution from the combustion of organic templates,representing an eco-friendly approach.Despite this,literature suggests that even so-called template-free synthesis systems often involve trace amount of organic substances like alcohol.In the present work,a calcined commercial ZSM-5 zeolite was served as seed,with sodium aluminate as aluminum source and silica sol as silicon source,ensuring an entirely template-free synthesis system.Polycrystalline ZSM-5 aggregates consisted of rod-like nanocrystals were successfully prepared in the completely OSDA-free system.Effects of the Si/Al ratio in ZSM-5 seed,dosage and crystallization conditions such as crystallization temperature and crystallization time on ZSM-5 synthesis were investigated.The results show that a highly crystallinity ZSM-5 aggregate consisting of primary nano-sized crystals less than 100 nm is produced from a gel precursor with 5.6%(in mass)seed after hydrothermal treatment for 48 h.Furthermore,the Si/Al ratio in ZSM-5 seed has little effect on the topological structure and pore structure of the synthesized samples.However,the seeds with a low Si/Al ratio facilitate faster crystallization of zeolite and enhance the acidity,especially the strong acid centers,of the catalyst.The catalytic performance of the synthesized polycrystalline ZSM-5 was evaluated during dehydration of methanol and compared with a commercial reference ZSM-5r.The results exhibit that as compared with the reference catalyst,the fabricated sample has a longer catalytic lifetime(16 h vs 8 h)attributed to its hierarchical pores derived from the loosely packed primary nanoparticles.Additionally,the prepared polycrystalline catalyst also exhibits a higher aromatics selectivity(28.1%-29.8%vs 26.5%). 展开更多
关键词 ZSM-5 polycrystalline aggregate crystal seed structure guiding agent
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Numerical investigation on the aerodynamic drag reduction based on bottom deflectors and streamlined bogies of a high-speed train
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作者 JIANG Chen LONG jn-lan +2 位作者 LI Yan-ong GAO Guang-jun FRANKLIN Eze 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第9期3312-3328,共17页
The complex structure of the bottom of a high-speed train is an important source of train aerodynamic drag.Thus,improving the bottom structure is of great significance to reduce the aerodynamic drag of the train.In th... The complex structure of the bottom of a high-speed train is an important source of train aerodynamic drag.Thus,improving the bottom structure is of great significance to reduce the aerodynamic drag of the train.In this study,computational fluid dynamics(CFD)based on three-dimensional steady incompressible Reynolds-average Naiver-Stokes(RANS)equations and Realizable k-εturbulence model were utilized for numerical simulations.Inspired by the concept of streamlined design and the idea of bottom flow field control,this study iteratively designed the bogies in a streamlined shape and combined them with the bottom deflectors to investigate the joint drag reduction mechanism.Three models,i.e.,single-bogie model,simplified train model,and eight-car high-speed train model,were created and their aerodynamic characteristics were analyzed.The results show that the single-bogie model with streamlined design shows a noticeable drag reduction,whose power bogie and trailer bogie experience 13.92%and 7.63%drag reduction,respectively.The range of positive pressure area on the bogie is reduced.The aerodynamic drag can be further reduced to 15.01%by installing both the streamlined bogie and the deflector on the simplified train model.When the streamlined bogies and deflectors are used on the eight-car model together,the total drag reduction rate reaches 2.90%.Therefore,the proposed aerodynamic kit for the high-speed train bottom is capable to improve the flow structure around the bogie regions,reduce the bottom flow velocity,and narrow the scope of the train’s influence on the surrounding environment,achieving the appreciable reduction of aerodynamic drag.This paper can provide a new idea for the drag reduction of high-speed trains. 展开更多
关键词 high-speed train numerical simulation drag reduction DEFLECTOR streamlined design
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Characteristic analysis of 1.06μm long-cavity diode lasers based on asymmetric waveguide structures
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作者 ZHAO Ren-Ze GAO Xin +3 位作者 FU Ding-Yang ZHANG Yue SU Peng BO Bao-Xue 《红外与毫米波学报》 SCIE EI CAS CSCD 北大核心 2024年第4期557-562,共6页
In long-cavity edge-emitting diode lasers,longitudinal spatial hole burning(LSHB),two-photon ab⁃sorption(TPA)and free carrier absorption(FCA)are among the key factors that affect the linear increase in out⁃put power a... In long-cavity edge-emitting diode lasers,longitudinal spatial hole burning(LSHB),two-photon ab⁃sorption(TPA)and free carrier absorption(FCA)are among the key factors that affect the linear increase in out⁃put power at high injection currents.In this paper,a simplified numerical analysis model is proposed for 1.06μm long-cavity diode lasers by combining TPA and FCA losses with one-dimensional(1D)rate equations.The ef⁃fects of LSHB,TPA and FCA on the output characteristics are systematically analyzed,and it is proposed that ad⁃justing the front facet reflectivity and the position of the quantum well(QW)in the waveguide layer can improve the front facet output power. 展开更多
