目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectr...目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectrometry,TIMS)分析检测^(87)Sr/^(86);样品用锡囊包裹后,利用元素分析-稳定同位素比质谱法分析检测δ^(13)C;利用SPSS 25.0软件对进口大麦的^(87)Sr/^(86)Sr和δ^(13)C进行正态性验证、方差分析、事后多重比较分析和判别分析。结果不同进口国大麦中的^(87)Sr/^(86)Sr和δ^(13)C具有显著性差异,经判别分析,进口自澳大利亚、法国和美国的大麦可以达到100%正确判别率,整体正确判别率达到86.2%,若将美国和加拿大进口的大麦归类为北美洲进口大麦,则可实现进口自北美、法国和澳大利亚大麦的100%正确判别率。结论利用^(87)Sr/^(86)Sr和δ^(13)C可以对不同进口国大麦进行产地溯源分析。展开更多
Infrared signal detection is widely used in many fields.Due to the detection principle,however,the accuracy and range of detection are limited.Thanks to the ultra stability of the^(87)Sr optical lattice clock,external...Infrared signal detection is widely used in many fields.Due to the detection principle,however,the accuracy and range of detection are limited.Thanks to the ultra stability of the^(87)Sr optical lattice clock,external infrared electromagnetic wave disturbances can be responded to.Utilizing the ac Stark shift of the clock transition,we propose a new method to detect infrared signals.According to our calculations,the theoretical detection accuracy in the vicinity of its resonance band of 2.6μm can reach the order of 10-14W,while the minimum detectable signal of common detectors is on the order of 10^(-10)W.展开更多
^87Sr/^86Sr, δ^18O and δ^13C ratios of calcite, dolomite, gypsum filling vugs and fissures in marine carbonates and their host rocks from the Sinian to the middle Triassic, are employed to trace the possible source ...^87Sr/^86Sr, δ^18O and δ^13C ratios of calcite, dolomite, gypsum filling vugs and fissures in marine carbonates and their host rocks from the Sinian to the middle Triassic, are employed to trace the possible source and migration path of key fluids related to development of hydrocarbon, hydrocarbon preservation condition are then discussed further. Comprehensive research, based on the paleo-fluid, the property of formation water and the deformation intensity etc., indicates that the preservation conditions in the Shizhu synclinorium zone and Fangdoushan anticlinorium zone are the most predominant in the central Yangtze. Three sets of fluid systems in the Shizhu synclinorium zone are identified. Little fluid exchange occurs between the upper-middle fluid system and the lower fluid system, so two independent preservation units have developed. Both the Permian and the Triassic in the upper preservation units and the Dengying Formation of the Sinian and the lower Cambrian in the lower preservation units have good preservation conditions. The preservation condition in the lower association （Z-S） located in the Huaguoping synclinorium zone in the western Hubei and Hunan is better than that in other tectonic units, where the fluids in the lower association migrated vertically across strata when the fluid isolating intervals were destroyed, the regional seals are absent and the conditions for the preservation of hydrocarbon accumulations are totally destroyed. The preservation condition is increasingly more favorable from the western Jiangxi and Hunan to the western Hubei ＆ eastern Chongqing on the whole.展开更多
文摘目的建立基于^(87)Sr/^(86)Sr和δ^(13)C稳定同位素比质谱法(stable isotope ratio mass spectrometry,IRMS)的进口大麦产地溯源技术。方法样品干燥粉碎后,经硝酸消解,锶特效树脂净化后利用热电离质谱法(thermal ionization mass spectrometry,TIMS)分析检测^(87)Sr/^(86);样品用锡囊包裹后,利用元素分析-稳定同位素比质谱法分析检测δ^(13)C;利用SPSS 25.0软件对进口大麦的^(87)Sr/^(86)Sr和δ^(13)C进行正态性验证、方差分析、事后多重比较分析和判别分析。结果不同进口国大麦中的^(87)Sr/^(86)Sr和δ^(13)C具有显著性差异,经判别分析,进口自澳大利亚、法国和美国的大麦可以达到100%正确判别率,整体正确判别率达到86.2%,若将美国和加拿大进口的大麦归类为北美洲进口大麦,则可实现进口自北美、法国和澳大利亚大麦的100%正确判别率。结论利用^(87)Sr/^(86)Sr和δ^(13)C可以对不同进口国大麦进行产地溯源分析。
基金Project supported by the National Natural Science Foundation of China (Grant No.12274045)。
文摘Infrared signal detection is widely used in many fields.Due to the detection principle,however,the accuracy and range of detection are limited.Thanks to the ultra stability of the^(87)Sr optical lattice clock,external infrared electromagnetic wave disturbances can be responded to.Utilizing the ac Stark shift of the clock transition,we propose a new method to detect infrared signals.According to our calculations,the theoretical detection accuracy in the vicinity of its resonance band of 2.6μm can reach the order of 10-14W,while the minimum detectable signal of common detectors is on the order of 10^(-10)W.
基金supported by the National Natural Science Foundation(41072082)National Basic Research Program of China(No.2005CB422106)national key subject constructional item of mineralogy,petrology and mineral deposit(SZD0407)and backup candidate fund of academic and technical senior scholar in Sichuan Province
文摘^87Sr/^86Sr, δ^18O and δ^13C ratios of calcite, dolomite, gypsum filling vugs and fissures in marine carbonates and their host rocks from the Sinian to the middle Triassic, are employed to trace the possible source and migration path of key fluids related to development of hydrocarbon, hydrocarbon preservation condition are then discussed further. Comprehensive research, based on the paleo-fluid, the property of formation water and the deformation intensity etc., indicates that the preservation conditions in the Shizhu synclinorium zone and Fangdoushan anticlinorium zone are the most predominant in the central Yangtze. Three sets of fluid systems in the Shizhu synclinorium zone are identified. Little fluid exchange occurs between the upper-middle fluid system and the lower fluid system, so two independent preservation units have developed. Both the Permian and the Triassic in the upper preservation units and the Dengying Formation of the Sinian and the lower Cambrian in the lower preservation units have good preservation conditions. The preservation condition in the lower association （Z-S） located in the Huaguoping synclinorium zone in the western Hubei and Hunan is better than that in other tectonic units, where the fluids in the lower association migrated vertically across strata when the fluid isolating intervals were destroyed, the regional seals are absent and the conditions for the preservation of hydrocarbon accumulations are totally destroyed. The preservation condition is increasingly more favorable from the western Jiangxi and Hunan to the western Hubei ＆ eastern Chongqing on the whole.
