New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl_(3)·{(CH...New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl_(3)·{(CH_(2))_(4)O_(2)}_(1.5)].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z=16.The trivalent antimony ion not only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.展开更多
In-situ rock failures can result from stress changes due to pure loading and/or unloading. Understanding of the damage evolution behavior in brittle rocks during loading and unloading is imperative for the designs of ...In-situ rock failures can result from stress changes due to pure loading and/or unloading. Understanding of the damage evolution behavior in brittle rocks during loading and unloading is imperative for the designs of rock structures. In this paper, we investigate the damage evolution characteristics of a granitic rock during loading and unloading after a series of triaxial experiments performed at different confining pressures. The axial stress-axial strain variations of the tested specimens revealed that the specimens undergoing unloading fail with a lower axial strain compared to the specimens failed purely by loading. Higher confining pressures were observed to exacerbate the difference. Volumetric strain versus axial strain curves indicated that the curves reverse the trend with the beginning of major damage of specimens. We suggest here a new form of equation to describe the secant modulus variation of brittle rocks against the axial stress for the unloading process. Failure mechanisms of tested specimens showed two distinct patterns, namely, specimens under pure loading failed with a single distinct shear fracture while for the unloading case specimens displayed multiple intersecting fractures. In addition, analysis of the evolution of dissipation and elastic energy during deformation of the specimens under loading and unloading conditions showed differentiable characteristics. Moreover, we evaluated the variations of two damage indices defined based on the energy dissipation and secant modulus evolution during deformation and observed that both of them satisfactorily distinguish key stages of damage evolution.展开更多
A series of researches were carried out for the soil samples in the Pearl River Delta under the action of consolidation loads,such as the quantitative analyses of the pore scale,shape and size distributions of micro-s...A series of researches were carried out for the soil samples in the Pearl River Delta under the action of consolidation loads,such as the quantitative analyses of the pore scale,shape and size distributions of micro-structure units,with an environmental scanning electron microscope (ESEM),a mercury intrusion analyzer and a mineral diffractometer. The experimental results show that the consolidation pressures remarkably change the pore sizes and distribution characteristics of the silt,thus changing its compressibility and permeability. This can be proved by the fact that,in the earlier stage with a consolidation pressure of p<200 kPa,the pore sizes are greater and the compressibility and permeability coefficients are larger. However,they rapidly decrease with the increase in consolidation pressure. And in the later stage with a consolidation pressure of p>200 kPa,the pore sizes are smaller and the compressibility and permeability coefficients are less. Therefore,the empirical formulas of compression coefficient and permeability coefficient vs consolidation load and average pore diameter are deduced.展开更多
A moisture-content based constitutive model was proposed based on the hyperbolic model as an attempt to move towards the implementation of unsaturated soil mechanics into routine geotechnical engineering practice. The...A moisture-content based constitutive model was proposed based on the hyperbolic model as an attempt to move towards the implementation of unsaturated soil mechanics into routine geotechnical engineering practice. The stress-strain behavior of in-situ soil at a depth of 5 m was investigated by conducting undrained triaxial compression tests using the remolded soil samples. The test results show that the stress-strain relationship of unsaturated cohesive soil is still hyperbolic. The values of parameters a and b given in the model decrease with increasing the confining pressure for soil samples with the same moisture content and increase with increasing the moisture content for soil samples under the same confining pressure. The relationships between parameters a, b and moisture content were studied for confining pressures of 100, 150, 200 and 250 kPa. The comparison between the measured and predicted stress-strain curves for an additional group of soil samples, having a moisture content of 25.4%, shows that the proposed moisture content-dependent hyperbolic model provides a good prediction of stress-strain behavior of unsaturated cohesive soil.展开更多
文摘New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl_(3)·{(CH_(2))_(4)O_(2)}_(1.5)].The crystal structure of the comple x belongs to cubic system,space group I-43d,a=17.1417(5)?,Z=16.The trivalent antimony ion not only bonds directly to three chlorine anions,but also is co ordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule wi ll coordinate to different antimony ions,respectively.
基金Projects(51774187,51324744,51374129)supported by the National Natural Science Foundation of ChinaProject(71380100006)supported by the Innovation Foundation of Doctoral Student in Hunan Province,China+1 种基金Project(2017SK2280)supported by the Key Research and Development Program of Hunan Provincial Science and Technology Department,ChinaProject(17A184)supported by the Key Research Foundation of Education Bureau of Hunan Province,China
文摘In-situ rock failures can result from stress changes due to pure loading and/or unloading. Understanding of the damage evolution behavior in brittle rocks during loading and unloading is imperative for the designs of rock structures. In this paper, we investigate the damage evolution characteristics of a granitic rock during loading and unloading after a series of triaxial experiments performed at different confining pressures. The axial stress-axial strain variations of the tested specimens revealed that the specimens undergoing unloading fail with a lower axial strain compared to the specimens failed purely by loading. Higher confining pressures were observed to exacerbate the difference. Volumetric strain versus axial strain curves indicated that the curves reverse the trend with the beginning of major damage of specimens. We suggest here a new form of equation to describe the secant modulus variation of brittle rocks against the axial stress for the unloading process. Failure mechanisms of tested specimens showed two distinct patterns, namely, specimens under pure loading failed with a single distinct shear fracture while for the unloading case specimens displayed multiple intersecting fractures. In addition, analysis of the evolution of dissipation and elastic energy during deformation of the specimens under loading and unloading conditions showed differentiable characteristics. Moreover, we evaluated the variations of two damage indices defined based on the energy dissipation and secant modulus evolution during deformation and observed that both of them satisfactorily distinguish key stages of damage evolution.
基金Project(2008ZA11) supported by State Key Laboratory of Subtropical Building Science in South China University of Technology, ChinaProject(20080430815) supported by China Postdoctoral Science Foundation
文摘A series of researches were carried out for the soil samples in the Pearl River Delta under the action of consolidation loads,such as the quantitative analyses of the pore scale,shape and size distributions of micro-structure units,with an environmental scanning electron microscope (ESEM),a mercury intrusion analyzer and a mineral diffractometer. The experimental results show that the consolidation pressures remarkably change the pore sizes and distribution characteristics of the silt,thus changing its compressibility and permeability. This can be proved by the fact that,in the earlier stage with a consolidation pressure of p<200 kPa,the pore sizes are greater and the compressibility and permeability coefficients are larger. However,they rapidly decrease with the increase in consolidation pressure. And in the later stage with a consolidation pressure of p>200 kPa,the pore sizes are smaller and the compressibility and permeability coefficients are less. Therefore,the empirical formulas of compression coefficient and permeability coefficient vs consolidation load and average pore diameter are deduced.
基金Project(50608038) supported by the National Natural Science Foundation of China
文摘A moisture-content based constitutive model was proposed based on the hyperbolic model as an attempt to move towards the implementation of unsaturated soil mechanics into routine geotechnical engineering practice. The stress-strain behavior of in-situ soil at a depth of 5 m was investigated by conducting undrained triaxial compression tests using the remolded soil samples. The test results show that the stress-strain relationship of unsaturated cohesive soil is still hyperbolic. The values of parameters a and b given in the model decrease with increasing the confining pressure for soil samples with the same moisture content and increase with increasing the moisture content for soil samples under the same confining pressure. The relationships between parameters a, b and moisture content were studied for confining pressures of 100, 150, 200 and 250 kPa. The comparison between the measured and predicted stress-strain curves for an additional group of soil samples, having a moisture content of 25.4%, shows that the proposed moisture content-dependent hyperbolic model provides a good prediction of stress-strain behavior of unsaturated cohesive soil.
