Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigate...Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.展开更多
The electromagnetic emission(EME) induced from the rock containing piezoelectric materials was investigated under both static stress and exploding stress wave in the view of piezoelectric effect. The results show that...The electromagnetic emission(EME) induced from the rock containing piezoelectric materials was investigated under both static stress and exploding stress wave in the view of piezoelectric effect. The results show that the intensity of the EME induced from the rock under static stress increases with increasing stress level and loading rate; the relationship between the amplitude of the EME from the rock under different modes of stress wave and elastic parameters and propagation distance was presented. The intensity of the EME relates not only to the strength and elastic moduli of rock masses,but also to the initial damage of the rock. The intensity of EME induced by stress wave reaches the highest at the explosion-center and attenuates with the propagation distance. The intensity of EME increases with increasing the elastic modulus and decreases with increasing initial damage. The results are in good agreement with the experimental results.展开更多
This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differenti...This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differential system is re-structured into the ordinary differential expressions by the implication of appropriate transformations.The developed differential equations are computed by homotopy analysis technique.Numerical consequences have been accomplished by various values of emerging parameters.Coefficients of skin friction and heat and mass transfer rates have been scrutinized.Irreversibility analysis is carried out.Influence of various prominent variables on entropy generation is presented.Moreover,the temperature increases for higher Dufour number and concentration distribution reduces against Soret number.Higher squeezing parameter enhances velocity while concentration reduces with an increment in squeezing parameter.Both entropy rate and Bejan number increase against higher diffusion parameter.展开更多
基金Projects(51874071,52022019,51734005)supported by the National Natural Science Foundation of ChinaProject(161045)supported by the Fok Ying Tung Education Foundation for Yong Teachers in the Higher Education Institutions of China。
文摘Siderite,as an abundant iron ore,has not been effectively utilized,with a low utilization rate.In this study,the in-situ kinetics and mechanism of siderite during suspension magnetization roasting(SMR)were investigated to improve the selective conversion of siderite to magnetite and CO,enriching the theoretical system of green SMR using siderite as a reductant.According to the gas products analyses,the peak value of the reaction rate increased with increasing temperature,and its curves presented the feature of an early peak and long tail.The mechanism function of the siderite pyrolysis was the contraction sphere model(R_(3)):f(α)=3(1−α)2/3;E_(α)was 46.4653 kJ/mol;A was 0.5938 s^(−1);the kinetics equation was k=0.5938exp[−46.4653/(RT)].The in-situ HT-XRD results indicated that siderite was converted into magnetite and wüstite that exhibited a good crystallinity in SMR under a N_(2) atmosphere.At 620℃,the saturation magnetization(M_(s)),remanence magnetization(Mr),and coercivity(Hc)of the product peaked at 53.63×10^(-3)A·m^(2)/g,10.23×10^(-3)A·m^(2)/g,and 12.40×10^(3)A/m,respectively.Meanwhile,the initial particles with a smooth surface were transformed into particles with a porous and loose structure in the roasting process,which would contribute to reducing the grinding cost.
基金Project(50490274) supported by National Natural Science Foundation of China
文摘The electromagnetic emission(EME) induced from the rock containing piezoelectric materials was investigated under both static stress and exploding stress wave in the view of piezoelectric effect. The results show that the intensity of the EME induced from the rock under static stress increases with increasing stress level and loading rate; the relationship between the amplitude of the EME from the rock under different modes of stress wave and elastic parameters and propagation distance was presented. The intensity of the EME relates not only to the strength and elastic moduli of rock masses,but also to the initial damage of the rock. The intensity of EME induced by stress wave reaches the highest at the explosion-center and attenuates with the propagation distance. The intensity of EME increases with increasing the elastic modulus and decreases with increasing initial damage. The results are in good agreement with the experimental results.
文摘This exploration examines unsteady magnetohydrodynamic(MHD) three-dimensional flow of viscous material between rotating plates subject to radiation,Joule heating and chemical reaction.The non-linear partial differential system is re-structured into the ordinary differential expressions by the implication of appropriate transformations.The developed differential equations are computed by homotopy analysis technique.Numerical consequences have been accomplished by various values of emerging parameters.Coefficients of skin friction and heat and mass transfer rates have been scrutinized.Irreversibility analysis is carried out.Influence of various prominent variables on entropy generation is presented.Moreover,the temperature increases for higher Dufour number and concentration distribution reduces against Soret number.Higher squeezing parameter enhances velocity while concentration reduces with an increment in squeezing parameter.Both entropy rate and Bejan number increase against higher diffusion parameter.