关键词 diode lasers longitudinal spatial hole burning free carrier absorption two-photon absorption
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Formation of mesophase microbeads from bulk mesophase pitch induced by fullerene
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作者 CHEN Wen-sheng LIU Lan-tao +5 位作者 WANG Zheng DUAN Chun-feng ZHANG Xing-wei MA Zhao-kun CHEN Xiao-hong SONG Huai-he 《新型炭材料(中英文)》 SCIE EI CAS CSCD 北大核心 2024年第4期645-654,共10页
A transformation of naphthalene-based coalescenced mesophase pitch(NMP)to mesophase microbeads was achieved by heating a mixture of NMP and fullerene(C_(60)).This is different from the conventional process of the liqu... A transformation of naphthalene-based coalescenced mesophase pitch(NMP)to mesophase microbeads was achieved by heating a mixture of NMP and fullerene(C_(60)).This is different from the conventional process of the liquid-phase carbonization of isotropic pitch to the emergence of carbon microbeads in the matrix and finally their growth to form a 100%anisotropic bulk meso-phase,but rather a reverse transformation.The effects of C_(60) loading and reaction temperature on the morphological transformation of mesophase were investigated by polarizing optical and scanning electron microscopies.The physical changes in the NMP induced by C_(60) were characterized by thermogravimetric analysis,Fourier transform infrared spectroscopy,X-ray diffractometry and Raman spectroscopy.The results show that the coalesced NMP can be converted to a spherical type at 300-320℃ with the addition of 5%C_(60),and the size of the mesophase microbeads increases with increasing temperature.Furthermore,a model is established to ex-plain the unique induction effect of C_(60) in the transformation process.This work makes the morphological transformation of MP con-trollable,and provides a new idea for the understanding and research of mesophase pitch. 展开更多
关键词 Reversible transformation Fullerene induction mechanism Mesophase texture π-electron-induced effect Mesophase microbeads
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CRISPR/Cas9的应用及脱靶效应研究进展 被引量:46
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作者 郑武 谷峰 《遗传》 CAS CSCD 北大核心 2015年第10期1003-1010,共8页
CRISPR/Cas9基因编辑技术在生命科学领域掀起了一场全新的技术革命,该技术可以对基因组特定位点进行靶向编辑,包括缺失、插入、修复等。CRISPR/Cas9比锌指核酸酶(ZFNs)和转录激活因子样效应物核酸酶(TALENs)技术更易于操作,而且更高效。... CRISPR/Cas9基因编辑技术在生命科学领域掀起了一场全新的技术革命,该技术可以对基因组特定位点进行靶向编辑,包括缺失、插入、修复等。CRISPR/Cas9比锌指核酸酶(ZFNs)和转录激活因子样效应物核酸酶(TALENs)技术更易于操作,而且更高效。CRISPR/Cas9系统中的向导RNA(Single guide RNA,sg RNA)是一段与目标DNA片段匹配的RNA序列,指导Cas9蛋白对基因组进行识别。研究发现,设计的sg RNA会与非靶点DNA序列错配,引入非预期的基因突变,即脱靶效应(Off-target effects)。脱靶效应严重制约了CRISPR/Cas9基因编辑技术的广泛应用。为了避免脱靶效应,研究者对影响脱靶效应的因素进行了系统研究并提出了许多降低脱靶效应的方法。文章总结了CRISPR/Cas9系统的应用及脱靶效应研究进展,以期为相关领域的工作提供参考。 展开更多
关键词 基因组编辑 CRISPR/Cas9 脱靶效应 RNA
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《荒原》:感情的逃避与寄寓 被引量:1
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作者 卢敏 朱伊革 《华中师范大学学报(人文社会科学版)》 CSSCI 1998年第S2期80-82,共3页
《荒原》问世已有四分之三个世纪了,其复杂的象征性语言、博学的隐喻的运用和晦涩然而娴熟的文字形式已被人们研究、破译、解读得愈见清晰、明朗。但对大多数后来学子而言,《荒原》依然是充满诱惑和恐怖之地。究其根源,最大的障碍乃... 《荒原》问世已有四分之三个世纪了,其复杂的象征性语言、博学的隐喻的运用和晦涩然而娴熟的文字形式已被人们研究、破译、解读得愈见清晰、明朗。但对大多数后来学子而言,《荒原》依然是充满诱惑和恐怖之地。究其根源,最大的障碍乃是难以把握诗人本人的情感态度,继而... 展开更多
关键词 《荒原》 艾略特 “客观对应物” “荒原” 情绪体验 情感态度 《坎特伯雷故事集》 “向导” 艺术形式 泰晤士河
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Modeling of photolithography process in semiconductor wafer fabrication systems using extended hybrid Petri nets 被引量:2
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作者 周炳海 潘青枝 +1 位作者 王世进 吴斌 《Journal of Central South University of Technology》 EI 2007年第3期393-398,共6页
To describe a semiconductor wafer fabrication flow availably, a new modeling method of extended hybrid Petri nets (EHPNs) was proposed. To model the discrete part and continuous part of a complex photolithography pr... To describe a semiconductor wafer fabrication flow availably, a new modeling method of extended hybrid Petri nets (EHPNs) was proposed. To model the discrete part and continuous part of a complex photolithography process, hybrid Petri nets (HPNs) were introduced. To cope with the complexity of a photolithography process, object-oriented methods such as encapsulation and classifications were integrated with HPN models. EHPN definitions were presented on the basis of HPN models and object-oriented methods. Object-oriented hybrid Petri subnet models were developed for each typical physical object and an EHPN modeling procedure steps were structured. To demonstrate the feasibility and validity of the proposed modeling method, a real wafer photolithography case was used to illustrate the modeling procedure. dynamic modeling of a complex photolithography process effectively The modeling results indicate that the EHPNs can deal with the dynamic modeling of a complex photolithography process effectively. 展开更多
