The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c r...The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.展开更多
To explore the stabilization effect of stabilizing agent GX07 on treating organic soil and the influence of organic matter on the strength development of stabilized soil,artificial organic soil with various organic ma...To explore the stabilization effect of stabilizing agent GX07 on treating organic soil and the influence of organic matter on the strength development of stabilized soil,artificial organic soil with various organic matter content was obtained by adding different amounts of fulvic acid into non-organic clay,and then liquid-plastic limit tests were carried out on the artificial organic soil.Meanwhile,unconfined compressive strength(UCS) tests were performed on cement-only soil and composite stabilized soil,respectively.The test results indicate that the plastic limit of soil samples increases linearly,and the liquid limit increases exponentially as the organic matter content increases.The strength of stabilized soil is well correlated with the organic matter content,cement content,stabilizing agent content and curing time.When the organic matter content is 6%,as the cement content varies in the range of 10%-20%,the strength of cement-only soil increases from 88.5 to 280.8 kPa.Once 12.6% GX07 is added into the mix,the strength of stabilized soil is 4.93 times compared with that of cement-only soil.GX07 can obviously improve the strength of cemented-soil and has a good economic applicability.A strength model is proposed to predict strength development.展开更多
基金Project(2009CB623105) supported by the National Basic Research Program of ChinaProject(51108341) supported by the National Natural Science Foundation of ChinaProjects(20110490703, 2012T50437) supported by China Postdoctoral Science Foundation
文摘The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.
基金Project(50678158) supported by the National Natural Science Foundation of China
文摘To explore the stabilization effect of stabilizing agent GX07 on treating organic soil and the influence of organic matter on the strength development of stabilized soil,artificial organic soil with various organic matter content was obtained by adding different amounts of fulvic acid into non-organic clay,and then liquid-plastic limit tests were carried out on the artificial organic soil.Meanwhile,unconfined compressive strength(UCS) tests were performed on cement-only soil and composite stabilized soil,respectively.The test results indicate that the plastic limit of soil samples increases linearly,and the liquid limit increases exponentially as the organic matter content increases.The strength of stabilized soil is well correlated with the organic matter content,cement content,stabilizing agent content and curing time.When the organic matter content is 6%,as the cement content varies in the range of 10%-20%,the strength of cement-only soil increases from 88.5 to 280.8 kPa.Once 12.6% GX07 is added into the mix,the strength of stabilized soil is 4.93 times compared with that of cement-only soil.GX07 can obviously improve the strength of cemented-soil and has a good economic applicability.A strength model is proposed to predict strength development.
