In this study,our recent work on advanced ion chromatographic methods for the simultaneous determination of inorganic ionic species such as common anions(SO2-4,Cl-and NO-3) and cations(Na+,NH+4,K+,Mg2+,and Ca2+),nutri...In this study,our recent work on advanced ion chromatographic methods for the simultaneous determination of inorganic ionic species such as common anions(SO2-4,Cl-and NO-3) and cations(Na+,NH+4,K+,Mg2+,and Ca2+),nutrients(phosphate and silicate) and hydrogen ion/alkalinity are summarized first.Then,the applications using these methods for monitoring environmental water quality are also presented.For the determination of common anions and cations with nutrients,the separation was successfully performed by a polymethacrylate-based weakly acidic cation-exchange column of TSKgel Super IC-A/C(Tosoh,150 mm×6.0 mm i.d.) and a mixture solution of 100 mmol/L ascorbic acid and 4 mmol/L 18-crown-6 as acidic eluent with dual detection of conductivity and spectrophotometry.For the determination of hydrogen ion/alkalinity,the separation was conducted by TSKgel ODS-100Z column(Tosoh,150 mm×4.5 mm i.d.) modified with lithium dodecylsulfate and an eluent of 40 mmol/L LiCl/0.1 mmol/L lithium dodecylsulfate/0.05 mmol/L H2SO4 with conductivity detector.The differences of ion concentration between untreated and treated wastewater showed the variation of ionic species during biological treatment process in a sewage treatment plant.Occurrence and distribution of water-quality conditions were related to the bioavailability and human activity in watershed.From these results,our advanced ion chromatographic methods have contributed significantly for water quality monitoring of environmental waters.展开更多
The w ater quality monitoring operation to evaluate the w ater quality of polluted river is an extremely im po rtant task fo r the river-w atershed m anagem ent/co ntro l based o n the enviro nm ental po licy.In this ...The w ater quality monitoring operation to evaluate the w ater quality of polluted river is an extremely im po rtant task fo r the river-w atershed m anagem ent/co ntro l based o n the enviro nm ental po licy.In this study,the no vel,sim ple and co nvenient w ater quality m o nito ring o f Jialing-River in Cho ngqing,China w as carried o ut using an advanced io n chro m ato graphy(IC) co nsisting o f io n-ex clusio n/catio n-ex change chro m ato graphy(IEC/CEC) with conductivity detection for determining simultaneously the common anions such as SO 2 4,Cl,and NO 3 and the catio ns such as Na +,NH + 4,K +,Mg 2 +,and Ca 2 +,the ion-exclusion chromatography(IEC) w ith visible detectio n fo r determ ining sim ultaneo usly the nutrient co m po nents such as pho sphate and silicate io ns,and the IEC w ith the enhanced co nductivity detectio n using a po st co lum n o f K +-fo rm catio n-ex change resin fo r determ ining HCO 3-alkalinity as an ino rganic-carbo n so urce fo r bio m ass synthesis in bio lo gical reactio n pro cess under the aero bic co nditio ns.Acco rding to the io nic balance theo ry betw een the to tal equivalent co ncentratio ns o f anio ns and catio ns,the w ater quality evaluatio n o f the Jialing-River w aters taking at different sam pling sites in Cho ngqing m etro po litan area w as carried o ut using the advanced IC system.As a result,the effectiveness o f this no vel w ater quality m o nito ring m etho do lo gy using the IC system w as dem o nstrated o n the several practical applicatio ns to a typical bio lo gical sew age treatm ent plant o n Jialing-River o f Cho ngqing.展开更多
基金supported by the Chugoku Regional Development Bureau of the Ministry of Land,Infrastructure,Transport and Tourism,Japan
文摘In this study,our recent work on advanced ion chromatographic methods for the simultaneous determination of inorganic ionic species such as common anions(SO2-4,Cl-and NO-3) and cations(Na+,NH+4,K+,Mg2+,and Ca2+),nutrients(phosphate and silicate) and hydrogen ion/alkalinity are summarized first.Then,the applications using these methods for monitoring environmental water quality are also presented.For the determination of common anions and cations with nutrients,the separation was successfully performed by a polymethacrylate-based weakly acidic cation-exchange column of TSKgel Super IC-A/C(Tosoh,150 mm×6.0 mm i.d.) and a mixture solution of 100 mmol/L ascorbic acid and 4 mmol/L 18-crown-6 as acidic eluent with dual detection of conductivity and spectrophotometry.For the determination of hydrogen ion/alkalinity,the separation was conducted by TSKgel ODS-100Z column(Tosoh,150 mm×4.5 mm i.d.) modified with lithium dodecylsulfate and an eluent of 40 mmol/L LiCl/0.1 mmol/L lithium dodecylsulfate/0.05 mmol/L H2SO4 with conductivity detector.The differences of ion concentration between untreated and treated wastewater showed the variation of ionic species during biological treatment process in a sewage treatment plant.Occurrence and distribution of water-quality conditions were related to the bioavailability and human activity in watershed.From these results,our advanced ion chromatographic methods have contributed significantly for water quality monitoring of environmental waters.
文摘The w ater quality monitoring operation to evaluate the w ater quality of polluted river is an extremely im po rtant task fo r the river-w atershed m anagem ent/co ntro l based o n the enviro nm ental po licy.In this study,the no vel,sim ple and co nvenient w ater quality m o nito ring o f Jialing-River in Cho ngqing,China w as carried o ut using an advanced io n chro m ato graphy(IC) co nsisting o f io n-ex clusio n/catio n-ex change chro m ato graphy(IEC/CEC) with conductivity detection for determining simultaneously the common anions such as SO 2 4,Cl,and NO 3 and the catio ns such as Na +,NH + 4,K +,Mg 2 +,and Ca 2 +,the ion-exclusion chromatography(IEC) w ith visible detectio n fo r determ ining sim ultaneo usly the nutrient co m po nents such as pho sphate and silicate io ns,and the IEC w ith the enhanced co nductivity detectio n using a po st co lum n o f K +-fo rm catio n-ex change resin fo r determ ining HCO 3-alkalinity as an ino rganic-carbo n so urce fo r bio m ass synthesis in bio lo gical reactio n pro cess under the aero bic co nditio ns.Acco rding to the io nic balance theo ry betw een the to tal equivalent co ncentratio ns o f anio ns and catio ns,the w ater quality evaluatio n o f the Jialing-River w aters taking at different sam pling sites in Cho ngqing m etro po litan area w as carried o ut using the advanced IC system.As a result,the effectiveness o f this no vel w ater quality m o nito ring m etho do lo gy using the IC system w as dem o nstrated o n the several practical applicatio ns to a typical bio lo gical sew age treatm ent plant o n Jialing-River o f Cho ngqing.