关键词 semiconductor wafer fabrication photolithography process hybrid Petri net object-oriented method
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Real-time operation guide system for sintering process with artificial intelligence
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作者 范晓慧 陈许玲 +1 位作者 姜涛 李桃 《Journal of Central South University of Technology》 EI 2005年第5期531-535,共5页
In order to optimize the sintering process, a real-time operation guide system with artificial intelligence was developed, mainly including the data acquisition online subsystem, the sinter chemical composition contro... In order to optimize the sintering process, a real-time operation guide system with artificial intelligence was developed, mainly including the data acquisition online subsystem, the sinter chemical composition controller, the sintering process state controller, and the abnormal conditions diagnosis subsystem. Knowledge base of the sintering process controlling was constructed, and inference engine of the system was established. Sinter chemical compositions were controlled by the strategies of self-adaptive prediction, internal optimization and center on basicity. And the state of sintering was stabilized centering on permeability. In order to meet the needs of process change and make the system clear, the system has learning ability and explanation function. The software of the system was developed in Visual C++ programming language. The application of the system shows that the hitting accuracy of sinter compositions and burning through point prediction are more than 85%; the first-grade rate of sinter chemical composition, stability rate of burning through point and stability rate of sintering process are increased by 3%, 9% and 4%, respectively. 展开更多
关键词 sintering process process control artificial intelligence
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Laser-induced forward transferred silver nanomembrane with controllable light absorption
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作者 LI Ruo-zhou GUO Lyu-jiu +2 位作者 YANG Ming-qing QU Ke YAN Jing 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第10期3399-3409,共11页
Laser processing provides highly-controlled modification and on-demand fabrication of plasmon metal nanostructures for light absorption and photothermal convention.We present the laser-induced forward tansfer(LIFT)fab... Laser processing provides highly-controlled modification and on-demand fabrication of plasmon metal nanostructures for light absorption and photothermal convention.We present the laser-induced forward tansfer(LIFT)fabrication of silver nanomembranes in control of light absorption.By varying the hatch distance,different morphologies of randomly distributed plasmon silver nanostructures were produced,leading to well-controlled light absorption levels from 11%to 81%over broadband.The anti-reflection features were maintained below 17%.Equilibrated and plain absorptions were obtained throughout all absorption levels with a maximum intensity fluctuation of±8.5%for the 225μJ cases.The 45μJ pulse energy can offer a highly equilibrated absorption at a 60%absorption level with an intensity fluctuation of±1%.Pattern transfer was also achieved on a thin tape surface.The laser-transferred characters and patterns demonstrate a localized temperature rise.A rapid temperature rising of roughly 15℃can be achieved within 1 s.The LIFT process is highly efficiently fabricated with a typical speed value of 10^(3)to 10^(5)cm^(2)/h.The results indicated that LIFT is a well-controlled and efficient method for the production of optical films with specific absorption levels. 展开更多
关键词 laser-induced forward transfer silver nanomembrane controllable light absorption laser printing
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Automated pattern-directed refactoring for complex conditional statements
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作者 刘伟 胡志刚 +1 位作者 刘宏韬 杨柳 《Journal of Central South University》 SCIE EI CAS 2014年第5期1935-1945,共11页
Complex conditional statement is one of the bad code smells, which affects the quality of the code and design of software. In the proposed approach, two commonly-used design patterns for handling complex conditional s... Complex conditional statement is one of the bad code smells, which affects the quality of the code and design of software. In the proposed approach, two commonly-used design patterns for handling complex conditional statements are selected, and they are the factory method pattern and the strategy pattem. Two pattern-directed refactoring approaches based on the two design patterns are proposed. Each approach contains a refactoring opportunities identification algorithm and an automated refactoring algorithm. After parsing the abstract syntax tree generated from source code, the refactoring opportunities are identified effectively and automatically. Then, for candidate code, refactoring algorithms are executed automatically, which are used to simplify or remove complex conditional statements. By empirical analysis and quality assessment, the code after refactoring has better maintainability and extensibility, and the proposed approach for automated pattern-directed refactoring succeeds to reduce code size and complexity of classes. 展开更多
关键词 REFACTORING abstract syntax tree complex conditional statements design patterns factory method pattem strategypattem
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Electrical conductivity effect on MHD mixed convection of nanofluid flow over a backward-facing step 被引量:4
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作者 SELIMEFENDIGIL Fatih OCAN CBAN Seda OTOP Hakan F. 《Journal of Central South University》 SCIE EI CAS CSCD 2019年第5期1133-1145,共13页
In this study,magneto-hydrodynamics (MHD) mixed convection effects of Al2O3-water nanofluid flow over a backward-facing step were investigated numerically for various electrical conductivity models of nanofluids.A uni... In this study,magneto-hydrodynamics (MHD) mixed convection effects of Al2O3-water nanofluid flow over a backward-facing step were investigated numerically for various electrical conductivity models of nanofluids.A uniform external magnetic field was applied to the flow and strength of magnetic field was varied with different values of dimensionless parameter Hartmann number (Ha=0,10,20,30,40).Three different electrical conductivity models were used to see the effects of MHD nanofluid flow.Besides,five different inclination angles between 0°-90° is used for the external magnetic field.The problem geometry is a backward-facing step which is used in many engineering applications where flow separation and reattachment phenomenon occurs.Mixed type convective heat transfer of backward-facing step was examined with various values of Richardson number (Ri=0.01,0.1,1,10) and four different nanoparticle volume fractions (Ф=0.01,0.015,0.020,0.025) considering different electrical conductivity models.Finite element method via commercial code COMSOL was used for computations.Results indicate that the addition of nanoparticles enhanced heat transfer significantly.Also increasing magnetic field strength and inclination angle increased heat transfer rate.Effects of different electrical conductivity models were also investigated and it was observed that they have significant effects on the fluid flow and heat transfer characteristics in the presence of magnetic field. 展开更多
关键词 electrical conductivity nanofluids backward-facing step MHD flow mixed convection
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Recognition algorithm for turn light of front vehicle
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作者 李仪 蔡自兴 唐琎 《Journal of Central South University》 SCIE EI CAS 2012年第2期522-526,共5页
Intelligent vehicle needs the turn light information of front vehicles to make decisions in autonomous navigation. A recognition algorithm was designed to get information of turn light. Approximated center segmentatio... Intelligent vehicle needs the turn light information of front vehicles to make decisions in autonomous navigation. A recognition algorithm was designed to get information of turn light. Approximated center segmentation method was designed to divide the front vehicle image into two parts by using geometry information. The number of remained pixels of vehicle image which was filtered by the morphologic feaatres was got by adaptive threshold method, and it was applied to recognizing the lights flashing. The experimental results show that the algorithm can not only distinguish the two turn lights of vehicle but also recognize the information of them. The algorithm is quiet effective, robust and satisfactory in real-time performance. 展开更多
关键词 intelligent vehicle turn light recognition adaptive threshold front vehicle
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Wavelength dependent loss of splice of single-mode fibers 被引量:1
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作者 YANG Bo DUAN Ji-an +1 位作者 XIE Zheng XIAO Hong-feng 《Journal of Central South University》 SCIE EI CAS 2013年第7期1832-1837,共6页
After reviewing three different definitions of mode field diameter of single-mode fibers, coupled efficiency calculation methods associated with lateral offset, longitude separation and wavelength, the effects produce... After reviewing three different definitions of mode field diameter of single-mode fibers, coupled efficiency calculation methods associated with lateral offset, longitude separation and wavelength, the effects produced by them, and the influences of splicing defects were discussed in detail. The regularities of the effects were studied according to the first order derivation of couple efficiency formula, and a simplified formula for couple efficiency calculation was presented under the circumstance of slight misalignment, with respect to wavelength, 2, and in a good agreement with the theoretical model. The simplified formula provides a new but simple approach to evaluate wavelength dependent couple efficiency of single-mode fibers. Theoretical analyses and numerical calculations show that, when those defects exist, the wavelength produces additional effects on the couple loss that growth of wavelength causes an increase on the couple efficiency for the lateral offset or longitude separation whereas lessens the couple efficiency due to angular misalignment or mode fields mismatching, and that the wavelength degrades the couple efficiency distinctly when λ≥2.5 μm whereas it distorts the couple slightly in range of λ≤2λ≤2 μm. 展开更多
关键词 wavelength dependent loss couple efficiency single-mode fiber cut-offwavelength
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Magneli phase titanium sub-oxide conductive ceramic Ti_nO_(2n-1) as support for electrocatalyst toward oxygen reduction reaction with high activity and stability 被引量:3
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作者 伍秋美 阮建明 +1 位作者 周忠诚 桑商斌 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第4期1212-1219,共8页
Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-... Magneli phase titanium sub-oxide conductive ceramic Tin O2n-1 was used as the support for Pt due to its excellent resistance to electrochemical oxidation, and Pt/Tin O2n-1 composites were prepared by the impregnation-reduction method. The electrochemical stability of Tin O2n-1 was investigated and the results show almost no change in the redox region after oxidation for 20 h at 1.2 V(vs NHE) in 0.5 mol/L H2SO4 aqueous solution. The catalytic activity and stability of the Pt/Tin O2n-1 toward the oxygen reduction reaction(ORR) in 0.5 mol/L H2SO4 solution were investigated through the accelerated aging tests(AAT), and the morphology of the catalysts before and after the AAT was observed by transmission electron microscopy. At the potential of 0.55 V(vs SCE), the specific kinetic current density of the ORR on the Pt/Tin O2n-1 is about 1.5 times that of the Pt/C. The LSV curves for the Pt/C shift negatively obviously with the half-wave potential shifting about 0.02 V after 8000 cycles AAT, while no obvious change takes place for the LSV curves for the Pt/Tin O2n-1. The Pt particles supported on the carbon aggregate obviously, while the morphology of the Pt supported on Tin O2n-1 remains almost unchanged, which contributes to the electrochemical surface area loss of Pt/C being about 2times that of the Pt/Tin O2n-1. The superior catalytic stability of Pt/Tin O2n-1 toward the ORR could be attributed to the excellent stability of the Tin O2n-1 and the electronic interaction between the metals and the support. 展开更多
关键词 magneli phase TinO2n-1 support oxygen reduction reaction stability
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Effects of lateral translation on aerodynamic characteristics of superconducting maglev trains
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作者 ZHANG Lei PAN Shen-gong +5 位作者 LIN Tong-tong YU Qing-song WANG Tian-tian YANG Ming-zhi LIU Dong-run XU Shu 《Journal of Central South University》 2025年第8期3150-3172,共23页
Irregularities in the track and uneven forces acting on the train can cause shifts in the position of the superconducting magnetic levitation train relative to the track during operation.These shifts lead to asymmetri... Irregularities in the track and uneven forces acting on the train can cause shifts in the position of the superconducting magnetic levitation train relative to the track during operation.These shifts lead to asymmetries in the flow field structure on both sides of the narrow suspension gap,resulting in instability and deterioration of the train’s aerodynamic characteristics,significantly impacting its operational safety.In this study,we firstly validate the aerodynamic characteristics of the superconducting magnetic levitation system by developing a numerical simulation method based on wind tunnel test results.We then investigate the influence of lateral translation parameters on the train’s aerodynamic performance under conditions both with and without crosswinds.We aim to clarify the evolution mechanism of the flow field characteristics under the coupling effect between the train and the U-shaped track and to identify the most unfavorable operational parameters contributing to the deterioration of the train’s aerodynamic properties.The findings show that,without crosswinds,a lateral translation of 30 mm causes a synchronous resonance phenomenon at the side and bottom gaps of the train-track coupling,leading to the worst aerodynamic performance.Under crosswind conditions,a lateral translation of 40 mm maximizes peak pressure fluctuations and average turbulent kinetic energy around the train,resulting in the poorest aerodynamic performance.This research provides theoretical support for enhancing the operational stability of superconducting magnetic levitation trains. 展开更多
关键词 superconducting magnetic trains lateral translation aerodynamic characteristics crosswind operation flow coupling
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